反应率

During the study, many factors, such as: density of H2SO4 solution, reaction ratio of materials, reaction temperature and time, are studied how to effect the extraction yield of Li2O. After these studies, the optimal conditions are summarized: 50% H2SO4 solution and lepidolite powder which has been grounded to a particle size of 80~100microns, react at 2:1ratio,120℃ temp for 8h～10h.

在此过程中主要探索了硫酸水溶液的浓度对氧化锂提取率的影响，以及硫酸溶液与云母粉的反应配比、反应温度、反应时间对提取率的影响；研究了提取液pH值的调节对溶液中金属离子的影响。

Yields from chiral bisoxazolines (5a) with diethyl oxalate using NaOCH〓 as base for the first time. The structures of chiral multioxazolines and their intermediates, multi (β-hydroxylamide) s, were characterized by 〓H NMR, IR, mass spectra and elemental analysis. The catalytic activities and enantioselectivities of chiral multi (β-hydroxylamide) s (4) and chiral multioxazolines (5～8) were investigated by using acetophenone and β-acetonaphthone as former chiral ketone, KBH〓 or NaBH〓 as reductive reagent in chapter three.

在此基础上，对合成方法作了创新，以羧酸或酯为原料，在无催化剂的条件下与手性α-氨基醇反应，通过回流分水或脱醇的方法，一步反应合成了手性多噁唑啉（5～8），产率为89.2%～98.4%；以手性双噁唑啉（5a）为原料，在NaOCH〓的作用下，与草酸二乙酯反应，首次合成了呋喃类双嗯唑啉（6a），产率为72.9%～75.6%。

And on the basis of mono-factor test, using COD decreasing rate and decolour rate as targets, six factors affecting catalytic effect were selected to proceed L9(34) orthogonal experiments. The conclusion of primary and secondary factors was drawn and the turn was : kind of catalyst-amount of catalyst-pH value-temperature-amount of H2O2-amount of air . The optimization were determined to be : initial pH value : 5.5 ; temperatare : 90 C; amount of H2O2: lml/400ml waste water ; kind of catalyst: AC3 ; inciting small amount of air ; amount of catalyst: 125g activated carbon to 500g stone .

并在单因素试验的基础上，以废液COD去除率和脱色率为指标，选择废液初始pH值、反应温度、启动剂用量、催化剂类型、鼓空气量、催化剂加入量为因素，进行L_9(3~4)正交试验，确定影响因素因素的主次关系为：催化剂类型→催化剂加入量→废液初始pH值→反应温度→启动剂量→鼓空气量；最佳处理技术条件为：废液初始pH5.5；反应温度90℃；启动剂量1ml／400ml废液；AC3型催化剂；鼓小流量空气；炭石比125g／500g。

The results showed that the degrdation rate of fluorobenzene by TiO2/SnO2 coating rosed from 71.9% to 90.1% compared with pure TiO2 coating. The apparent rate constant k of the photocatalytic degradation is related to the initial concentration of fluorobenzene and the reaction order is zero. The corresponding degradation rate of aldehyde with the concentration of 100ppm rosed from 69.2% to 91.4% and the reaction order is one.

结果表明：与未改性涂料相比，SnO2改性涂料的活性对氟苯的降解率由71.9％提高到90.1％，反应表观速率常数与降解液初始浓度有关，光催化降解氟苯属于零级反应；对100ppm乙醛的降解率由69.2％提高到91.4％，光催化降解乙醛属于一级反应。

Now, a convenient, efficient pinacol coupling of aldehydes mediated by zinc in good yields has been carried out in ammonia water in the presence of a little crown ether. Adding a small amount of crown ether was highly effective to enhance the yields of pinacol from 63% to 84%.

本文报道一种简便、有效的水相呐偶合反应，它是在含有少量冠醚的稀氨水溶液中，使用锌粉促进醛基化合物进行水相呐偶合反应，其中加入少量的冠醚有助于提高反应的产率，呐醇产率由63%提高到84%。

