反应物

A process for preparing the olefine sulfide includes addition reaction between sulfur monochloride and C3-C12 olefine under existance of low-carbon alcohol as catalyst to obtain addition compound, mixing it with C1-C15 haloalkane, sulfide of alkali metal, sulfur powder, and aqueous solution of emtrol, sulfurizing, dechlorinating, and refining.

一种硫化烯烃的制备方法，包括：(1)使一氯化硫和C 3 ～C 12 烯烃在低碳醇催化剂的存在下进行加合反应，生成加合物；(2)将(1)步的加合物与C 1 ～C 15 卤代烷、碱金属硫化物、硫磺粉、脂肪醇水溶液混合，进行硫化脱氯反应后，精制处理，得到硫化烯烃产品。

This invention carrying through alcoholysis of common gloss polyester chip, getting low-molecular polymer of polytetramethylene terephthalate, using this low-molecular polymer as pregnant liquor, doing esterification reaction and polycondensation reaction of PTA and hybrid diatomic alcohol in normal pressure, getting the modified copolyester product which has inherent viscosity of 0. 65-0. 85dl/g, fine pellucidity and is suitable in the application of engineering plastics.

本发明是通过对普通大有光聚酯切片进行醇解，得到对苯二甲酸乙二酯低聚物，以此低聚物为母液，在常压下使PTA与混合二元醇进行酯化反应和缩聚反应，制备得到了特性粘数在0.65-0.85dl/g且具有良好透明性的适用于工程塑料领域应用的改性共聚酯产品。

The influence of the behavior, mechanism, product structure and relation of structure with properties for co-curing reaction of epoxy resin and cyanate ester system catalyzed by transition metal acetylaceton, etc. was studied.

研究了用乙酰丙酮过渡金属络合物等促进剂催化促进环氧树脂与氰酸酯(在氰酸酯欠量，适量和过量条件下)的共固化反应行为、固化反应的机理、固化物的结构特征以及结构与性能关系。

During these years (1997-2000) in the research area of annonaceous acetogenins 5 natural products and a number of chiral-pure analogs of annonaceous acetogenins have been synthesized using sugars as the starting materials. Their high activity and selectivity against cell line of colon tumor and a relationship between activity and configuration have been found too. In the respect of inhibitor of sialidase two new methodologies for the synthesis of chiral-pure 3-deoxy-ulosonic acid using hetero-Diels-Alder reaction or asymmetric propargylation as the key reaction were developed. On the topic of anti-leukemia marine natural product clavulactone a synthetic method based on the free radical cyclization and starting from sugar has been developed. In other title of PKC inhibited agent sphingosine a new synthetic route with SN2' as the key reaction has also been disclosed.

项目期间（1997-2000）在番荔枝内酯方面从糖出发合成了五个天然产物和一批手性纯的类似物，它们对肠癌细胞有很高的活性和选择性，并与构型有关；在唾液酸酶抑制剂方面发展了二类全新手性纯高碳糖的合成方法－杂原子D－A反应或丙炔基不对称加成为关键的反应；抗白血病海洋天然产物群柱虫内酯方面研究了由糖出发和自由基环化反应的合成方法；对PKC 起抑制作用的鞘氨醇方面也开创了新的合成途径－由糖出发并以SN2'反应为关键反应。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下，以异丙醇作溶剂，苯硒酚与化合物2不反应。在氢氧化钾存在下，以异丙醇／水作溶剂（体积比20：1，在室温下，硒酚可以有效地进攻中化合物2中1，3，2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件，顺利实现了硒酚对N^1-（2-呋喃基）-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环，生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

A highly regio- and stereoselective diboration of allenes was achieved with a catalytic amount of phosphine-free Pd complex and alkenyl or aryl iodide.

双硼试剂加成到1，2双烯的反应，传统上利用Pt金属错合物为催化剂，根据文献的报导，单独只使用Pd金属错合物是无法进行此反应的。

Maturation feeding weevils displayed higher anemotaxis responses to -β- pinene, myrene and limonene than those of sexually matured weevils; whereas - carene, which was detected only in volatiles of trunk phloem, elicted more olfactory respones of sexually matured weevils than of maturation feeding weevils.

在华山松枝梢挥发物中含量较高的-β-蒎烯、月桂烯和柠檬烯引起补充营养期华山松木蠹象较大的趋向反应；在华山松树干韧皮部挥发物中含量较高的3--蒈烯则引起交尾产卵期的华山松木蠹象较大的趋向反应。

Four adduct compounds are found for the former, and three are found for the latter. This indicates the DNA adduct formation capabilities both of 2-chloro benzamide and the photoproduct sample. Meanwhile the result of Ames experiments of them is positive. Thus we should pay more attention to important meaning of these results since the compound, which can produce adducts with DNA, may possibly be tumorigen or even carcinogen and mutagen.

结果表明，前者与DNA反应形成四个可辨认的加合物斑点，后者与DNA反应形成三个可辨认的加合物斑点，能与DNA加合的物质为潜在的&三致&物质，同时，二者的Ames试验结果显阳性这应当引起人们对灭幼脲环境安全性的重视。

The effects of ,, and temperature on the distribution ratio have been investigated. The composition of the extracted species is determined by the methods of slope ratio, continuous variation,extraction isotherm curves and their chemical analyses. The extraction is found to proceed according to the reaction:AuCl_4 ~-+DEOTA_(0)TAuCl3 .DEOTA_...

着重研究了盐酸浓度、氯离子浓度、氢离子浓度和温度诸因素对萃取的影响；对有机相中金的反萃行为也进行了初探；通过斜率法、等摩尔系列法、萃取等温线法确定了配合物的组成；推定了DEOTA在盐酸体系中萃取金的机理为配位取代反应；计算了萃取反应的表观平衡常数和配合物的稳定常数。

Firstly,two novel rare earth complexes(CH_2=CHO)Ln~Ⅲ[2,6-_2PhNSiMe _3]_2Li_3Ln=Y(2,Yb(3)containing arylamido and enolate mixed ligands have been synthesized by treatment of 2 equiv of of 2,6-~iPr_2PhNHSiMe_3 with exces n-BuLi at -78℃in THF for 12h,followed by reaction with 1 equiv of LnCl_3at 80℃for 24h in one-pot.All the two compounds were characterized by spectroscopic methods,elemental analyses,and a single-crystal X-ray diffraction study.

首先，-78℃下，在两当量的2，6-~iPr_2PhNHSiMe_3(1)THF溶液中加入过量的n-BuLi，反应12小时，再加入一当量的LnCl_380℃下，反应24小时，一锅法合成了含胺基、乙烯醇基混合配体的新型稀土金属配合物(CH_2=CHO)Ln~Ⅲ[2，6-_2PhNSiMe_3]_2Li_3Ln=Y(2、Yb(3)，上述化合物结构经单晶X-ray衍射、光谱和元素分析表征，表明我们得到的是一类新型的三价稀土配合物。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。