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Biocompatibility of tissue and material: All the materials used in operation were interstitial implant of titanium alloy. To the end of follow-up, there were no reaction of blood, immunization and tissue, no peplos formation or changes in cytoplasm, and no reaction of materials such as alloy corrosion and worn out.

材料与组织的生物相容性反应:术中所用材料均为钛合金体内植入物,与人体组织的生物相容性好,到随访结束时,无血液、免疫、组织等反应,无囊膜形成及细胞质的转变;亦无钛合金腐蚀、磨损等材料反应的发生。

On the other hand the proliferation activity of ConA-induced splenocytes was enhanced by polysaccharide fraction of Hoshouwu. In mucosal immunity, although polysaccharide fraction of Hoshouwu might not be an effective adjuvant, it enhanced IgM antibody production induced by Pneumococcus vaccine.

何首乌甲醇粗萃物促进自然杀手细胞活性和增强骨髓系造血反应,而何首乌高分子提升全身免疫作用的 T 细胞活性;肠道黏膜系统免疫反应方面,虽然何首乌高分子无法作为有效的佐剂,但可加强肠道病菌感染时的 IgM 抗体反应。

After extensive experimental studies,the optimum baking conditions were determined as follow:the molar ratios of potash feldspar powder and soda is 1.30,the baking temperature is 845℃,and baking time is 150 min.The optimum hyd...

对合成样品化学成分分析、X射线物相分析、红外光谱分析、扫描电镜分析表明,合成13X沸石分子筛结晶完好,性能优良,水热反应经由溶解水合反应和聚合浓缩反应两大阶段。

In chapter three,we investigated a new Baylis-Hillman-type reaction,organozinc speciesCF_3COOZnEt can react withα,β-acetylenic ketones and N-tosylated imines providing Baylis-Hillman adducts in good yield in the absence of any catalysts.

有机锌试剂CF_3COOZnEt可以与各种类型的α,β-炔酮及亚胺发生偶联反应,高产率的得到β-取代的Morita-Baylis-Hillman反应加合物,这类反应不需要任何的催化剂,产物具有立体单一型,完全是Z式结构。

In order to develop an useful synthestic process, we have synthesized amides with various substitutents. The isoquinoline skeleton was constructed through Bischler-Napieralski reaction, followed by asymmetric reduction of the imine intermediates with a Ru complex to form the only chiral center. Finally, we connected the two phenyl groups by Heck reaction and effectively obtained optically active aporphine alkaloids.

为了发展一套实用的合成方法,我们首先制备於苯环上具有不同种取代基的苯乙醯胺,接著透过Bischler-Napieralski反应进行分子内合环,并利用钌金属对亚胺中间体进行不对称的还原反应,建立出产物中唯一的光学活性中心,最后再利用Heck反应连结两个苯环,就可以顺利得到具有光学选择性的阿朴吩类天然物。

Some new results are obtained from the studies: 1 a novel thermokinetic research method, the characteristic reduced parameter method, has been proposed, and the kinetics of oxidation of benzoquinone by hydrogen peroxide has also been investigated with this method; 2 the kinetic mathematical models that the metallomicelles made from the mono-nuclear or dinuclear complexes and surfactants catalyze the phenolic derivant oxidation have been established respectively; 3 the feasibility and mechanism that the metallomicelle, a mimetic model of peroxidase, catalyzes the phenolic derivant oxidation has been discussed.

研究得到如下新的结果:(1)提出了一种新的热动力学研究法——特征对比参量法,用该法研究了过氧化氢氧化苯醌反应动力学;(2)分别建立了由单核和双核金属配合物与表面活性剂形成的金属胶束催化酚类氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

Fu Xiangkai Carbonylation reaction in biphase system is the important atomic economicreaction in the field of green chemistry.

含膦酸根等水溶性膦配体及其钯配合物的合成、表征和催化羰基化反应两相催化体系的羰基化反应是一类重要的绿色化学&原子经济型&反应。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物,通过&Click chemistry&,合成了具有1,2,3-三唑环结构单元的全氟环丁基类聚芳醚;利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应,制备了具有苯基氧膦结构单元的含氟聚芳醚;通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应,得到了具有PPO结构单元的含氟聚醚酰亚胺。

A satisfactory result was obtained in synthesis that using the material of high reactivity and high valence such as PPh3I*. The research area of material in electrosynthesis has been extended.

本文还重点研究了非水体系中不含酸性氢原料(I_2)的电化学反应机理,提出以电化学反应活性强的高价氧化态物质(如PPh_3I~+)作为阴极反应原料,在合成中取得了满意的结果,拓展了非水介质配合物电化学合成原料的研究和应用范围。

The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明,由丙烯脱氢生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处;基于此提出了较完整的丙烯氧化反应网络:丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H,生成烯丙基物种,该物种嵌氧生成σ-O络合物,脱氢得到丙烯醛前驱体,脱附生成丙烯醛;完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成;较低反应温度下丙烯氧化生成丙酮,通过烯醇式中间物种氧化生成丙酮前驱体得到。

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