反应物

In order to study the aldol condensation of 2.15-hexadecanedione on the surface of aluminium, the intermolecular condensation mechanism of acetone occurring on aluminum was simulated by using semi-empirical AM1 method embodied in MOPAC 6.0 program package. The optimized structures and geometry parameters of 5 transition complexes and 4 intermediates were given.First, 2 molecules of acetone coordinated with aluminum by electrostatic attraction.One atom of hydrogen of acetone migrated to aluminum because of t...

为了研究2，15－十六烷二酮在氧化铝表面的环合机理，选择小分子丙酮为模型化合物，用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理，给出了反应过程中的5个过渡态和4个中间体的结构和几何参数，该催化反应可以认为是氧化铝分子与两分子丙酮分子发生静电络合作用，然后借助氧原子的负电荷导致脱氢并实现缩合，根据中间体的能量变化，推测有较稳定的铝复合物生成。

Chiral SalanCrX complexesa saturated version of SalenCr(ⅢX are designed,and in conjunction with an ionic quaternary ammonium salt or organic strong base can efficiently catalyze the asymmetric,regio-and stereoselective alternating copolymerization of CO_2 with rac-PO at mild conditions to afford isotactic-enriched polycarbonates with～95%head-to-tail linkages and moderate enantioselectivity.

本论文在Salen构型配体的基础上，设计合成了一系列手性Salan型铬配合物，并将其与季铵盐/有机强碱组成亲电-亲核双组分催化体系，在室温下可以有效的催化CO_2和环氧丙烷的不对称交替共聚反应，实现了CO_2和环氧丙烷的不对称交替共聚反应的区域和立体化学控制，得到95%的头尾连接单元和中等光学纯度(对映体过量值ee%≈70%)的全同结构的聚碳酸酯。

In the enzymatic reaction, the browning substrates are oxidized toο-quinones and finally polymerized into the brown-colored by-products.To identify the browning substrates caused by PPO of pericarp tissues of litchi fruit, the experiments were conducted for the first time to separate, select and purify these substrates.

一般认为荔枝采后褐变主要是由于果皮细胞中多酚氧化酶与酚类底物区域化分布的破坏而导致酶促反应的发生，表现为酚类物质被催化氧化为醌，后者则通过聚合反应形成褐色产物。

Chiral ligands mentioned above and their complexes with acetate copper were used as enantio-selective catalysts in asymmetric cyclopropanation reactions of diazoacetate and 1,1-diphenyl ethylene. Investigations indicate that all of them reveal certain optical-selective capability, but chiral C2-symmetric 2,6-bispyridine ligands show better catalytic capability than chiral asymmetric schifF-base ligands.

选择了2个手性2，6-吡啶双噁唑啉配体和6个手性不对称席夫碱配体与醋酸铜形成的配合物作为催化剂，对重氮乙酸乙酯与1，1-二苯乙烯不对称环加成进行催化反应，发现这8个催化剂对1，1-二苯乙烯的不对称环丙烷化反应都表现出了一定的光学活性诱导能力，手性2，6-吡啶双噁唑啉-铜类具有比手性Schiff碱-铜类更好的催化性能。

L~(-1) each, 3.5μL of downstream primer 10μmol ? L~(-1,4μL of RNA,5μL of double-distilled DEPC H_2O;PCR mixture consisted of 20μL of RT-Mixture,5μL of 10 × PCR buffers, 1μL of Taq5U·μL~(-1, 5uL of mixture of dNTPs the 2.5 mmol ?

包括AMV5u·μL~(-11μL，5×Reverse transcriptase buffer 4μL，RNase Inhibitor40U·μL~(-10.5μL，dNTPs混合物10mmol·L~(-1each2μL，下游引物10μmol·L~(-13.5μL，模板4μL，水5μL；PCR反应体系：总反应体系为50μL。

Nine different aphid-resistant alfalfas and four cross bred F1 were used in this experiment to investigate better dosage in SSR technique system and to seek the best combination among factors.At last,the best SSR technique system was established. The Taq DNA polymerase was 0.2μL(5U/μL),the 10×Buffer(Mg2+Plus)was 2.5μL , the dNTP Mixture was 2μL ( 2.5mmol/L), the primer was 1.5μL (10μmol/L),the template DNA was 1μL,the ddH2O was 16.3μL ,and the whole system was 25μL.

以九个不同抗蚜级别的苜蓿品种及四个杂交F1代为试材，摸索SSR反应体系中各个影响因素的浓度和用量，确定适合苜蓿抗蚜虫基因定位的SSR反应体系：其中Taq DNA聚合酶0.2μL(5U/μL)，10×Buffer(Mg2+Plus) 2.5μL，dNTP Mixture 2μL (各2.5mM)，引物各1.5μL (10μM)，模板DNA1μL，ddH2O 16.3μL补足25μL。

The coordination reactions of Cu and Ni with acid alizarine blue B in the presence of cetyltrimethylammonium bromide micelle were investigated using the microsurface adsorptionspectral correction technique. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu or Niand AABB.

应用微相吸附-光谱修正技术，研究了Cu、Ni与酸性茜素蓝B在溴化十六烷基三甲铵胶束上的配位反应，分析了表面活性剂在配位反应中的增效机理，表征了二元和三元结合物的性质。

Under these conditions several aryl iodides bearing awide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下，大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化储蓄型投资银条合物，但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应，高度非对映选择性地一步控制了含有季碳的三个相邻立体中心，有效地构建了&2-季碳1，3-二醇&结构单元，首次实现了此类重排—还原过程的催化循环，其中对于两个C1位的差向异构体底物，此反应具有明显的非对映选择性放大特点。

When the proportion of amino acid and Fe~(3+) is above 2, the photoreduction reaction of Fe~(3+) at the early stage exhibits a first-order reaction kinetic pattern, but remains nearly stable after 100 min.

在氨基酸与铁浓度配比大于2的情况下，在铁-氨基酸盐配合物的光还原反应初期铁浓度的增长符合一级动力学反应规律，100 min后浓度趋于稳定。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。