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反应作用

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The comparison of hydrolysis-polycondensation reaction and microstructure of ORMOSILs derived by TEOS, MTES, VTES, ETES confirms that the influence of organic group such as methyl, vinyl, ethyl and ethoxyl on the hydrolysis and polycondensation reaction rate depends on several factors including electron-donating capability, size and number of ethoxyl group which can participates polycondensation reaction.

确认甲基、乙烯基和乙基和乙氧基等改性基团对硅醇盐水解-缩聚反应速度的影响是取决于有机改性基团的电负性、尺寸和可水解的-OR基团数目等因素综合作用的结果,其水解速度依MTES>TEOS>VTES>ETES的顺序递减。由于Si原子上可聚合的基团数目减少,导致MTES、VTES和ETES的聚合反应速度降低,而与水解速率失配。

After esterification, the ethyl-2-chloro-3-phenylpropionate reacts with diethyl malonate under the catalysis of sodium ethylate, and we obtain the corresponding triethyl ester. The-benzylsuccinic acid is formed by the triethyl ester reacting with concentrate hydrochloric acid and taking place hydrolyzation and decarboxylation reaction at the same time. In order to avoid the formation of cinnamic acid, the sodium ethylate and diethyl malonate must be react sufficiently. The course has simple operation, inexpensive materials and better yield.

具体制备工艺为:首先以L-苯丙氨酸为原料采用重氮化方法得到-2-氯-3-苯基丙酸,再经酯化得到-2-氯-3-苯基丙酸乙酯后在乙醇钠催化作用下和丙二酸二乙酯缩合,发生SN2反应,得到相应的三乙酯,然后经水解和脱羧,得到-苄基丁二酸;在实验中乙醇钠要和丙二酸二乙酯充分反应,避免生成肉桂酸乙酯;该过程操作简单,原料便宜,产率较高,总收率可达到26.8%。

Both accumulation of ROS and reduction of GSH-PX have relation with diabetic renal dysfunction, which also causing execration increase of urine MCP-1. ROS via inflammation reaction can damage diabetic renal function.

ROS合成增加、GSH-PX的活性下降均参与了糖尿病肾脏的损伤,并使代表肾脏炎症反应的尿MCP-1随尿排出增加,推测ROS介导的炎性反应在糖尿病肾病的发生、发展中发挥了作用。

The results indicated that the rate of potassium ferrate removing aniline depends on the value of pH, potassium ferrate concentration, and reacting time.

结果表明,高铁酸钾对苯胺具有比较好的去除作用,但受高铁酸钾的投加量、反应时间、体系的pH、苯胺初始浓度等的影响,其最佳反应时间为30min,pH=

Becausethe ginger flavine and its the synonym have many kinds of pharmacologyactiveness, at present, conducted the research take this kind ofcompound as the forerunner which the structure optimized to cause inthe world scope chemist and the medicine scientist's widespreadattention, take the ginger flavine as the raw material, first had thefunction production corresponding sodium salt in the organic solventby NaOH or NaOEt and a-H, then and 卤代烃carried on the substitution reaction, the response condition which theresearch optimized, and grew this derivative monocrystal with thesolution law.

由于姜黄素及其类似物所具有的多种药理活性,目前,以该类化合物为先导进行结构优化的研究引起了世界范围内的化学家和药物学家的广泛关注,以姜黄素为原料,先在有机溶剂中以NaOH或NaOEt与a-H发生作用生成相应钠盐,再和卤代烃进行取代反应,研究优化的反应条件,并用溶液法生长该衍生物单晶体。

Acid catalyst and H + catalysis in the acid catalysts were studied for synthesis of methyl glycolate via coupling of methyl formate and trioxane in a microform high-pressure autoclave(120mL).

在微型高压反应釜中(12 0ml),考察了酸催化三聚甲醛和甲酸甲酯制备羟基乙酸甲酯的偶联反应,并对酸催化剂中H+的作用进行了研究。

The factors in the gradational boundary may show a sensitive and reactive response under the competitive force between the actions of capture and dissociation.

环带边界上的要素在本体系统的捕获力和游离力的共同作用下有可能产生感知反应,反应的结果导致了系统边界的扩张或收缩,促使系统结构重组,从而实现系统的突现或塌陷。

As anti-wear agents, the s -hexyl ZDDP is found to be more effective than the n -hexyl ZDDP, and the n -hexyl ZDDP is superior to the phenyl ZDDP.

反应生成由多磷酸盐和铁硫化物组成的反应膜,该膜具有较好的抗磨作用,仲烷基ZDDP比伯烷基ZDDP的抗磨性好,而伯烷基ZDDP的抗磨性优于芳香基ZDDP的。

The two—step sulfomethy lation and the reaction with HOCH〓SO〓Na in sulfite cooking were illustrated in this paper. The optimum technological conditions were determined on the basis of suitable amount of HCHO in sulfite pulping. The differences of delignification and paper properties of wheat straw were also studied in SFP—AQ and alkaline sulfite and AQ cooking .

对麦草粉的两步法磺甲基化反应以及与羟甲基磺酸钠的反应进行了研究,解释了甲醛在亚硫酸盐蒸煮中脱木素作用机理,从理论上确定了甲醛在SFP—AQ蒸煮中的适宜用量,并据此提出了合理的蒸煮工艺和最佳工艺条件。

The experimental result showed that three byproducts was formed and the optimal condition was as follows: the molar ratio of ethylene glycol, hydrogen bromide, and acetic acid was 1:1:1.3, when ethylene glycol was 1 mol, refluxed 5 h under the action of 100 mL toluene.

结果表明:较适宜的合成条件为乙二醇1 mol, n:n:n=1:1:1.3,在带水剂甲苯(100 mL)的作用下,回流反应5 h,约4 h后分两次追加0.12×2 mol醋酸酐,合成效果最好,产率可达到95%,反应副产2-溴乙醇及少量的1, 2-二溴乙烷、乙二醇二乙酸酯和二乙二醇二乙酸酯。

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