反应作用

We discuss the mechanism of trimerization of nitriles catalyzed by organolithium compounds and study the catalystic characteristics. Using this new method, the yield of triazines is greatly improved.

另外，实验探讨了有机锂化物对芳香腈三聚反应的催化作用，得到了较高的产率，同时，研究了它的作用机理和催化性能。

Reaction of 9-bromofluorenewith diethyl malonate and sodium carbonate gives diethyl 2-(9-Fluorenyl)malonate.Aminolysis of diethyl 2-(9-Fluorenyl)malonate in ethylenediamine and propylene diamine give〓 and 〓, respectively.〓 and 〓 were synthesized by the reaction of 9-bromofluorene with oxalyl bisethylenediamine. Copper and nickel complexes of 〓 and 〓 were obtained by the reaction of 〓 and 〓 with copper and nickel salt, respectively, in aqueoussolution and extrusion of two hydrogen ions from the amide groups.

使9-溴芴与丙二酸二乙酯在无水碳酸钠存在下反应合成出2-(9-芴基)丙二酸二乙酯。2-(9-芴基)丙二酸二乙酯在乙二胺中胺解得到配体〓，2-(9-芴基)丙二酸二乙酯在1，2-丙二胺中胺解得到配体〓，使9-溴芴与草酰二乙二胺作用得到配体〓和〓与相应的金属盐作用分别得到它们的铜、镍配合物。

Also the performance of this modified electrode was compared with sodium molybdate modified platinum electrode. The cyclic voltammetry tests show that phosphomolybdic acid modified platinum electrode can increase the catalytic activity for methanol oxidation and it is almost the same as the mono-molybdate (Na2MoO4) modified Pt electrode does. This promote effect mainly comes from the transformation of different valency of molybdenum.

通过循环伏安和计时电流法研究了该修饰电极对甲醇氧化的电催化活性和抗中间产物的毒化作用，并比较了该修饰电极与其单酸盐(Na2MoO4)修饰铂电极的性能，测试结果表明：磷钼酸修饰铂电极能够提高对甲醇氧化反应的催化活性，基本上同其单酸盐Na2MoO4修饰铂电极的催化活性相当，并且这种促进作用主要是由Mo原子价态变化引起的。

We have presented a practical method for the preparation of propargylic alcohols from terminal alkynes and carbonyl compounds promoted by KOH in the presence of 18-crown-6,and subsequent efficient cyclizations of propargylic alcohols with 2-naphthol catalyzed by InCl_3·4H_2O under the solvent-free ball-milling conditions.Ball milling exhibits its superiority over the reported methods in the preparation of propargylic alcohols and naphthopyran derivatives.

采用机械研磨方法进行了连续的两步固相化学反应的研究：首先，在氢氧化钾和18-冠-6的作用下，端基炔和羰基化合物在机械研磨条件下反应可以高效地生成相应的炔醇化合物；其次，在四水合三氯化铟的催化作用下，生成的炔醇化合物和2-萘酚在机械研磨条件下环加成生成相应的萘并吡喃产物。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst. The effect of the internal quaternary ammonium and/or pyridiniumsalt on the epoxidation of substituted chromenes is similar to that of the externalpyridinium salts and ammonium halides.

分子内季铵盐和吡啶盐具有相转移能力，对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似，使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

Berberine is mainly used to treat major used in enteric bacterial infection,recently,researches showed that Berberine can not only be used to treat cardiovascular disease,endocrine disease,nutritional and metabolic disease,central nervous disease,tumors,but also can improve immune function and anti-graft rejective reaction of skin besides its antibacterial action.

黄连素在临床上主要用于治疗肠道细菌感染，但大量研究和临床应用表明，黄连素除了有抗菌作用外，还可用于治疗心血管疾病、内分泌、营养及代谢疾病、中枢神经系统疾病、肿瘤等疾病，同时具有增强免疫机能及抗皮肤移植排斥反应等作用。

The binding interaction of DNA with the di-iron complex 〓, designed as a model for the di-iron active site in mammalian purple acid phosphatase , are examined firstly and spectroscopically.

对所有研究的含有双核铁、双核锌及双核铜的配合物促进DNA双链水解断裂的反应性进行比较，我们发现要有效地水解断裂DNA双链，对DNA骨架的磷酸基氧原子有一定配位作用的双核金属离子是必要的，因为两个金属离子间存在协同作用，这与有关的天然酶类似。

So our work is further to study the characteristics of DOX-induced cardiotoxicity with proteomics and metabonomics, combined with conventional toxical technologies, so as to exploring the unknown toxicity targets and selecting biomarkers to detecting the adverse effects.

为了深入了解DOX心脏毒性的作用机制、寻找新的毒性作用靶标及合理选用生物标志物以监测其不良反应，本研究拟将代谢组学技术和蛋白质组学技术与传统毒性评价技术相结合，研究DOX心脏毒性的特征。

To elucidate the possible mechanism of differentiation and /or apoptosis in NB4, K562 cells induced by tributyrin, a histone deacetylase inhibitor, the level of acetylated histone H3 was detected by Western blot, p21~ WAF1expression was detected by semi-quantitative RT-PCR.

为了探讨组蛋白去乙酰化酶抑制剂三丁酸甘油酯(tributyrin，TB)诱导NB4、K562白血病细胞分化和凋亡的作用机制，利用Westernblot方法及逆转录聚合酶链反应检测TB作用前后NB4、K562细胞组蛋白H3乙酰化水平以及p21WAF1表达量的改变。

Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车，和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特，那个是爱朗。