反应物

In DMSO, the polymerization of methyl methacrylate could be carried out efficiently. However the photopolymerization was inhibited in acetonitrile. It was ascribed to the complex formed between coumarin 1 and HTIB photolyzed to unreactive species after irradiation in acetonitrile.

在一般极性溶剂中如DMSO中能有效地引发甲基丙烯酸甲酯光聚合，而在电子受体性质的极性溶剂如乙腈中，光聚合反应受阻，这归结于香豆素1与羟基苯基碘鎓盐形成络合物，使得光反应后生成不具活性的产物。

Rational reaction condition is that ratio of the Cu(superscript 2+) schiff base complex of disproportionated rosin amine is 3%, urushiol concentration is 68.8 g/L, the system of reaction reacts 36 h at 30℃ in alcohol dissolvent.

结果表明，氧化聚合反应的理想条件是以乙醇为溶剂，加入3%歧化松香胺席夫碱－铜配合物催化剂，漆酚浓度为0.0688g/ml，在30℃下反应36h后，漆酚聚合物的沉淀得率为51.3%。

The structure reveals the catalytic intermediate of DAPDC, in which L-lysine is covalently bonded to PLP to form an external aldimine. This conformation provided the best insight to date on the substrate binding and catalytic mechanism of DAPDC. It also supplied valuable clues for designing specific DAPDC inhibitors.

通过分析我们发现这是DAPDC酶家族的第一个反应中间态结构，即反应产物L-赖氨酸与辅酶PLP共价结合形成了外源醛亚胺的构象，这为了解DADPC的底物结合情况及催化机理提供了迄今为止最详细深入的结构信息，也为针对DAPDC设计特异性抑制剂提供了宝贵的线索。

The selected alkylogen shall not react with magnesium in the mode of Grignard reaction.

结果表明：将镁、有机醇以及不与镁发生&格式反应&的卤代烷相互作用可迅速发生反应形成新型含镁络合物溶液。

We make chloroacetylaion to N-terminal of Asp, and then convert this compound to GD dipeptide by aminolysis. Followed the lipase -catalyzed peptide synthesis of RGD in aqueous water-miscible organic cosolvent is studied. We set up a new efficient reaction method to synthesize RGD tripeptide. The problem that peptide containing polar amino acid can not be synthesized readily in organic solvent was solved. We offer a new experimental proof for PPL-catalyzed peptide synthesis and make a more general analysis for the effect of some factors in theory.

采用氯乙酰基保护天冬氨酸，然后进行氨解生成GD二肽，利用猪胰脂肪酶催化合成RGD三肽，着重解决了亲水氨基酸/肽片段底物的溶解性与合成产率低的问题，建立了一种新的有效合成RGD三肽的反应模型，并探索解决了极性较强的氨基酸的酶促肽合成的问题，对脂肪酶催化合成肽的影响因素从理论上作了较全面的分析，为肽片段的缩合反应提供了一种新思路。

The amphoteric fatliquor of N-amidel- polyethylene polyamine -β-aminopropionic acid types has been synthesized by nature oil and fat reaction with polyethylene polyamine and acrylic acid .

用天然油脂、多乙烯多胺和丙烯酸合成制得N -酰胺基多乙烯多胺-β-氨基丙酸型两性加脂剂，最佳合成条件分两步的反应温度分别控制在 10 0℃及 12 0℃、两步反应时间分别为 2h和 4h ，天然油脂与多乙烯多胺及丙烯酸的物质量的比为 1：0 。

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论；能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性；掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

The synthesis and reactivity binuclear complexes with Ph_2PPy have assumed considerable interest because of the novel structural and reactive features of these complexes, and their potential as catalysts.

因为Ph_2PPy类双核配合物新奇的结构和反应特征，以及潜在的催化性能，其合成和反应引起人们很大的兴趣。

And the exciplex formation which was occurred in excited state in aliphatic amine systems will not affect the ATRP process as serious as salt formation in the system of bipyridyl.

而脂肪胺体系生成的激基复合物由于发生于激发态，因此它就不像联吡啶的成盐反应哪样，会严重影响反应进行，导致ATRP效率的降低。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。