反应物

It is existed competitiveness inhibition of 6APA, non-competitiveness inhibition of PAA and substrate inhibition of Penicillin on the hydrolysis of benzylpenicillin to 6APA and PAA by an immobilized penicillin amidase. The heat conductive coefficients were determined on the vacuum elevation liquid membrane concentration. The thermodynamics and kinetics of PAA extraction were studied on the organic solvent extraction of the above solution.

研究证明固定化青霉素酰化酶裂解反应是典型的底物、产物抑制酶反应，其反应动力学数据表明，青霉素、苯乙酸以及6APA对反应分别存在底物抑制、非竞争性抑制和竞争性抑制；真空升膜浓缩适应热敏性以及粘度不大的物系，对于6APA水溶液的真空升膜浓缩过程研究得到了浓缩实验的传热系数；浓缩液萃取主要是提取出其中的苯乙酸，本文测定了不同温度以及溶剂条件下的苯乙酸溶解度，并观测了苯乙酸萃取动力学。

According to the electrophilic substitution of α-Allocryptopin by ICl, it can be suggested that there are competitions of n-donors (such as N and O atom occurred in alkaloid or solvent molecules) with the conjugated π system in alkaloid molecule for iodine monochloride when charge-transfer complexes are formed, which may block the formation of pre-reactive π-complex intermediate, and thus suppress the electrophilic substitution.

这一方法标记过程简便，标记产物富集于有机相，易于进一步纯化，其放射化学纯度接近95%，标记率超过70%；ICl与α-别隐品碱的亲电碘化反应结果表明，生物碱底物或溶剂分子中的N、O等n电子给体可能与亲电试剂形成电荷转移络合物，竞争芳香亲电取代反应π络合物反应前体的形成，从而抑制碘化反应的发生。

A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials of the subcomponents excluded when preparing the pre-reaction material with the obtained reacted material to obtain a dielectric ceramic composition.

本发明提供一种介电陶瓷组合物的制造方法，其中介电陶瓷组合物以特定的比例含有如下成分：含有特定组成的介电体氧化物的主成分，该主成分可以提供具有优异的低频率介电特性的、绝缘电阻的加速寿命进一步提高的耐还原性介电陶瓷组合物的制造方法，含有V氧化物的第1副成分，含有Al氧化物的第2副成分，含有Mn氧化物的第3副成分，以及含有特定的烧结助剂的第4副成分；该方法包含如下工序：将至少除去第3副成分的原料和第4副成分的原料的一种或两种的其它副成分原料的至少一部分，与为了得到主成分原料而准备的起始原料混合，准备反应前原料的工序；使准备的反应前原料反应而得到反应后原料的工序；以及在所得的反应后原料中，混合在准备反应前原料时除去的副成分原料，得到介电陶瓷组合物原料的工序。

At present,the rate laws and reaction mechanisms of pyrite oxidation,pyrite and chalcopyrite formation,uraninite and magnetite dissolution in aqueous solutions are mainly studied,and it is discovered that (1)oxidation rate of pyrite controlled by surface reaction assume fractional dependence on Fe3+ and O2 molalities in acid solutions;(2)Pyrite cannot nucleate directly from solutions below 300 ℃,it can only form initially through sulfidation of a FeS precursor. The rate equation of reaction between FeS and H2S to form pyrite is of the second order;(3)Chalcopyrite is formed by reactions of pyrrhotite or pyrite with Cu2+,the former proceeds via a series of mediate metastable phases of Cu-Fe sulfide,whereas the rate equation of the latter is apparently of the first order which is controlled by surface reaction;(4)The nonlinear behavior of magnetite dissolution at acid pH can be represented by a shrinking core model coupling with surface reaction and diffusion transport.

