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The optimized structures and energies of the reactants, intermediates, transition states and products of two reaction channels (corresponding to syn-acraldehyde and anti-acraldehyde) in gas or in methanol solvent were obtained. The potential energy profiles reveal the processes of the trimethylamine-catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde in gas or in methanol solvent at the microscope level.

通过研究,获得了三种情况下两种反应通道(分别对应于顺式-和反式-丙烯醛)中涉及的反应物、产物、中间体、过渡态的优化结构及其能量,并由此得到了反应的势能面图,在电子微观层次上揭示了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程。

In this sense, IDA plays dual effects, tridentate chelating to Cu(2) and bridgebetween two Cu(1) andCu(2).3 Metal complexes were selected as the appropriate for the study of cleavage plasmid pBR322DNA by gel electrophoresis technique. The results showed Ni and Mn complexes could cleave effect- ively DNA in the presence of H2O2 at physiological pH and temperature, whereas individual Zn complex could cleave effectively DNA.

通过电泳实验研究了一系列金属配合物与pBR322DNA的作用,发现在Tris-HCl缓冲溶液中,生理条件下,镍、锰配合物在共反应物H_2O_2存在下能够很好的断裂DNA,而Zn配合物单独作用就能够使DNA由ccc型转化为oc和linear型。

Glucose was gasified in various temperature, pressure and concentration of the reactant mixture. The results were analyzed carefully, and the effects of the parameters on the gasification were discussed and some key points were concluded.

选择纤维素这一原始生物质的主要成分作为原料,试验考察了改变温度、压力、反应物驻留时间、反应物浓度等条件对纤维素气化的影响,发现上述参数对纤维素的气化转化率和产品气体的组成有着显著的影响。

Recently, theoretical approaches to these reactions also indicated that often the reactants and products had ground states of different spin multiplicities, and the transformations of spin multiplicities occurs frequently in thermal reactions.

近年来,人们在研究这类反应的过程中还发现反应的基态反应物和基态产物通常有着不同的自旋态,整个热反应前后频繁出现自旋多重度改变的现象,即反应不遵守&自旋守恒定律&。

After the cold plasma has supplied the necessary energy for the dissociation of CH4 and CO2, syngas, higher hydrocarbons and oxygenates can be easily produced.

等离子体可以提供足够能量以分解反应物,一旦反应物被解离,合成气、含氧化合物及高碳烃都很容易形成。

Synthetic progresses of the sorbitol acetals in process routes, the molar ratios of aldehyde to sorbitol, the reaction temperature, the types and the amount of acid catalysts, the types of acromatic aldehyde, reaction solvents and purification methods of products were reviewed at domestic and aboard with 46 references.

讨论了缩醛反应机理。从反应工艺路线、反应物醛与醇物质的量比、反应温度、酸催化剂的种类和用量、芳香醛的种类、反应溶剂及产物的纯化方法等方面全面综述了国内外山梨醇缩醛类成核剂合成研究进展。

Light yellow nitrogen-doped nano-TiO2 powders were prepared by directly calcining the mixture of anatase TiO2 powders and guanidine hydrochloride in the muffle furnace at different temperatures.

以锐钛矿相纳米TiO2粉体和盐酸胍的混合物为起始反应物,通过在不同温度条件下对反应物直接进行热处理制得了淡黄色的掺氮纳米TiO2粉体。

Although many researchers have studied the synthesis of allyl phenyl ether by phase-transfer catalysis, no studies have used it in membrane reactor up to now. The purpose of this paper is to combine the studies of membrane reactor and phase-transfer catalysis. The membrane was used to stabilize the aqueous/organic interface at a fixed position, also the quaternary ammonium ion in the membrane was used as the catalyst to partake in the reaction system directly, and so it can also separate the product and reactants at the same time. A theoretical model is also presented.

中文摘要对於利用相间转移触媒催化技术来合成丙烯基苯基醚的反应,已有不少专家学者研究过,而至今还无在薄膜反应器中进行此反应之研究,本研究则是要结合薄膜反应器与相间转移触媒两者之特性,固定水油两相之界面,并且利用薄膜上的四级铵离子为触媒,直接在反应系统中参与反应,并同时分离产物及反应物,进而推导出相关之理论模型。

The paper has studied the influence of deluent contents,kinds of reactents,particle size of medal reductants and composition of carbon on the speed and temperature and the phase composition of combustion reaction during the process of SHS synthesis of WC-Al2O3 compound ceramic materials.

研究了WC-Al2O3复合陶瓷材料的自蔓延高温合成过程中,稀释剂含量、反应物类型、金属还原剂粒度,以及碳的配比含量对燃烧反应的速率、温度和燃烧合成物相组成的影响。

The invention uses the industry byproduct in production of sulfonation-process phenol or the byproduct (Na2SO3 content is 60-85percent) in production of p-cresol and sodium hydrosulfite to produce the aliphatic high range water reducer and takes acetone, formaldehyde, industry byproduct, sulphite or sodium pyrosulfite as raw materials and then sulfonation and condensation reactions are carried out in aqueous medium, the reactant weight ratio is acetone: formaldehyde: sulphite plus industry byproduct: water is equal to 1:2.5-4.5:1.5-2.6:4.0-6.0, the mass concentration of the condensation compound obtained is 30-42 percent, and the viscosity thereof is 20-100m.

本发明利用磺化法苯酚生产中的工业副产品,或者对甲酚和保险粉生产过程中副产品(Na 2 SO 3 含量在60~85%)生产脂肪族高效减水剂,采用丙酮、甲醛、工业副产物、亚硫酸盐和或焦亚硫酸钠作为原材料,在水介质中进行磺化和缩合反应,反应物的质量比为丙酮∶甲醛∶亚硫酸盐副产品∶水=1∶2.5~4.5∶1.5~2.6∶4.0~6.0,所得到的缩合物的质量浓度为30~42%,粘度为20~100m。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。