反应的

The effects of water,free fatty acid,and acetic acid in the reaction system on the reaction were systematically studied.

系统研究了反应体系中的水、游离脂肪酸和乙酸对反应的影响。

The effects of the amount of catalyst, the amount of acetic anhydride, reaction time, and addition of solvents etc. on the acylation reaction were investigated.

考察了催化剂用量、乙酐用量、反应时间和溶剂的加入等因素对该酰化反应的影响。

The catalytic esterification of acetic anhydride and nine phenols were investigated in the presence of complex resin catalyst at 20 ℃,and its mechanismes were discussed.

研究了 2 0℃时，醋酸酐与九种酚在复合树脂催化剂下的催化酯化反应，并探索了其反应的机理。

This article analyzed the method of calcify reaction on oxalic acid process and put forward the conditions of calcify reaction and acidify reaction.

根据钙化法草酸生产工艺的研究，提出了钙化反应、酸化反应的工艺条

Thus, we redesigned and synthesized a series of new precursors devoid of the unfavourable structural elements for the organocatalytic intramoleculor aldol reactions.

我们重新设计合成了该关环前体的衍生物，希望除去分子中不利于Aldol反应的结构单元以实现关环反应。

The catalytic activity was found to increase with the alkalescence of solvents.

提出在碱金属碳酸盐K_2CO_3的作用下可能遵循两步循环反应的反应机理。

This article that focuses on the systematic and in-depth research in the current primal problem about abnormal burst pressure reservoir depress burst pressure has procured following main fruits:1 It forms the method which could obtain massive vertical static state mechanics parameters.2 In a foundation of acquisition of rock mechanics parameters,apply bent lamella that as mechanical model along with characteristic of actual geologic characteristics to analysis curvature for anticlinal strcture, get homologous tectonic stress value throug relation between the curvature and stress and different principal curvature in anticlinal structure,consequently set up laminational stress model for anticline reservoir. The block lamination for existed fracturing date has formed method of setting up mechanical model of lamination terrestrial stress by abtaining the block tectonic stress coefficients which are got by complex utilization test, laboratory test and fracturing date playback.3 Analysesing the main reason which lead to high burst pressure by considering the characteristic of reservoir geology,reservoir,and rock mechanics and reservoir damage,etc.Establishing burst pressure quantitative prediction model which provide gist for depressing construction risk and optimizing construction craft under the condition of open hole completion ,gun-perforated completion and damaged reservoir.4 Provding theoretical basis for interpreting acidification pretreatment which could depress busrt pressure by finding the relation between the influencing factors and rock machanics parameters and analysing the factors that have effect on rock mechanics parameters. Expounding the mechanism of reaction of mixed monomineral and acid from the angle of microcosmic element, evaluating quantitatively acid sensilility of different kinds of mineral effectively, and determing the first-order reaction dynamical equation of each mineral.5 Revealing rock mechanics property chage as a result of acid flooding in different condition by sandstone traumata experiment in different temperatures which combined with rock mechanics triaxial stress experiment.6 Associating damage mechanics with sandstone acidizing, established sandstone damage mechanics model in the foundation of the recognition on the rock mechanics parametric variation which is caused by acid-rock reaction in both macroscopic view and microscopic view ,also demonstrated those processes and quantitative estimated the acid busrt pressure to direct the site operation.