目前主要研究了水溶液中黄铁矿氧化、黄铁矿和黄铜矿形成、晶质铀矿和磁铁矿溶解的速率定律和反应机理，发现：(1)酸性溶液中黄铁矿的氧化速率对Fe3+和O2浓度呈分数依赖并受表面反应的控制；(2)低于300 ℃时黄铁矿不能从溶液中直接成核，而需初始地通过FeS先驱物的硫化生成，FeS与H2S反应形成黄铁矿的速率方程为二级；(3)磁黄铁矿或黄铁矿与Cu2+反应均可形成黄铜矿，前者经历了一系列准稳的Cu-Fe硫化物的中间物，后者的速率方程为表观一级并受表面反应的控制；(4)酸性pH时磁铁矿的非线性溶解行为可采用表面反应扩散输运耦合的收缩核模型来描述。

The results show that isobutene oligomerization is fast liquid-solid reaction. Under the temperature of 80 ℃～120 ℃ and pressure of 2.0 MPa, the products of oligomerization are mainly dimers and trimers of isobutene. The yield of trimers is higher than that of dimers and the mass fraction of trimers decreases with reaction temperature increasing. The yield of tetramers is much lower than that of dimmers and trimers. The tetramers are formed by reaction of isooctenes and C8 carbonium ion.

结果表明，异丁烯齐聚反应为快速液固相催化反应，在80 ℃～120 ℃，2.0 MPa的实验条件下，反应产物主要是异丁烯的二聚物和三聚物，且三聚物的收率远高于二聚物，两者的浓度比值随反应温度的升高而下降；少量四聚物的生成主要源于碳八烯烃与碳八正碳离子的反应。

These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

Firstly, a series of organic molecules which use phthalimido group as electron acceptor, N as electron donor, COO~- as eletrofugal group were synthesized based on SET-promoted photocyclization processes. These compounds were irradiated by 500 W ultraviolet under nitrogen atmosphere in room temperature. After filtration of the photochemical character of these molecules, substrate S1 and S2 were selected as appropriate model reactants. Secondly, the monosubstituted derivatives at the 6-position ofβ-cyclodextrin were synthesized as chiral template of photocyclization.

首先，以单电子转移机理为指导，设计了一系列以邻苯二甲酰亚胺基为电子受体、N为电子给体、羧基为离去基团的光环合反应底物，这些化合物在氮气保护下以500瓦紫外光室温下进行光照反应，对这一系列的分子的反应情况进行了研究与筛选，最终选择底物S1和S2作为研究光环合反应中立体控制方法的模型底物；其次，又合成了一系列6-位单取代β-环糊精，以此作为光环合反应的手性模板。

It is prepared from titanium tetrachloride carried on an alcohol carrier that Mg and Li chlorides with molar ratio of 1:(2-20) are dissolved in alcohol, and by: co-dissolving Mg chloride and Li chloride in a low carbon alcohol and stirring at high speed in an inert medium to form micro-particles; reacting the said alcohol with titanium tetrachloride twice, adding organic acid polyester at first time, washing out uncarried titanium tetrachloride, and drying to obtain powdery pruduct.

它是由四氯化钛负载于将氯化镁和氯化锂共溶于醇形成的醇合物载体上组成，其中氯化锂与氯化镁的摩尔比为1∶2～1∶20。这种主催化剂组分的制备有两个步骤：(1)无水氯化镁和氯化锂共溶于低碳醇中形成醇合物，并在惰性介质中高速搅拌形成醇合物微粒；(2)醇合物与四氯化钛进行两次反应，其中第一次反应时加入有机酸多元酯。反应结束后用惰性溶剂洗去未负载的四氯化钛，干燥后得到呈粉末状的主催化剂组分。

Conductivity of Polyoxyethylene/Poly (2-vinyl pyridine)Blend and Compatibilizing Effect of Lithium Perchlorate;2. Graft terpolymerization of polyoxyethylene macromer with acrylates;3. Then multiblock copolymers was obtained by condensing polyoxyethylene and poly(2 vinylpyridine)with dichloromethane in the presence of potassium hydroxide.

甲基萘锂作为引发剂利用阴离子聚合得到 2 乙烯基吡啶的遥爪双羟基低聚物(P2VP)，然后以二氯甲烷作偶联剂与聚环氧乙烷反应制备P2VP和PEO多嵌段共聚物，考察了反应时间对偶联反应的影响，并对共聚物进行了IR和1H NMR表征，由1H NMR谱的积分曲线得到了共聚物中PEO链段质量分数。

The esterification reaction was carried out in isooctane solvent at 50℃, with 0.15mol/L of substrate and 1:1.4 of acid-alcohol molar ratio.

研究了反应温度、溶剂、底物浓度、底物摩尔比、吸水剂用量等因素对酯化反应的影响，确定了正戊酸异戊酯的最佳合成条件为：反应温度为50℃，异辛烷为反应介质，底物浓度为0.15mol/L，酸醇摩尔比为1：1.4。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。