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The development of novel catalysts is the key of the study. In some typical technologies developed up to now, [PtCl2] or HgSO4 is used as catalyst with oleum as solvent with higher conversion ratio and yield.

甲烷液相部分氧化反应制甲醇的研究中催化剂的开发是该研究的关键,迄今为止,已开发的该过程典型工艺是在发烟硫酸溶剂中,采用铂配合物[PtCl2]或HgSO4为催化剂进行的反应。

Under basic conditions p-nitrotoluene was oxidized to p-nitrobenzoic acid with oxygen or air. The reaction parameters, such as reaction temperature, reaction time, substrate concentration were optimized and 75% of p-nitrobenzoic acid was obtained under proper conditions.

论文探讨了在碱性条件下,用空气/氧气氧化对硝基甲苯的反应,得出了温度、时间、底物浓度、催化剂用量等工艺参数对反应的影响,在较佳的工艺条件下,对硝基苯甲酸的收率可达到75%左右。

The method is raw material with pyrimidine of 5- fluorine make water, after reacting with chloric second acid below the intention that changes potassium in oxyhydrogen, with complex intermediate body 2- amino - 5- is replaced - 1, 3, 2 Zun reaction makes 4- Sai target content, evaluate its to fight tumor active.

方法以5-氟尿嘧啶为原料,在氢氧化钾的功能下和氯乙酸反应后,和合成的中间体2-氨基-5-取代-1,3,4-噻二唑反应制得目标物,并评价其抗肿瘤活性。

The results show that demethanolation reaction of CaCl 2·2CH 3OH is subject to the mechanism of irregular phase boundary reaction.

结果表明,氯化钙的甲醇络合物解离反应符合不规则的相边界反应机理。

Under aqueous phase reactant limiting condition, the yield can reach 95% under appropriate conditions after reacting for 150 minutes.

於水相反应物为限量试剂时,较能突显其功效,在适当的反应条件下,反应150分钟,产率能达95%。

The influence of various parameters,such as the molar ratio of rhodium to phosphine,the reaction temperature and pressure on the hydroformylation were investigated.

50年代中期[1 ] ,人们发现铑络合物比钴对氢甲酰化反应具有更高的活性,可以使反应在更温和的操作条件下进行。

However, Pinene and Benzaldehyde were the effect of inhibition.

雄蛾、处女蛾和交配后雌蛾对各挥发物的反应有所差异,以处女蛾对各组分的反应最高,雄蛾次之。

With the characterization of NMR and IR, combining with the synthesis of active species and studies of their structures, it is suggested that the hydride [RuHCl(PPh3)3], being favorably formed in the acid media, exhibited higher activity in the reduction of the C=C bond, while the hydride [RuH4(PPh3)3], being preponderantly formed in the basic media, showed activity and higher selectivity towards the C=O reduction.

通过核磁、红外等表征手段,并结合可能催化活性配合物的合成和结构研究,推测了在非水介质中对C=C和C=O双键起到活化作用的催化剂活性物种和可能的选择加氢反应机理,即,催化剂[RuCl2(PPh3)3]在酸性环境下倾向于生成[RuHCl(PPh3)3]物种,该Ru-H物种对C=C双键加氢反应表现出较高的活性;而碱性环境下则易于生成[RuH4(PPh3)3]物种,该Ru-H物种对C=O双键加氢具有较高的催化活性。

While the basicity of the N-atom is stronger, more active second generation catalyst is indispensable and the temperature needs to be reached 150℃, and mixture of pyrrolidine and pyrrole was gained.

研究结果表明微波辐射条件下氮原子的碱性强弱对于二烯丙基胺发生关环复分解反应具有很大的影响:当底物的碱性比较强时,必须使用活性更高的第二代Grubbs催化剂,且温度需升至150℃反应才能顺利发生,得到光学纯吡咯啉和吡咯的混合物。

Results In the therapy group, most patients had taken ARV drugs for 4-8 months, which accounted for 78.24 % of the total number, with the adherence rate above 90% as 67.51 %. The main reason for the patients not listening to their doctor\'s advice was due to ART drug\'s side effects( 66.95 %), including queasiness, vomiting and tetter.

结果治疗组治疗时间在4-8个月的人数最多占78.24%,服药依从性达到90%~100%的占67.51%,停服和漏服药物的主要原因是不良反应占66.95%,最显著的不良反应是服药后引起的恶心、呕吐、皮疹等不适。

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