反催化剂

Mono-cinnamyl maleate was prepared by esterification of maleic anhydride and cinnamyl alcohol of 1 mol:2 mol at 95 ℃ for 2～4 h.Then added isomeric catalyst and mono-cinnamyl fumarate was made by reacting at 90 ℃ for 4 h.After methanol (methanol:mono-cinnamyl fumarate = 6 mol:1 mol) was added,the mixture maintained at 90 ℃ for 4.0 h to synthesize CMF.

合成试验表明：以摩尔比为1：2的马来酸酐与肉桂醇在95 ℃醇解反应2～4 h后加入异构化催化剂，90 ℃转型反应4 h后，添加6倍摩尔质量的甲醇，在90 ℃恒温反应4 h，反丁烯二酸桂醇甲酯的合成产率较高。

The performance of this catalyst for the cross-coupling reaction of iodobenzene with acrylic acid was studied.

研究了该催化剂对碘代苯与丙烯酸交叉偶联生成反式－肉桂酸的催化性能。

Basic ionic liquid OH has been introduced as catalyst and reaction medium for Knoevenagel and Perkin reactions.

以碱性离子液体OH作为催化剂，在无溶剂条件下，催化Knoevenagel反应和Perkin反应两类缩合反应。

Emphasis analyzed,researched and estimated pinacol rearrangement actions,catalysts,reaction machine,related some reaction formulae etc,and characteristic,regulation relative with migration groups and more uses.

重点分析、研究和评述了频呐醇重排的作用、所用的催化剂、反应机理、相关的一些反应式、与迁移基团相关的重排特征和规律以及其较多的应用等，也论及了反频呐醇重排反应恰好是频呐醇重排的逆过程。

In this mechanism, a phosphine ligand in the Ru hydride complexes is replaced by protonic solvent ROH to generate the chain carrier.

三、反应机理论文提出，在固载Ru基催化剂上的scCO〓加H〓生成HCOOH的反应中，CO〓的活化在Ru配合物的作用下，以反插入Ru-H键，生成金属-羧酸配合物的形式进行。

The investigation of reaction kineties of tetralin hydrocraking on modified Molyblenum-Nickel catalysts with zeolite Y were conducted in the improved China-made continuous micro reactoe WF-8900 connected with gas chromatograph on-line.

在活性趋于稳定的以改性Y沸石为担体的钼镍催化剂上，利用经改造的国产WF—8900型连续流动微反-色谱装置，进行了四氢萘加氢裂化反应动力学方面的研究。

The Mg1.0AlO catalyst prepared by back-titration shows relatively high activity and stability, the conversion of acetone maintains at 65% even after 85 h at 573 K.

实验结果表明，以反滴沉淀方式制备的Mg1.0AlO催化剂具有较高的反应活性和稳定性，在反应温度为573K条件下，反应85h后丙酮的转化率仍可以达到65%。

Five vanadium catalysts were made with γ-Al2O3 and the mesoporous molecular sieve MCM-41 as carrier, and were made by dipping method, intermingle process and functionalizing method respectively.

结果表明，采用以V2O5为活性组分，介孔分子筛为载体，浸渍法制备的钒催化剂，反应时DPC收率及DPC选择性是最高的，催化反应的效果最好。

In the fifth part, asymmetric synthesis of β,γ-trans-alkenyl α-amino esters was achieved by chiral phosphoric acid catalyzed transfer hydrogenation of β,γ-alkynyl α-imino esters. Utilizing Hantzsch ester as the hydrogen donor, both the alkyne and imine moieties of β,γ-alkynyl α-imino esters were reduced to yield β,γ-trans-alkenyl α-amino esters with up to 96% ee.

第五部分工作中，使用手性磷酸作为催化剂，Hantzsch酯作为氢源，β，γ-炔烃取代的α-酮酸酯亚胺中的炔键和亚胺官能团均被还原，以中等的收率和优秀的对映选择性（up to 96% ee）得到β，γ-反式烯烃取代的α-氨基酸衍生物。

The reactor is set with side sampling mouth able to collect the samples in different positions of the reactor, and has backflushing part able to regularly wash the catalyst in the reactor, effectively the salt stain problem always occurring in the course of wet-oxidizing actual high-concentration organic industrial waste water.

反应器设有侧线取样口，可以采集反应器不同位置的样品，反应器具有反冲洗部分，可以定期清洗反应器内的催化剂，有效地解决实际高浓度有机工业废水湿式氧化中经常出现的盐垢问题。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。