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反应作用

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According to the Box-Benhnken design principle,the method of response surface method with 3 factors and 3 levels was used. The factors influencing the technological parameters were determined by means of regression analysis. Response surfaces were finally graphed with the yield as the response value. The synthesis conditions were optimized as follows:reaction reagent was NBS,stoichiometric proportion between NBS and anhydrovinblastine was 1.07; the dosage of TFA was 22 mL/L; reaction temperature was -68 ℃ and duration was 90 min.

在单因素实验基础上,根据Box-Benhnken实验设计原理,采用三因素三水平的响应面分析法,研究了各个因素及其交互作用后,得到了合成7′-Br-脱水长春碱的最佳工艺条件:以二氯甲烷为溶剂,采用NBS为溴代剂,其用量与底物的物质的量比为1.07∶1,TFA的加入量22 mL/L,在-68 ℃下反应90 min,终止反应后,得到卤代产物。

Steps of the invention are that an agitator in a main reaction region is started while water enters to implement the nitrification process under the hypoxic condition. When a maximum value appears on a pH value curve and an inflection point appears on an ORP curve, the stirring is stopped. When the last stirring stage is stopped, oxygen is added in the mixture for the degradation of organic compounds and the nitrification of nitrogen compounds. When a minimum value appears on the pH value curve, the aeration is stopped. The steps are repeated till the water inletting stage is finished. And an aerobic aeration stage is taken as an ending stage of a reaction period.

本发明步骤:进水同时开启主反应区搅拌器,进行缺氧条件下的反硝化过程,当pH值曲线上出现极大值且ORP曲线上出现拐点停止搅拌;上一搅拌阶段停止后,向混合液中供氧,进行有机物的降解和含氮化合物的硝化作用,当pH值曲线上出现极小值停止曝气;重复以上步骤,直到进水阶段结束,并以好氧曝气阶段为反应期的结尾阶段。

The results indicate that the relative atom content of Nd islow contrasted to that of Fe, which results from the weak competitive reaction ofNdCl〓 because of the strong bulk effects. The results of x ray photoelectronspectroscopy reveal that other valence of Fe could be in NdCl〓-FeCl〓-GIC.It is considered as the result of the charge shift between FeCl〓,〓 and graphitein intercalating process. Structural model of RECGIC was supplemented after thinking of the chargeshift between the intercalates and graphite. The characteristic layer distance, I〓, ofstage-1 RECGIC were calculated by the model.

利用能谱分析测定了NdCl〓-FeCl〓-GIC中插入剂的含量,结果表明, Nd的相对含量低于Fe的相对含量,这是因为NdCl〓的空间效应较大,而致使其竞争插入反应处于劣势的缘故。X光电子能谱研究表明,Fe可能有其它价态存在,这是由于在插入反应过程中,FeCl〓、NdCl〓以及石墨间发生电荷转移等作用的结果。

The endolymphatic sac contains immunocompetent cells capable of processing and presenting viral or bacterial antigen, potentiating the immune response, attacking the invaders directly or attacking infected cells, and developing immunoglobulin responses in situ.

本研究拟探讨DC是否参与了内耳的免疫反应,在内耳的这种反应中神经免疫和自身免疫与细胞免疫之间有相互影响,这种影响对内耳的形态和功能是否有保护作用。

The conducting wall in micro-tube preheats the inlet mixture by axial heat transfer. The existence of conducting wall will help to reach full reaction in the micro-tube. As the inlet velocity increases, both the existence of the surface catalytic combustion and the gas phase combustion become the limiting factors on combustion. Wall material and equivalence ratio of hydrogen/air mixture have important influence on catalytic combustion of hydrogen.

计算结果表明:表面催化反应对空间气相反应有抑制作用;在微型管道内,通过导热壁轴向间的传热,预热入口混合气体,使氢气燃烧更加充分;随着入口速度的增大,燃烧过程同时存在着表面催化反应和空间气相反应两种控制因素;管壁材料和当量比对氢气的催化燃烧过程有重要的影响。

The models of the ear swilling of mice and paw edema of rats were adopted to assay anti-inflammatory effect. Results 5-ASA(ig,75,150 and 300 mg.kg-1,for 3 d)significantly reduced the ear swelling of mice and the paw edema of rats and also decreased the writhing. 5-ASA at the dose of 300 mg.kg-1 ig,prolonged pain latency on hot-plate reaction.

结果 5-ASA片剂3种剂量(75、150及300 mg.kg-1,ig×3 d)对二甲苯诱导的小鼠耳肿胀度及蛋清诱导的大鼠踝关节肿胀度均有明显抑制作用;以上剂量还可明显抑制小鼠扭体反应,大剂量还可延长小鼠热板的舔足反应潜伏期。

Reactive Red 195(RR 195) and C.I. Acid Black 234(AB 234) in the presence of H2O2. The catalytic function of Fe-AO-PAN on dye degradation was investigated with respect to decoloration percentage in this work.

活性红195(RR 195)和C.I。酸性黑234(AB 234)的光催化氧化降解反应中,考察了其对降解反应的催化作用。

Wereport the synthesis of an alkyl imidazolium salt supported pyrrolidine amide organocatalyst L-1 and its use and recycling in Aldol condensation reaction.

在这里,我们小组报道了用脯氨酸为原料合成了一种双官能团的离子液体接枝的新型有机催化剂并应用于Aldol缩合反应,它和脯氨酸具有相似的催化作用,可以有效地促进反应的进行。

In order to study the aldol condensation of 2.15-hexadecanedione on the surface of aluminium, the intermolecular condensation mechanism of acetone occurring on aluminum was simulated by using semi-empirical AM1 method embodied in MOPAC 6.0 program package. The optimized structures and geometry parameters of 5 transition complexes and 4 intermediates were given.First, 2 molecules of acetone coordinated with aluminum by electrostatic attraction.One atom of hydrogen of acetone migrated to aluminum because of t...

为了研究2,15-十六烷二酮在氧化铝表面的环合机理,选择小分子丙酮为模型化合物,用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理,给出了反应过程中的5个过渡态和4个中间体的结构和几何参数,该催化反应可以认为是氧化铝分子与两分子丙酮分子发生静电络合作用,然后借助氧原子的负电荷导致脱氢并实现缩合,根据中间体的能量变化,推测有较稳定的铝复合物生成。

The main species of the antimony catalysts are antimony trioxide, antimony acetate and the recent widely concerned ethylene glycol antimony.

此外,用于酯交换反应的锰、锌、钙、钴、铅等金属的醋酸盐对缩聚反应也有一定的催化作用。

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