反应率

It was also obtained that the supercooling or the overpressure degree and time could stimulate the formation of hydrate.

得出了衡量反应进行程度的天然气水合物含气率随反应进行时间的关系曲线。

Under aqueous phase reactant limiting condition, the yield can reach 95% under appropriate conditions after reacting for 150 minutes.

於水相反应物为限量试剂时，较能突显其功效，在适当的反应条件下，反应150分钟，产率能达95%。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

The experimental result showed that the optimal conditions were the molar ratio of potassium bromide to cyclohexanol 1:0.8, H2O 1.5mL,concentrated sulfuric acid 5mL , reflux reaction for 4h, the separated yield was high up to 93%.

结果表明，当反应条件为：溴化钾与环己醇摩尔比1：0.8，水1.5mL，浓硫酸5mL，回流反应4h，分离产率高达93%。

We focused the study on the synthesis methods of quinoxaline, nitration of its aromatic ring and chlorination of its heterocycle. In this paper, we thought about environmental protection, the cost of material, the feasibility of industrialization, workup easily, and obtained 2,3(1H,4H)-quinoxalinedion, 6-nitro-2,3(1H,4H)-quinoxalinedion, 6,7-dinitro-2,3(1H,4H)–quinoxalinedion, 2,3-dichlo- roquinoxaline, 6–nitro-2,3-dichloroquinoxaline,and 6,7- initro-2,3-dichloro-quinoxaline. A more reasonable, easily, efficient and simple reactive route to synthesize above-mentioned compounds was developed by systematically investigating the yield, the purity and physical character of intermediates.

本文针对喹喔啉及其芳环硝化、杂环氯代的合成进行研究，主要考虑了环保性、原料成本、产业化的可行性、反应操作的简便性等问题，获得了2，3(1H，4H)-喹喔啉二酮、6-硝基-2，3(1H，4H)-喹喔啉二酮、6，7-二硝基-2，3(1H，4H)-喹喔啉二酮、2，3-二氯喹喔啉、6-硝基-2，3-二氯喹喔啉和6，7-二硝基-2，3-二氯喹喔啉等六个中间体，考察了反应产物的产率、纯度和性状等因素，得到了更为合理、方便、实用、简洁的可供产业化的合成路线。

The results showed that there three important factors to influence the yield: that is concentration of the acid,concentration of reactant and reaction temperature.

发现了影响产率的三个重要因素分别是：酸类型和浓度、反应物浓度和反应温度。

It was found that low hydrogen purity and high moisture content of the hydrogen used for deoxidation was the main cause. Countermeasures such as exhausting 90% of the waste gas from the deoxidation process to hydrogen recompression system to reduce the water content in deoxidation zone, and using hydrogen from PSA unit to replace recycle hydrogen to increase the hydrogen purity, were adopted.

参考UOP公司及其它重整装置的经验，对重整催化剂还原工艺进行了改进，将90％的还原废气排入增压氢系统，可有效降低还原区的水含量；用PSA氢替代循环氢，可进一步提高还原区氢纯度，从而提高还原反应速度，改善再生催化剂的性能，使重整反应的芳烃产率有所提高。

According to orthogonal experiments, the optimum technological conditions were obtained as follows: m(88.5% safrole): m: m=1: 0.2: 0.25, temperature 90℃ and time 5 h. The yield of isosafrole was 99.9% under such conditions.

通过正交实验，得到固载PEG-X(polyethylene glycol-X)催化最优工艺条件为：m（88.5%黄樟油）：m： m=1：0.2：0.25，反应温度90℃，反应时间5h，在此工艺条件下，异黄樟油素得率为99.9%。

Results in mac group,painless percentage was 100%,98 patients (98%)was sedately asleep,16 patients(16%)had low grade body movement,4 patient(4%) had obvious body movement,awake time was short,and the vital signs were stable during colonoscopy.in control group,all patients have different windy,bellyache,crying out,body movement or other discomfort.the incidence of adverse reaction in control group was higher than that in mac group.

结果 mac 组无痛率100%，其中安静入睡98例(98%)，轻微肢体活动16例(16%)，明显肢体活动影响操作4例(4%)，清醒时间短，不良反应少，检查中生命体征平稳。对照组病例则有不同程度的腹胀、腹痛、大声喊叫、肢体活动及其他不适，不良反应多。

The dissolution remarkedly slows down when the dissolved percentage of Ti is in excess of 22% due to lower reactivity of the perovskite and the coverage from silicic acid, of which the former may be the primary reason.

当钛的浸出率超过22%以后，浸出速度显著下降，这是钙钛矿的反应活性差以及硅酸的包裹所致，而钙钛矿的反应活性差可能是浸出速度显著下降的主要原因。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！