本文针对目前异常破裂压力储层降低破裂压力的主要问题展开较为系统和深入的研究，取得了以下主要成果：1形成了利用测井资料，结合室内岩芯测试结果，获取静动岩石力学参数的相关性特征，从而获得纵向上大量静态力学参数的方法。2在获取了岩石力学参数的此基础上，利用弯曲薄板作为力学模型，结合区块实际地质特征对背斜构造进行曲率分析，通过曲率与应力的关系，利用背斜构造不同部位的主曲率求得相应的构造应力值，从而建立起背斜储层的分层应力模型；对已有压裂资料的区块分层，形成了综合利用测试、室内实验、压裂资料反演获得该区块构造应力系数，建立起分层地应力的力学模型的方法。3综合考虑储层地质、油藏、岩石力学特性和储层伤害等因素，分析造成高破裂压力的主要原因，综合利用岩石力学、弹性力学等知识，建立了裸眼完井、射孔完井条件下以及储层受到伤害后的储层破裂压力定量预测模型，为降低施工风险和优化施工工艺提供了依据。4完成了物性、岩性影响岩石力学参数的因素分析，找出了各影响因素和岩石力学参数之间的关系，为从机理上解释酸化预处理降低破裂压力提供了理论基础；从微观元素的角度阐述了单矿物与酸反应的机理；并在此基础上，有效评价了各种矿物的酸敏感性，定量确定了岩石中各矿物的一级反应动力学方程。5完成了不同温度下的酸液类型、酸液浓度、注酸量等一系列砂岩损伤实验，结合岩石力学三轴应力实验，系统揭示了在不同条件下注酸而引起的岩石力学性质变化。6将损伤力学与砂岩酸化相结合，在宏观、微观两个方面认识酸岩反应引起岩石力学参数变化基础上，建立了砂岩损伤力学模型，并对其进行验证，在此基础上定量计算酸化后的破裂压力，有效指导现场施工

Dynamic reliability under Littlewood-Paley wavelet is the biggest, dynamic reliability under modified meyerwavelet and harmonic wavelet are close. Analyzing the dynamic reliability of structure under odd exponent wavelet is very simple, it doesn't calculate Power Spectral Density function integral, it is only to calculate the square of displacement standard deviation and the square of velocity, then the dynamic reliability of structure can be concluded by max distribution. In addition the effects of upper limit is considered, when upper limit is smaller, the dynamic reliability of structure is less, that is, the damage possibility is bigger.

通过结构地震反应在小波基下的动力可靠性分析说明：无论是单自由度还是多自由度从理论上推导在这四种小波下的结构动力可靠性是可行的，而且考虑的结构地震反应都是非平稳的高斯过程，方法实现也比较容易；在Littlewood—Paley小波基下求得的结构的动力可靠度比较大，由改造的meyer小波和谐波小波求得的动力可靠度略有差异；单边指数小波下的结构动力可靠性分析非常简单，不用求功率谱函数来积分，只需求得结构地震反应的位移方差，速度方差，利用最大值分布公式就可得到结构的动力可靠时程；另外也考虑了超越界限对结构动力可靠度的影响，超越界限越小，结构的动力可靠度越小，即破坏概率越大。

Dynamic reliability under Littlewood-Paley wavelet is the biggest, dynamic reliability under modified meyerwavelet and harmonic wavelet are close. Analyzing the dynamic reliability of structure under odd exponent wavelet is very simple, it doesnt calculate Power Spectral Density function integral, it is only to calculate the square of displacement standard deviation and the square of velocity, then the dynamic reliability of structure can be concluded by max distribution. In addition the effects of upper limit is considered, when upper limit is smaller, the dynamic reliability of structure is less, that is, the damage possibility is bigger.

通过结构地震反应在小波基下的动力可靠性分析说明：无论是单自由度还是多自由度从理论上推导在这四种小波下的结构动力可靠性是可行的，而且考虑的结构地震反应都是非平稳的高斯过程，方法实现也比较容易；在Littlewood—Paley小波基下求得的结构的动力可靠度比较大，由改造的meyer小波和谐波小波求得的动力可靠度略有差异；单边指数小波下的结构动力可靠性分析非常简单，不用求功率谱函数来积分，只需求得结构地震反应的位移方差，速度方差，利用最大值分布公式就可得到结构的动力可靠时程；另外也考虑了超越界限对结构动力可靠度的影响，超越界限越小，结构的动力可靠度越小，即破坏概率越大。

Nickel phosphide was chosen as the HDN catalyst in the present dissertation because it is reported to have the highest activity among transition metal phosphides. For the supported nickel phosphide catalysts, mesoporous MCM-41 was used as the carrier. The effect of support modification and the introduction of a secondary metal species on the activity of supported nickel phosphide catalysts were studied.

本论文以磷化镍催化剂为研究对象，考察了MCM-41负载的磷化镍催化剂的制备及其对喹啉的HDN反应性能，载体和活性组分的改性对喹啉HDN反应性能的影响，以及TiO_2的引入对非负载的磷化镍催化剂HDN反应的影响。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！