反应体

In the research of advanced key techniques, the technique of nano-catalyst is developed and tested according to the requirement for the catalytic flame stablizer gas turbine and the related reaction model wil be fully construced. In the aspect of hydrogen shift and separation process, we are going to probe into various operating parameters for the water shift reaction and the membrane reactor alread constructed. Also, the high efficiency DPMS-based hydrogen shift and separation system that carry out both water gas shift and pressure swing absorption will be tested. The main task this year is to construct the proto-type clean hybrid power generation system.

前瞻关键技术研究方面，奈米触媒制备技术将依触媒驻焰气涡轮引擎之需求进行开发与测试，并建立相关反应模式；气化合成气转化与分离技术部分，将进行已建立水气转移反应与薄膜反应器之各项操作参数探讨，并进行以双孔径分子筛为担体，附加水气转移反应与变压吸附分离所建立之高效率分离富集H2方法之系统实测。

METHODS: MyoD cDNA fragments were extracted from plasmids pEMSV-MyoD with polymerase chain reaction, and PCR was used to clone the whole-length gene of MyoD. After adding CACC sequence at 5' end, MyoD gene was cloned by orient topology into transfer ventor, pENTR/D-TOPO. Objective gene was transferred into adenoviral expression vector DNA via pENTR/D-TOPO vector. The recombinant adenoviral vectors transfected into HEK293A cells by using lipofectamine were packaged and amplified.

从pEMSV-MyoD质粒上用聚合酶链反应法扩增出MyoD cDNA片段，再通过聚合酶链反应使MyoD基因加上CACC序列接头，经过定向拓扑克隆使目的基因连接到转移载体上，再通过LR酶促反应，将目的基因转移到腺病毒表达载体DNA上，获得MyoD基因重组的腺病毒DNA，用脂质体转染法转染HEK293A细胞，包装扩增出MyoD基因重组的腺病毒。

Fu Xiangkai Carbonylation reaction in biphase system is the important atomic economicreaction in the field of green chemistry.

含膦酸根等水溶性膦配体及其钯配合物的合成、表征和催化羰基化反应两相催化体系的羰基化反应是一类重要的绿色化学&原子经济型&反应。

The Schiff base transitional metal complexes of various structures and their metallomicelles as peroxidase models for the phenol and phenolic derivant oxidation have been investigated. Some results are obtained from the studies:(1) the Schiff base transitional metal complexes have high catalytic activity for the phenol and phenolic derivant oxidation, and the structure of the complexes has a great effect on its catalytic activity;(2)a novel kinetic mathematical model for the complexes and their metallomicelles catalyzing the phenolic derivant oxidation has been established;(3) the feasibility and mechanism for the phenolic derivant oxidation catalyzed by the metallomicelle(as the mimetic model of peroxidase)have been discussed.

研究了冠醚Schiff碱金属配合物作为过氧化物酶的模拟模型对酚类物质氧化反应的催化作用，取得如下结果：(1)几种冠醚Schiff碱金属配合物对催化酚类物质氧化具有良好的催化活性，其中配体结构对其催化活性有较大的影响；(2)建立了金属配合物与表面活性剂形成的金属胶束催化酚类物质氧化反应的动力学数学模型；(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

The reaction performance of Pt-Sn-Li/Al_2O3/FeCrAl catalyst was measured,and the properties of the catalyst were characterized.It was found that reaction temperature,LHSV and the molar ratio of hydrogen to alkane have greatly affected on the catalytic performance of the Pt-Sn-Li/Al_2O_3/FeCrAl catalyst.Under a set of optimal reaction conditions,at 0.1 MPa,470℃,the molar ratio of hydrogen to alkane of 4 and LHSV of 0.14 mL·m~(-2)·h~(-1),the dodecane conversion is 6%,and the dodecene selectivity is about 72%.

结果表明：工业催化剂的催化性能比至今实验室制备的γ-Al_2O_3和SBA-15颗粒负载型颗粒状催化剂的性能好；反应温度、液时空速和氢烃摩尔比对Pt-Sn-Li/Al_2O_3/FeCrAl金属基整体式催化剂脱氢性能都有重要影响，最适宜的反应条件是压力为0.1 MPa，反应温度为470℃，进料氢烃摩尔比为4和LHSV为0.14 mL·m~(-2)·h~(-1)，此时十二烷的转化率约为6%，十二烯的选择性约为72%；活性组分涂层与金属基体结合良好。

The anterior cingulate cortex and dorsolateral prefrontal cortex are the basic cortex of execution control and conflict monitor.

结论扣带回和背外侧额叶是执行冲突监控和反应抑制基础，在冲突监测和反应抑制形成反馈环路，实验支持背外侧额叶是执行控制脑区，提示在持续注意状态下，执行反应控制依赖脑干和新纹状体协调。

A model of reactive astrogliosis was successfully established in vitro which showed an active reaction to injury. The characteristics of reactive gliosis parallel that seen in vivo.

体外分离培养的Ast对损伤表现出活跃的反应，呈现出典型的反应性胶质化特征，其发生、发展过程与规律类似于在体情况下的Ast反应。

The results in this paper are concluded as follows:(1) Rolling contact fatigue has been used to examine the interfacial reaction products and study the mechanism of ion beam intermixing effect on the adhesion of Cr-N coating on steel by IBAD.

对多次冲击条件下薄膜的失效抗力及其与薄膜力学性能之间的关系进行了初步探讨，得到如下结果：（1）用滚动接触疲劳法检测离子轰击导致的界面反应产物和研究离子束共混对钢基体上IBAD沉积Cr-N薄膜结合强度的影响本质，结果表明，滚动接触疲劳能有效地分析界面最薄弱位置和评估界面反应产物，滚动接触疲劳引起的剥落可作为研究界面反应产物对结合强度影响的根据。

In ternary system of PGA/POH and HDI isocyanurate, there are twomain reactions: one forms urethane at 30-50℃, the other producesoxazolidone at 140-165℃.

聚丙烯酸环氧丙酯（PGA、聚丙烯酸羟丙酯（POH和HDI三聚体的三元反应体系中，醇羟基与异氰酸酯在30-50℃下反应可生成氨酯，环氧基团与异氰酸酯在140-165℃下反应生成噁唑烷酮。

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。