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The mechanism of PNPP catalytic hydrolysis has been proposed based on the analytic result of specific absorption spectrum.

通过对水解反应体系的特性吸收光谱的分析,表明在PNPP催化水解的反应过程中形成了由PNPP和Co配合物组成的关键中间体。

The formation cross sections of the complex between 〓 and quenchers were calculated by using collision complex model. It is found thatthe qualitative tendency of the formation cross sections of complex is inagreement with that of the measured quenching cross sections.

表明猝灭剂分子与〓可能经历了无垒反应过程。5 用碰撞络合物模型模拟了〓(0,4,0)与猝灭剂的碰撞猝灭过程,计算了〓(0,4,0)和一些分子体系的络合物生成截面并与实验猝灭截面相比较,发现计算结果与实验结果定性吻合。

Determination of Tyrosine in Urine Spectrophotometric Method;2. For chemical pre-extraction, MSTFA/TMSL derivatization reaction, GC/MS analysis, it is confirmed that two main metabolites (19-no-randrosterone and 19-noretiocholanolone) were found in nandrolone urine.

本文对合成的19-去甲雄烷醇酮的四个差向异构体混合物进行气相色谱分离,对诺龙和炔诺酮用药后,留取的人尿样通过化学预处理,MSTFA/TMSI衍生化反应,GC/MS分析,确证了尿样中诺龙的两个主要代谢产物为19-去甲雄酮和19-去甲原胆烷醇酮,炔诺酮的两个主要代谢物是四氢炔诺酮的两个形式,可能是3α-OH-5α-THINE和3α-OH-5β-THINE,在炔诺酮代谢前期,还发现有诺龙的上述两个代谢物存在。

It is discovered that there is a satisfied linear relationship between the experimental impact sensitivity and the activation energy of the ring breaking reaction.

首次提出并运用&取代基模型&(即将金属原子视为四唑环上的取代基、对金属配合物的处理采取与计算衍生物完全相同的模式)较为简便地计算研究了系列四唑金属配合物的热解反应,发现开环形成叠氮化物的活化能与它们的实验撞击感度之间存在良好的线性关系。

The B3LYP/6-31+G level of theory and the polarizable continuum model are employed to study the binding interactions between amidinium and tetrazolate anion which have two binding modes (side-on and end-on) as well as the binding interaction between amidinium and formate anion. We find, in the gas phase, that the end-on acetamidinium tetrazolate is more stable with its interaction energy 3.56 kJ/mol higher than that of the side-on.

采用密度泛函B3LYP/6-31+G 方法和自洽反应场极化连续模型研究四唑负离子与脒类正离子形成的两种形式的复合物及甲酸根负离子与脒类正离子形成的复合物在气相和二甲亚砜溶剂中的稳定性。

Behaviourists suggest that the child who is raised in an environment where there are many stimuli which develop his or her capacity for appropriate responses will experience greater intellectual development.

行为主义者认为,如果一个儿童在有许多刺激物的环境中成长,而这些刺激物能够发展其作出适当反应的能力,那么这个儿童将会有更高的智力发展。

Behaviourists suggest that the child who is raised in an environment where there are many stimuli which develop his or her capacity for appropriate responses will experience greater intellectual development.

行为主义者认为,如果一个儿童在有许多刺激物的环境中成长,而这些刺激物能够发展其作出适当反应的能力,那么这个儿童将会有上海中级口译翻译的智力发展。

A reagent, called the titrant or titrator[1], of known concentration and volume is used to react with a solution of the analyte or titrand[2], whose concentration is not known.

一种叫作滴定液的浓度和体积已知的试剂与未知浓度的被测物或被滴定物反应。

The POSS-based hybrids were characterized by FTIR,~1H-NMR,~(29)Si-NMR and UV. The POSS content in the hybrids were determined using three kinds of different methods and could be effectively controlled by varying the POSS feed ratio.4. It was estimated that about 5~8 vinyl groups in POSS participated in the copolymerization reactions by the ~1H-NMR spectra.

分别采用FTIR、~1H-NMR、~(29)Si-NMR和UV等方法对五个系列POSS基高分子材料进行了表征,证实POSS已与共聚单体发生了聚合反应;并通过红外标准曲线和紫外标准曲线以及核磁积分面积对共聚物中POSS的含量进行了计算,发现可以通过投料比来控制共聚物的组成。

However, another cause for loss of response to biologic therapies may be enhanced clearance in association with either neutralising or non-neutralising antibodies, particularly in seropositive RA patients.

血清蔗糖梯度表明抗体复合物也存在于两例不回应患者中。不同大小的抗体复合物,包括非常大的,在严重输液反应的不回应患者观察到。

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