反催化的

The catalytic effects of 1a on the direct aldol reaction in water were much better than that of 1b.

与有机相中的反应相比，在水中反应时，1a比1b催化活性更高。

The kinetics of PenG hydrolysis catalyzed by penicillin amidase entrapped in the reversed micelles was studied.

研究了青霉素酰化酶在AOT/异辛烷反胶团体系中催化PenG水解反应的动力学。

In this thesis, the dynamic course of penicillin G hydrolysis to 6-aminopenicillanic acid (6-APA) with penicillin amidase entrapped in the bis (2-ethylhexyl) sulfosuccinate /isooctane reversed micelles was studied.

本文主要研究青霉素酰化酶在反胶团体系中催化青霉素G水解的反应过程，并对反胶团介质中酶的稳定特性、反应动力学以及反应器开发等方面进行了较为系统的研究。

The result shows that catalyst concentration, reaction time, urushiol concentration and temperatures affect the polymer yield in oxypolymerization of urushiol system.

讨论了该配合物作为催化剂，催化漆酚氧化聚合反应时，催化剂浓度、时间、底物浓度以及温度对漆酚氧化聚合反应的影响。

The reason may be that complex formed by rhodium and halide was difficult to produce the catalytic active species. Therefore halide ion was the poison for the rhodium catalyst in hydroformylation of olefins in ionic liquid. The effect of double long chain cationic surfactant (DCMAB, dicetyl dimethylammonium bromide) on selective hydrogenation of cinnmaldehyde catalyzed with RuCl3·x H2O/TPPTS was studied.

进一步的研究表明在使用有良好反应活性的两种催化剂HRh3 、Rh_2进行催化反应时，向体系中加入含有卤离子的化合物时将使反应活性大大降低，而且随着卤化物加入量的增加，催化剂的活性迅速下降，这是卤离子可能和金属铑作用使它难于生成催化活性物种，进一步证明卤素离子是引起催化剂活性下降的极其重要的因素。

The results indicate that little conversion of iodobenzene was observed on unmodified carrier supported catalysts; and a conversion of 100% and a selectivity of above 98% to trans-isomers were found over 10%Cu/5%KF/ZnO, 20%Cu/10%KF/ZnO.

结果表明，对碘苯与丙烯酸正丁酯的Heck反应的催化性能，未改性催化剂基本没有活性，而改性后，10%Cu/5%KF/ZnO、20%Cu/10%KF/ZnO催化剂的催化转化率为100%和反式异构体的选择性为98%以上。

Results showed that AOT reversed micellar systems provided a suitable micro-environment for biodiesel production. The optimal parameters were: the ratio of water and AOT 11, AOT concentration 50 mmol/L, temperature 40℃, pH 7, molar ratio of methano and oil 3, and rotating speed 180 r/min. The transesterification rate reached 90% when a 3-step methanolysis protocol was used.

研究结果表明： AOT/异辛烷反胶束体系为Candida sp.99-125脂肪酶催化提供了较为合适的微环境，在W0为11，表面活性剂浓度为50 mmol/L，温度为40℃，缓冲液pH值为7的AOT/异辛烷反胶束体系中，醇油摩尔比为3∶1，摇床转速为180 r/min，采用12h3次流加1 mol当量的甲醇，单批最高酯转化率可以达到90%。

The progress of reversed micellar extraction in food science was reviewed,including the separation of proteins and amino acids.

综述了反胶束萃取技术在食品中的研究进展，包括分离蛋白质和氨基酸，反胶束体系还可以作为酶催化反应介质，具有良好的食品工业应用前景。

By use of titration analysis, the thesis investigated various factors such as isocyanate, PE molecular weight, reacting substance molecular ratio, reacting temperature and time etc. influencing upon prepolymerization step. It was found that 2, 4-tolulene diisocyanate and 4, 4'diphenylmethane diisocyanate is more rapidly reacted with PE600 than HDI. With PE molecular weight increasing, the reacting temperature or time should be raised or extended relevantly. Thus PE2000+2HDI pre-polymerization should be better carried out under some catalyst, for example, Triethylene diamine , Dibutyltin dilaurate and Tin octoate were used.

首先采用滴定分析方法对WRPU预聚反应的影响因素进行了研究：芳香族二异氰酸酯TDI、MDI比脂肪族二异氰酸酯HDI反应活性高，其中TDI在反应初始阶段的反应速率比MDI快，不过随着反应的进行，MDI比TDI反应速率加快，这主要是因为TDI分子中的两个-NCO反应活性差异大所致；二元醇分子量越大，反应速度越慢；聚醚二元醇比聚酯二元醇的反应速度快；当分子量超过2000的二元醇与HDI进行预聚反应时，需借助适当的催化剂来加快反应速度，从而使预聚反应能够顺利进行，分别选择DABCO、TOA和DBDTL三种催化剂进行催化反应，发现不同的催化剂，其催化效果相差较大。

Its optimum pH and temperature are 5 and 40℃ respectively. 2 Solubility and Kinetics Characteristics of Tannase in RM System 2. 1 A method of HPLC was set up to assay the content of gallic acid and alkyl gallate at the same time.

反胶束单宁酶的动力学性质研究 2.1 建立了HPLC同时测定反胶束酶催化体系中底物没食子酸和产物没食子酸烷基酯含量的方法。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。