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It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节,以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料,合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂,并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征;首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应,详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能,用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性,并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

Nanosized zinc carbonate prepared by the method of microemulsion has shown good disper- sion, narrow distribution and light agglomeration.

分别改变表面活性剂和反应物的浓度,制备出了1号、2号和3号纳米碳酸锌。

The results show that the composite is dense and silicon particles are distributed uniformly. Transmission electron microscope observations show that stacking faults with high density, twins and dislocations are found in silicon particles. The Si-Al interfaces are well-bonded and no interface reactants are found. The dislocations and eutectic silicon precipitates are observed in LD11 matrix. Sip/LD11 composite has low density of 2.4 g/cm3, low coefficient of thermal expansion of 8.1×10-6/K, high thermal conductivity of 161.3 W/, and the annealing treatment can reduce the CTE and improve the thermal conductivity.

研究结果表明:复合材料组织致密,颗粒分布均匀;透射电镜观察发现,在Si颗粒内部存在高密度的层错,同时还存在孪晶和位错; Si-Al界面结合状况良好,无界面反应物; LD11铝合金中存在位错和析出的共晶Si;复合材料具有低密度(2.4 g/cm3),低热膨胀系数(8.1×10-6/K),高热导率161.3 W/(m·K的特性,可以通过退火处理进一步降低其热膨胀系数,提高热导率。

Softening point of the product is significantlyhigher than that of the product (64℃) without initiator.

其软化点明显高于未加引发剂的α-P与MA的反应物软化点(64℃),表明前者的聚合度明显高于后者。

Two-way matrix of kinetic-spectroscopic data is obtained after measuring a series of absorption spectra during the process of chemical reaction.

针对化学反应动力学谱-吸收光谱组成的两维数据,提出了以优化速率常数而消去反应物波谱信息为减秩手段的速率常数-秩分析法。

The ion mobility was measured at different temperatures and the effects of the temperature in drift tube on the variety and yield of the reactant ions and product ions were discussed.

离子迁移率、反应物离子的种类和产量与漂移管工作温度有很大的关系。

The ion mobility was measured at different temperatures and the effects of the temperature in drift tube on the variety and yield of the reactant ions and product ion s were discussed.

本研究在不同温度下进行了离子迁移率实验,结果表明,离子迁移率随温度的升高而增大,而提高工作温度可以减少水分子对产物离子的影响,有利于改善系统检测的分辨率;选择合适漂移管工作温度,能有效地增加反应物离子的产量,从而提高系统检测的灵敏度和选择性。

The results show that the ion mobility increases as temperature rises; the influence of water vapor on product ions was reduced and the system resolution was enhanced at a higher temperature. In addition, the reactant ion yield can be effectively increased by choosing a proper temperature in drift tube, and improves the sensitivity and selectivity of system.

本研究在不同温度下进行了离子迁移率实验,结果表明,离子迁移率随温度的升高而增大,而提高工作温度可以减少水分子对产物离子的影响,有利于改善系统检测的分辨率;选择合适漂移管工作温度,能有效地增加反应物离子的产量,从而提高系统检测的灵敏度和选择性。

Ion mobility spectrometry ; ion mobility ; drift tube ; reactant ion ; product ion

离子迁移率谱;离子迁移;漂移管;反应物离子;产物离子

The acceleration of chemical reaction with the radiation of microwave is caused by not only the dielectric heating,but also the athermal action.

微波加快化学反应速度除了微波对反应物的加热以外还有非致热的作用。

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