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In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions(0-D chain); complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物,并用X-射线单晶结构分析方法确定了晶体结构,分别为: [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构;配合物2借助水分子形成一维链状结构;配合物3、4、5、6是以H4btc为第一配体、phen为第二配体,通过水热法合成的配合物,其中,Co2+、Ni2+、Cu2+为中心离子;配合物3中的二价钴离子具有相同的配位环境,不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境,在配合物4中,一维链通过H4btc上的羧基形成一个二维层结构;配合物5、6是借助H4btc上的羧基形成的一维链状结构;配合物7、8属于异质同晶结构,它们的分子通过分子间氢键形成三维网状结构,H4btc上的羧基失去2个质子,作为一个二价负离子起到电荷平衡作用。

The results showed that there were differences between adaption and regulation of different wheat varieties by prophyl dihydro jasmonate, so as to show diversity of gas exchange parameters, such as photosynthesis, water usage, etc. There was no evident difference between the reaction of two spring wheats (Jinchun1 and 1608) and the winter wheat (Xiaoyan 22) to PDJ. Different parameters of different wheat varieties had inequable reaction to different concentration of PDJ. Photosynthesis rate, water use efficiency and stomatal limiting value were enhanced when PDJ concentration reached a high degree. At the same time, leaf transpiration rate and stomatal conductance decreased. Therefore, wheat could maintain normal physiological activities while environmental conditions were changed.

结果发现,面对类似激素双氢茉莉酸丙酯调控下的不同品种小麦适应与调节存在差异,从而导致光合和水分利用等气体交换参数的表现也存在差异;两种春小麦(金春1号、l608)和一种冬小麦(小偃22)之间对PDJ的反应没有明显的冬春性间的差别;对不同品种、不同参数,PDJ起到作用的浓度不同,但无论如何PDJ都有相同的作用,当这种激素达到一定的浓度后,就会增强小麦的光合速率和水分利用率,增加气孔限制值,降低叶片的蒸腾速率和气孔导度,从而在外界条件变化时保持体内水分、延缓气孔关闭,维持体内正常的生理活动。

Alexander has demonstrated an iodide peroxidase in animal thyroid tissue and believes this enzyme is responsible for the iodination reactions through formation of an oxidized iodinating intermediate.

Alexander已经证明在动物甲状腺组织中有一种加碘过氧化物酶,并相信该酶对加碘反应起作用,它是通过形成一个氧化态的碘中间体而起作用。

The way to prepare iodomethane using methanol, potassium iodine and acid as regents has the disadvantages such as many side reactions and low yield, while the synthesize route from dimethyl sulfate and potassium iodine has the advantages of high yield and simple separation.

醇与氢卤酸作用是制备卤代烃的常用方法,以甲醇为试剂,以碘化钾与酸作用生成氢碘酸制备碘甲烷的方法存在副反应多、收率不高的特点;而以硫酸二甲酯及碘化钾为试剂的合成路线具有操作容易、收率高、纯化简单的优点。

At first, urea decomposed into isocyanic acid, which interacted with ZnO to form a relatively steady isocyanate species. Then propylene glycol reacted with isocyanate species to form hydroxypropyl carbamate, and the HPC lost ammonia to form PC.

结果表明,该反应是分步进行的,首先尿素分解生成氨气和异氰酸,异氰酸与ZnO作用形成异氰酸物种,在丙二醇的作用下生成中间产物羟丙基氨基甲酸酯,然后由HPC脱氨气生成PC。

Gel-type cross-linked polystyrene-isocyanuric acid resin has been obtained by reaction of chloromethylated polystyrene with isocyanuric acid under the existence of triethylamine.

由氯甲基化低交联聚苯乙烯和异氰尿酸在三乙胺作用下反应,制得了凝胶型交联聚苯乙烯-异氰尿酸树脂,测定了该树脂对苯酚和间苯二酚在不同温度下的吸附等温线,依据Clapeyron-Clausius方程从吸附等温线计算出了吸附热,从热力学的角度论证了树脂是基于氢键键合和疏水作用而吸附苯酚和间苯二酚的。

Jinake has the synergic effect to chemical drugs in the treatment of cancer shch as malignant lymphadenoma.

金艾康具有对化学药物治疗肿瘤增效作用,其作用机理可能是逆转MDR,并能降低化学药物引起的如消化道反应与肢端麻木症状等毒副作用。

Properties : White crystallization or powder , proportion 1.735 , melting point is 287 ℃, apt to dissolve in water , ethanol and propanone , aqueous solution is neutral , turn into the blood red sulphur cyaniding iron with molysite , reactionless with inferior molysite, salt function turns into dark blue sulphur cobalt cyanide, turn into white sulphur silver precipitating or black sulphur copper cyanide cyanide to precipitate with the silver salt or copper salt function with cobalt.

白色结晶或粉末,比重 1.735 ,熔点 28 7 ℃,易溶于水、乙醇和丙酮,水溶液呈中性,与铁盐生成血红色的硫氰化铁,与亚铁盐则无反应,与钴盐作用生成深蓝色的硫氰化钴,与银盐或铜盐作用生成白色的硫氰化银沉淀或黑色的硫氰化铜沉淀。

The results showed that monocarboxylic acid stearic acid played a role of surfactant, and the product was still orthorhombic Ce2O(CO3)2·H2O with a high crystallization degree. In turn, duality-carboxylic acid tartaric acid...

实验结果表明在尿素及硝酸铈的混合溶液中分别加入一元羧酸硬脂酸,二元羧酸酒石酸和三元羧酸柠檬酸时,一元羧酸硬脂酸在混合溶液中只起表面活性剂的作用,其产物为斜方晶系的单晶Ce2O(CO3)2.H2O微粉,且表面活性剂硬脂酸的加入使得晶体的晶化程度明显提高;而二元羧酸酒石酸与三元羧酸柠檬酸在均相反应中则起螯合剂的作用,分别与Ce3+形成螯合物酒石酸铈和柠檬酸铈,这些结果的造成是由于其反应机理的不同所导致的。

Qingkailing effective composition can prevent ischemic injury through various neurotrophy mechanisms during the early period after ischemia.

黄芩甙、栀子甙的作用在于促进Ast的反应性增生,而胆酸、珍珠母水解液、合方则表现为对Ast功能活化的促进作用。

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