反应物

Chapter three focuses on the application of the Baylis-Hillman adduct in organic synthesis and some new exploration was made.

第一章对钐试剂促进的有机反应和Baylis-Hillman反应在有机合成中的应用作了简要介绍；第二章研究了二碘化钐促进的还原消除反应；第三章研究了Baylis-Hillman加成物参与的立体选择性的转化反应。

It has been detected in a wide range of aerobe. The decomposition of hydrogen peroxide catalyzed by catalase is a bi- substrate enzyme-catalyzed reaction. As Chance proposed, it is an overall first-order reaction.

过氧化氢酶催化过氧化氢分解是一个两底物酶促反应，依照Chance提出的机理，反应速率方程具有一级反应方程的形式。

Through experiment, we have found that the combination of naphthol/sodium naphtholate is a high efficient bifunctional catalyst for direct aldol reaction.

通过实验，我们发现并筛选出了一组活性较高的β-萘酚和其钠盐双功能催化剂，该方法不需要预先活化Aldol反应的底物就能直接反应，且反应可在室温进行，条件温和，速度快，收率高达98%。

The material is titanium alligation implant and has good biocompatibility. Till the end of follow-up, blood, immune or tissue reactions were not found. No peplos or cytoplasmic change was seen. Besides, titanium alligation corrosion or abrasion did not appear.

材料与组织的生物相容性反应：术中所用材料均为铁合金体内植入物，与人体组织的生物相容性好，到随访结束时，无血液、免疫、组织等反应，无囊膜形成及细胞质的转变；亦无钛合金腐蚀、磨损等材料反应的发生。

Multistep deposition process has been adopted in the preparation of superfine inorganic composite antibacterial powder, Ag~+ as crystal nucleus, packed outside by the hydroxid and phosphate precipitate of Ti and Zr elements etc., The optimal process conditions have been found from one-factor influence tests and multi-factor orthogonal test,and the optimal process conditions were: Ag iron was imported by silver ammine, and then 100ml Titanyl sulphate solution mixing with zirconium sulfate keep hot at 90 ℃ for 30 mins, and the Zr/Ti ratio is 0.15,and Na_2HPO_4 was added in the end.

超细无机复合抗菌粉体的制备采用以Ag~+沉淀物作为晶核，外包裹Ti、Zr等金属的氢氧化物沉淀和磷酸盐沉淀物的多步沉淀工艺，并利用单因素和正交试验法对制备工艺进行了优化，其最佳工艺条件是：Ag~+以银氨络合物引入，沉淀钛锆的反应时间为0.5h，反应温度为90℃，水解反应时体系总液量为100ml、Zr/Ti为0.15，沉淀物经水洗、干燥，于700℃煅烧4.0h；即得最终产品。

Through screening of lipases, lipase Novozym435 was found to show the highest activity and enantioselectivity for the ammonolysis of CHBE. The effect of different solvents on the ammonolysis was investigated.

经过对脂肪酶及反应溶剂的筛选，确定最佳脂肪酶及溶剂分别为Novozym435和二氧六环；并在该反应体系中考察了温度、底物浓度、酶浓度与摇床转速对反应的影响。

High active enzyme was selected from several lipases which can catalysed the ammonolysis of unnatural sbstance trimethylsilylmethyl acetate.

从不同来源的脂肪酶中筛选出能催化非天然底物———乙酸三甲基硅甲酯的氨解反应且具有较高活性的脂肪酶，并首次探讨了氨源、有机介质、反应初始水活度和温度对该酶促反应的影

The results indicate that improving temperature to reflux, using low polarity solvent as dispersion medium and proper molar ratio of tetrabutyl titanate to stearic acid can bring out good modification. The function of tetrabutyl titanate is to react with the surface hydroxyl groups and adsorbed H2O on the powder particles to produce new binding sites such as M—O—Ti—OC4H9and M—O—Ti—OH, which can easily react with the carboxylic acid. As temperature increases from room temperature to reflux temperature, the reactions between RCOO- and Ti change from coordinate bonds to covalent bonds, which makes the carbon chains of stearic acids more strongly bound with the powder particles surface.

研究结果表明，提高处理温度、适当增加复合改性剂中硬脂酸的量并选用极性弱的有机溶剂可达到比较理想的改性效果；钛酸四丁酯的作用是与粉体粒子表面的羟基以及吸附水反应产生偶联点，如M—O—Ti—OH，这些偶联点易于与羧酸反应；在低温时RCOO-与偶联点的Ti之间以配合物的形式发生作用，在回流温度下处理时，主要发生酯化反应，使硬脂酸更牢固地嫁接到粉体粒子表面，改性效果更好。

In an acetate buffer of pH 6.0,and in the presence of CTMAB,a stable complex,having the mole ratio of 1 to 3,was formed between cobalt ion and nitroso R salt,which was concentrated on C18 solid phase extraction column,achieving a concentration multiplication of 100 times.

研究了用亚硝基R盐离子对固相萃取光度法测定钴，在pH 6.0的HOAc-NH4OAc缓冲介质中，溴化十六烷基三甲基铵存在下，亚硝基R盐与钴反应生成3∶1稳定络合物，该络合物可用C18固相萃取小柱富集，富集倍数达100倍，小柱上富集的络合物用乙醇洗脱后用光度法测定，钴的质量浓度在0.05~5.0 mg.L-1内符合比耳定律。

These complexes showed modest catalytic activity, and the PDIs of the polymers obtained were relatively broad.6. Reaction of CpjLn with MBMPHa in THF in 1 :1 molar ratio, isopropanol was added to the system in 1 equiv., after workup, a new kind of neutral lanthanide complexes [LnCw-OiPrXTHF2]2 Ln = La (14, Nd (15),Yb (16) were gained.

配合物cp3Ln与MBMPH：按卜1的摩尔比在THF中反应1小时，然后再原位按卜1的摩尔比加入异丙醇，合成了中性的桥联双芳氧基稀土烷氧基配合物 [L城犷0，P以THF2]2Ln=La(14，Nd(15)，Yb(16)，产物经红外光谱，元素分析和核磁共振氢谱(配合物14)等表征。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。