反催化剂

Using mordern physical chemistry techniques (such as XRD、 TG-DTA、 IR、 XPS and 〓Xe-NMR)、 chemical adsorption techniques (NH〓-TPD、 H〓-TPD、 TPO、 TPR etc.) and pulse flow microreaction of n-hexane、 methylcyclopentene and n-hexane containing 0.2ppm thiophene, we studied mainly the following three points:(1). the changes occured during the calcination pretreatment of Pt ammine complex supported on β and L zeolites;(2). the effect of structure and acidity-basicity of zeolite on the dispersion and electron state of Pt particles; and (3). the influence of second metal component on the reactivity of nhexane aromatization and sulphur-resistance of Pt/L zeolite catalyst. Several interesting and valuable results are obtained and summerized as follows

本论文运用各种近代物理表征方法(XRD、BET、TG-DTA、IR、XPS和〓Xe-NMR)、化学吸附技术(NH〓-TPD、H〓-TPD、TPO、TPR等)和正己烷、甲基环戊烷及含噻吩正己烷的脉冲微反等方法，着重研究了(1)载Pt的β和L沸石在分解预处理过程中发生的变化；(2)沸石载体结构及酸碱性对Pt粒子分散及电子状态的影响；(3)第二金属组份对载Pt沸石催化剂上正己烷芳构化及抗硫性能的影响等，得到了某些有意义的结果。

The yield of iso amyl propionate was up to 91.8% when molar ratio of isoamyl alcohol to propionic acid was 3.0:1, mass ratio of catalyst was 2.5%, and reaction time was 2.0 hs.

在醇酸物质的量比为3.01，催化剂用量为反应物料总质量的2.5%、反应时2.0h，产品收率可达91.8%。

The aromatization performance of Mo/HZSM-5 with different molybdenum species has not been well investigated.

另一方面，使用MoO_3／HZSM-5进行甲烷芳构化反应时，反应过程中钼物种会被还原和碳化形成多种钼物种，但关于这些不同钼物种的Mo／HZSM-5催化剂的芳构化性能尚不清楚或存在争议。

The process can convert over 95% isobutylene in C 4 olefin into diisobutylene or isooctene in the present of acid cation exchange resin catalyst,and partial 1-butylene also take part in the reaction.

介绍了一种混合碳四烯烃叠合利用的预反和催化蒸馏组合技术，该技术以酸性阳离子交换树脂为催化剂，可以将混合碳四烯烃中的95%以上的异丁烯叠合反应生成二异丁烯和异辛烯，且部分正丁烯也参与二聚或共聚。

Then, the mechanism and rate constant of the photocatalytic degradation of the methylene blue solution were investigated.

结果显示，反相微乳液法制备的纳米TIO：具有较高的光催化活性，但负载型光催化剂MCM一TIOZ显示更好的光催化活性。

The effect of monomolecular reactions and bimolecular reactions on the yields of propylene and dry gas was investigated in a fixed-bed micro-activity test unit using n-hexadecane and Daqing VGO as feedstocks respectively, under various reaction conditions and catalyst types.

在固定床微反实验装置上，选择正十六烷和大庆蜡油为原料，通过改变反应条件和催化剂类型研究了单、双分子反应对丙烯和干气生成的影响。

Hydroisomerization reactions of n-paraffins with double-function catalysts have been developed as one of the most important clean method to improve the octane number of the gasoline.

将正构烷烃在氢溢流条件下使用双功能催化剂催化为异构反烷烃是提高汽油辛烷值的最重要的绿色方法。

The TiO2 synthesized by normal and reverse micelles as templated were applied for phot ocatalytic of Rhodamine B and organic toxic small molecule 2.4-dichlorophenol under ultraviolet irradiation. Oxidation species and photodegradation products in the photoreaction process were detected for studying their photocatalyst properties. The results showed that: the R-TiO2 had a better photocatalysis property under UV irradiation when photodegradation of RhB and DCP compared to the N-TiO2. After 160min, the mineralized rate of RhB can be 95%. And the oxidative species was mainly referred to OH radical.

利用正相和反相胶束介质模板制备的纳米TiO2为光催化剂，在紫外光照射下，对染料罗丹明B和有机有毒无色小分子2，4-二氯苯酚进行光催化降解，研究了其光催化性能，并对光催化过程中氧化物种及降解产物进行了跟踪测定，结果表明，反相胶束模板体系制备的纳米TiO2与正相胶束介质制备的纳米TiO2比较，在紫外照射下对RhB及DCP的降解有较好的光催化性能，对RhB在160min尤催化矿化率可达95%，光催化反应主要的氧化物种涉及在基自由基。

With propanal and malonate as reaction agents and piperidine as the catalyst, Knoevenagel reaction was used in the synthesis of flavor 2-pentenoic acid.

以丙醛和丙二酸为原料，哌啶为催化剂，采用Knoevenagel反应合成了食用香料2-戊烯酸反式构型，产率64.2%，其具有干酪味、淡烤香味。

Secondly,the synthesis of SIPE and the reaction conditions such as catalyst,anti-ether agent,temperature and water are researched to control the generation of diethylene glycol and the self-polymerization of SIPM by controlling the total quantum of distillate and the temperature of distillation column and reaction and the reliable synthetic conditions of SIPE are obtained.

其次，在此基础上，研究了三单体的中间体SIPE的合成工艺，研究了催化剂、抑醚剂、反应温度及水分等对合成反应的影响，同时提出了控制馏出物总量、控制分馏柱温度和控制反应温度等措施来控制二甘醇生成反应和SIPM自聚等副反应，得到了可靠的SIPE合成工艺。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。