ABSTRACT It is because that the excellent acceptors for maize transgenic engineering are insufficient in our country, especially in the southwest mountain areas of china and hereditary variation regularity for the two characters such as efficiency of embryonic callus induction and number of regenerating plant (these two characters were abbreviated to the nduction efficiency and number of regenerating in the following of the paper, respectively), which hint the maize culturing capacity, is not very clear. Therefore, aiming at picking out superior acceptors, we had made systematic researches on the two characters with combing traditional quantitative-character genetic analyzing methods such as single-factor genetic mating design, diallel crossing genetic design, genetic effect analyzing method and the modern molecular locating method such as QTLs'. The main results are followed.(1) 50 superior inbred lines and about 30 crosses in our country, especially in the southwest of China were used for identifying and selecting the superior genotypes in the above two investigated characters under the same culturing condition in 2000 and 2001. There was very significant difference among the genotypes in the both characters. But the two characters were not certainly related. Some genotypes such as 18-599 and 18-599 were very good in them. For some ones such as zong 31, induction was higher than 18-599 and 18-599 in the efficiency, but it was only 1/3 to the later in regenerating number. In some genotypes such as S37, R08, R15, P138, A318, induction efficiency was just about 3% and scarcely any regenerating plants were got. On the whole, hybrids acted better than inbreeds in the both characters.(2) Two kind of inbreeds were selected as parents of the Griffing's method 1. 18-599 and 18-599 and the inbred line zong 31 are one kind because they are not only superior in the characters of maize cross breeding, such as CA, resistance to disease and the important agricultural characters, but also excellent in transformation characters as the induction and regeneration.

针对我国、特别是西南山地所需玉米转基因工程育种优良受体极为匮乏和反应玉米幼胚培养能力的2个主要性状，即玉米幼胚胚性愈伤组织诱导率和胚性愈伤组织绿苗发生数的遗传变异规律十分不清楚的实际情况，本研究从筛选玉米转基因工程所需要的优良受体入手，采用单因素遗传交配设计、双列杂交遗传交配设计、世代基因效应等传统数量性状分析方法，以及现代分子标记定位主效QTL分析方法，对玉米幼胚胚性愈伤组织诱导率和胚性愈伤组织绿苗发生数等2个性状进行了较为系统的分析研究，取得以下主要研究结果：(1)于2000年和2001年通过对我国、特别是西南地区近50份优良自交系和近30个杂交组合，在相同培养条件下，对幼胚培养胚性愈伤组织诱导率和胚性愈伤组织绿苗发生数等2个幼胚培养能力性状进行了筛选与鉴定，发现玉米不同基因型具有完全不同的幼胚培养胚性愈伤组织诱导率和胚性愈伤组织绿苗发生数，但幼胚培养胚性愈伤组织诱导率与胚性愈伤组织绿苗发生数并不具有必然的相关关系，有的基因型，如自交系18-599和18-599在胚性愈伤组织诱导率和愈伤组织绿苗发生数等2个性状都表现相当优异；有的基因型，如自交系综31，仅幼胚培养胚性愈伤组织诱导率性状表现高于19-599和18-599，但在胚性愈伤组织绿苗发生数这一性状则与它们有相当大的差距，仅为19-599和18-599的1/3左右；有的基因型，如S37、R08、R15、P138、A318等玉米自交系不仅幼胚培养胚性愈伤组织诱导率很低，平均仅在3％左右，而且胚性愈伤组织绿苗发生数表现也很差，基本上没有分化成苗。

Under catalysis of AlCl3, trans-1-chloro-3-phenyl-1-propen-3-one was first prepared using benzoyl chloride and acetylene in CH2Cl2 at 20~25℃, which the yield is 7% higher than that in CCl4 at 40~45℃.

通过对其反应条件的研究，首次用苯甲酰氯和乙炔在三氯化铝作用下合成出反－3-苯基－1-氯－1-丙烯－3-酮；并发现用二氯甲烷作介质在20~25℃下的反应产率，比用四氯化碳作介质在40~45℃下的反应产率约高7%。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围内，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不随NaBr浓度增大而增大。

In the concentration rage used the rete constant k is directly proportional to the concentration of TEMPO while is proportional to the concentration of NaBr in a relatively lower range and tends to level off at higher concentration.

在本研究所用的TEMPO浓度范围內，氧化反应这率与TEMPO的浓度成正比。在较低浓度时，氧化反应速率与NaBr用量也成正比，但浓度较大时，氧化反应这率基本不隨NaBr浓度增大而增大。

In this situation,the electrode potential at equilibrium(i.e,when the rate of the anodic reaction equals the rate of the cathodic reaction) will be shifted from the standard electrode potential and can be defined by the Nernst equation:(5)where E0 is the standard electrode potnetial ,RT/F is a constant,n is the number of electrons transferred ,and a is the activity of the anodic and cathodic reactants.

在这个情况，电极电位在平衡(即，当正极反应的率合计负极反应的率)从标准电极电位将被转移，并且可以由能斯脱等式定义：(5) E0是标准电极potnetial的地方， RT/F是常数， n是转移的电子的数量，并且a是正极和负极反应剂的活动。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。