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In this mechanism, a phosphine ligand in the Ru hydride complexes is replaced by protonic solvent ROH to generate the chain carrier.

三、反应机理论文提出,在固载Ru基催化剂上的scCO〓加H〓生成HCOOH的反应中,CO〓的活化在Ru配合物的作用下,以反插入Ru-H键,生成金属-羧酸配合物的形式进行。

In contrast to lung sequestration of neutrophil count,there were no transpulmonary gradient of MBE between left and right atrium after aortic declamping.

MBE或MBE总活性与术后炎性反应标记物如C反应蛋白及组织功能标记物如乳酸、肌酸磷酸激酶、丙氨酸氨基转移酶之间均无相关关系。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-bPCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过RAFT活自由基聚合方法制备聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终获得了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-b-PCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过可逆加成-断裂链转移聚合活性自由基聚合方法制备了聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终得到了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

The results showed that the optimum concentration of five important components i.e. Tag DNA polymerase, Mg2+, primer, template DNA and dNTPs in 25μL RAPD reaction system were 1.0u, 2.5mM, 20ng, 40ng and 0.2mM, respectively. The RAPD fingerprinting of five Japanese plum cultivars were established by using optimum reaction system with ten random primers.

结果表明:1、改良陈大明法是提取中国李叶片基因组DNA的适宜方法。2、以5′-GACCGCTTGT-3′为随机引物,建立了优化的中国李RAPD反应分析体系:25μL反应体系中,Taq酶、Mg~(2+)、引物、模板DNA和dNTPs 5种主要成分的适宜浓度或用量分别是:1.0u、2.5mmol·L~(-1)、20ng、40ng和0.2mmol·L~(-1)。

Results indicated that reaction moved according to de novo synthesis mechanism with the increase of oxidation ability of MFA, while increasing chlorinating ability moved reaction towards precursor formation mechanism.

结果显示,模拟飞灰氧化性的增强使反应向从头合成反应机制的方向移动,氯化性的增强使反应向前驱物反应机制反应方向移动。

The analysis results of FTIR , SEM, X-ray Diffraction and TG-DSC proved that,the existence of graft copolymerization between cassava starch and acrylamide was occured;the structures of cassava were destroyed during the copolymerizing; the structures of the copolymer were largely amorphous; within the range of 700℃,the thermal degradation process of the St-g-PAM was divided into three-steps, which was more complex than that of cassava.

FTIR、SEM、X射线衍射、TG-DSC分析结果表明木薯淀粉与丙烯酰胺已发生接枝共聚反应;木薯淀粉在接枝共聚反应中,结构被破坏,接枝共聚物的结构基本上为无定型结构;在700℃温度范围内,木薯淀粉丙烯酰胺接枝共聚物的热降解为三步降解历程,比木薯淀粉复杂。

The immunological traits such as titer,affinity,sensitivity and specificity of this mAb were characterized.The results showed that the conjugation ratio of SM to BSA in SM artificial antigen was about 25∶1.The titer of supernatant hybridoma cell lines of 3F9-C4 was 1∶3.2×10~2 by indirect ELISA.The isotypes in ascites was IgG_(2a)/κ,the affinity constant was 8.4×10~(11)L/mol,IC50 was 8.99μg/L,cross-reactivity to dihydrostreptomycin was 109.6% and little cross-reactivity to other compounds.

结果表明,BSA-SM人工抗原分子结合比为1∶25;筛选出3F9-C4敏感特异的杂交瘤细胞1株,间接ELISA测定细胞培养上清,效价为1∶3.2×102,同种型为IgG2a/κ;腹水的亲和常数为8.4×1011L/mol;IC50为8.99μg/L,与双氢链霉素交叉反应为109.6%,与其他SM结构相似物和功能近似物无交叉反应性。

The immunological traits such as titer, affinity, sensitivity and specificity of this mAb were characterized. The results showed that the conjugation ratio of SM to BSA in SM artificial antigen was about 25:1. The titer of supernatant hybridoma cell lines of 3F9-C4 was 1:3.2×10^2 by indirect ELISA. The isotypes in ascites was IgG(subscript 2a)/k, the affinity constant was 8.4×10^11L/mol, IC50 was 8.99μg/L, cross-reactivity to dihydrostreptomycin was 109.6% and little cross-reactivity to other compounds.

结果表明,BSA-SM人工抗原分子结合比为1:25;筛选出3F9-C4敏感特异的杂交瘤细胞l株,间接ELISA 刚定细胞培养上清,效价为l:3.2×10^2,同种型为IgG(下标 2a)/k腹水的亲和常数为8.4×10^11L/mol;IC50为8.99μg/L,与双氢链霉素交叉反应为109.6%,与其他SM结构相似物和功能近似物无交叉反应性。

Chemically pure elemental Al and CuO powder with an Al mass percentage of 20, 35, 57, 70 and 85 were milled respectively. The ball milled powders were analyzed by X-ray diffractometry and differential scanning calorimetry. When the amount of Al was under 20%, the reduction occurred only. When the amount of Al exceeded 20%, besides reduction, the synthesis reaction occurred simultaneously.

对Al含量在20%~85%范围内的Al/CuO进行高能球磨,采用X射线衍射进行物相分析,并对Al含量分别为20%和75%的试验分析了物相随研磨时间的变化,做了差示扫描量热分析,对比研究了固态还原反应与固态复合反应过程的异同。

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