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1 Heptane, it was revealed that the Cr〓/ Catsan and ZnCl〓 could catalyze the Michael addition of pyrrole with conjugate olefine at α-position of pyrrole to get mono- or bi-Michael addition product selectively under mild condition in good yield. Totally, forty-six new compounds, including thirty target compounds, were prepared.

在探索7-氮杂桥环母体的构建方法过程中,发现了Cr〓/Clay和ZnCl〓可有效地催化吡咯的α-位与多种共轭烯烃发生Michael加成反应,可在温和的条件下,以良好的收率选择性地得到单或双Michael加成产物。

Yet, completely differ from the cases of 〓-H, the 〓-dihydroxyl group was introduced after subsequent epoxidation and oxane ring opening of the 〓 tricyclic olefin.

在〓-β-H三环烯31基础上的环氧化和环氧开环反应引入的两个羟基,为双直立的〓,不同于〓类。

The structure of the compound 〓(1) consists of a pentanuclear molecule which is center-symmetric. One W atom is coordinated by four S atoms and two Cu atom. As expected, the Fe atoms are sandwiched between two staggered pentadiene rings. The most interesting aspect of the structure is that Fe-C-P-Cu-P-Cconstitutes a distorted hexagon and Fe-Cu-W-Cu-Fe is nearly in a line.

结构是以W原子为对称中心含有五个金属原子的线型结构,W原子与四个μ〓-S和两个Cu原子配位;Fe原子在两个戊二烯环中间形成一个三明治夹心结构;Fe〓-C〓-P〓-Cu〓-P〓-C〓-构成扭曲的六边形,由于两边1,1'-双二茂铁配体的作用导致Cu-S键的拉长。

Pilot-plant test for synthesis of poly/attapulgite superabsorbent composite was carried out using acrylic acid and attapulgite as main raw materials,N,N′-methylene-bisacrylamide as crosslinker and composite composed of V-50 and ammonium persulphate as initiator by solution polymerization in a 100 L pilot-plant test equipment.

在100 L的中试设备上,用水溶液聚合法,以丙烯酸和凹凸棒黏土为主要原料,以N,N-亚甲基双丙烯酰胺为交联剂,V-50和过硫酸钾复配作为引发体系,进行了聚丙烯酸/凹凸棒复合保水剂的中试放大实验。

The beta-thioalkoxyalcohols could be obtained in good yields by the reaction of dialkyl-substituted propargylic dithioacetals with a series of carbonyl compounds.

我们发现在铁触媒和格林那试剂的存在下,利用双烷基取代炔丙基硫缩酮和羰基化合物反应生成的beta-硫烷氧基醇,可以进行不常见的beta-氧消去反应,而得到烯炔衍生物。

A series of ansa-metallocenes were synthesized. Their catalytic properties for the polymerization of ethylene and propene were studied.

4合成了一系列硅桥连双茂化合物,并分别研究了它们对乙烯和丙烯聚合的催化性能。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性,发现丁烷到异丁烯的一步转化无法在这一反应体系十有效实现。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性,发现丁烷到异丁烯的一步转化无法在这一反应体系中有效实现。

The curing reaction of hydrogenated terpinene maleic anhydridewith bisphenol A epoxy resin was investigated by FT-IR spectrum, and the curing degree, gelation time and its affecting factors were analyzed.

采用FT-IR光谱研究了氢化萜烯马来酸酐与双酚A型环氧树脂的固化反应过程,并分析了固化度、凝胶时间及其主要影响因素。

The curing reaction of hydrogenated terpinene maleic anhydride with bisphenol epoxy resin was investigated by FT-IR spectrum, and the curing degree, gelation time and its affecting factors acre analyzed.

采用FT-IR光谱研究了氢化萜烯马来酸酐与双酚A型环氧树脂的固化反应过程,并分析了固化度、凝胶时间及其主要影响因素。

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