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By analyzing the molar fraction of St and MAh in the copolymers obtained from 〓C spectra, the copolymers obtained are proved to be strictly alternating structure, and sequence information obtained from DEPT experiments also verifies the copolymers with MSM sequence.

通过分析〓C NMR得到共聚物中St和MAh摩尔含量,证明共聚物具有严格交替结构,从DEPT实验中得到的结构信息表明共聚物只含有MSM序列。并且探讨了可控聚合反应的机理。

The structures of the trimetal bridging carbene complex 28 and the ion-pair bridging carbyne complex 31 have been further confirmed by X-ray diffraction studies.

在与羰基金属阴离子络合物PPN和Na的反应中,我们得到了桥卡宾碳键合氢的桥卡宾络合物,并对两个此类桥卡宾络合物进行了晶体和分子结构的研究。

Based on analysis of Wx of D4063-1, indica and japonica and according to the special sites of the three species, primers as markers-AUT4063-I were designed to distinguish D4063-1 from other rice. Combining with primer pair F5, dominant and codominant ways were established for discriminating them, and rapid and correct identification of D4063-1 from other rice could be done.

本研究还根据D4063-1和籼稻、粳稻的序列差异及D4063-1在该片段上的特征序列位点设计了用于识别D4063-1的寡核苷酸片段,并作为PCR反应的引物命名为AUT4063-1,将该引物与作者设计的扩增普通籼稻、粳稻Wx基因的引物F5配合使用,建立了识别D4063-1的显性和共显性两种检测方式的分子标记,为快速、准确鉴别低直链淀粉含量突变体D4063-1创造了条件。

The effects of the surfactants, trioctyl phosphine oxide, sodium dodecyl sulfonate and hexadecyl trimethyl ammonium bromide, on the extraction rate of Co^2^+ were investigated. The acceleration in the kinetics in contributed to the associated molecule~2 TOPO taking part in the extraction process directly. The decrement effects of SDS or CTMAB on the rate of extraction kinetics of Co^2^+ with HDEHP were also observed, which caused by the adsorption of molecules of SDS or CTMAB on the interface and decreased the interfacial adsorption amount of HDEHP. In addition, the extraction rate was reduced by a bigger margin in HDEHP-SDS system. This can be explained in terms of the formation of an electric field at the interface.

研究体系中加入不同表面活性剂所引起萃取速率的不同改变:三辛基氧化膦因与HDEHP形成可萃取的Co^2^+活性分子缔合物,降低了萃取过程活化能而使反应加速;十二烷基磺酸钠和十六烷基三甲基溴化铵因占据发生萃取反应的界面区,减小了HDEHP与Co^2^+反应的机会而使反应减速; SDS还因其在界面形成较强的负电场,造成Co^2^+的附加势能而使萃取速率有更大幅度的降低。

The temperature and the addition of surfactant can accelerate conversion and selectivity of reaction. Under the conditions of 200℃、0.38MPa、0.06 mol/L、t=4h,the conversion of hexene is 86.32%.Selectivity of 2-hexene and 3-hexene is 30.46% and 57.86%.

结果表明,当表面活性剂的加入以及反应温度的升高,能明显提高反应的转化率和选择性,在200℃、0.38MPa、0.032 mol/L的反应条件下,反应4小时底物转化率为86.32%,3-己烯的选择性为57.86%,2-己烯的选择性为30.46%。

It is shown that the reaction U+CO→CUO with a long-lived intermediate complex has no threshold energy, which agrees with the potenlial surface. When the collision energy is greater than 418.4 kJ/mol, the intercharge reaction increases, until the CUO molecule will decompose into U, C, O completely, and these reactions have threshold energy.

结果表明:在碰撞能低(15kJ/mol)时可以生成长寿命络合物CUO(X^3A),并且该络合反应是无阈能反应;碰撞能大于418.4kJ/mol后,先后出现置换产物UO和UC;随着碰撞能进一步增大,CUO分子将被完全碰散成U,C和O原子,而且反应U+CO(0, 0)→UO+C,U+CO(0, 0)→UC+O和U+CO(0, 0)→U+O+C是有阈能反应。

A novel biodegradable copolymer of poly and poly (γ-benzyl-L-glutamate) was successfully synthesized. Under appropriate conditions, the PBLG initiates the ring-opening polymerization of L-lactide to produce block copolymer, by using low toxicity stannous octoate as catalyst. The optimal reaction conditions were determined as follows; the catalytic agent: PBLG=1:1, the temperature is 120℃, the reaction time is 6h.

以L-丙交酯为原料,在催化剂辛酸锡酯Sn2的作用下,利用聚的活性端氨基引发LLA进行开环聚合,合成了聚L-丙交酯与聚的共聚物,对反应条件的各项因素进行了讨论,确定了最佳反应条件是:m:m=1:1;反应温度120℃;反应时间6h。

To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

In the second part, the cross-coupling reaction of organoboronic acid witharyl halide catalyzed by Pd has been studied, and the 〓 catalyzedcross-coupling reaction in organic phase and the 〓-TPPTS catalyzed reac-tion in water phase have been investigated also.

结果表明,无论是有机相催化反应还是水相催化反应,都得到了很高的转化率和产率。该反应条件温和,并且硼试剂和亲电底物上可以带各种官能团,适用范围极宽,是一个极有应用价值的反应。

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