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This structure is unstable,and the proton is transferred from C6 to the sulfone to yield the bicyclic end product.

烯胺反应物也可先通过噻唑环内的氢迁移得到亚胺式反应物,从而得到亚胺式双环产物。

A Theoretical Study on the Reaction Mechanism of Epoxidation Reaction of the 4- Bicyclo

CEPS 思博网--文章书目;-1页数:7 需求点数:28 电子全文:请登入。篇名(4-溴甲基双环[4.4.1]-1,3,5,7,9-十一碳五烯基-3-)甲醇环氧化反应机理的理论研究

Components were identified which represented 85.1% of the total essential oil by the silica gel column separately.Conclusion 10 components were identified which included Bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect. of the essential oil from Angelica acutiloba Kitag were analyzed for the first time.

结果超临界CO2萃取物为黄棕色油状物,得率为0.9%,用GC-MS联用技术从中鉴定出亚油酸乙酯、5,5-二甲基-双环(6,3,0)-1,7-十一烯-3-酮等30种成分,占挥发油总含量65.66%;萃取物经硅胶柱色谱分离纯化,从中鉴定出十八酸乙酯等11种成分,占总含量的85.1%。

Components were identified which represented 65.66% of the total essential oil includding 9.12-octadecadienoic acid, ethyl ester and ect. 11 components were identified which represented 85.1% of the total essential oil by the silica gel column separately.conclusion 10 components were identified which included bicyclo (6,3,0) undeca-dien-3-one, 5,5-dimethyl ect.

结果超临界co2萃取物为黄棕色油状物,得率为0.9%,用gc-ms联用技术从中鉴定出亚油酸乙酯、5,5-二甲基-双环(6,3,0)-1,7-十一烯-3-酮等30种成分,占挥发油总含量65.66%;萃取物经硅胶柱色谱分离纯化,从中鉴定出十八酸乙酯等11种成分,占总含量的85.1%。

In the same time, water-soluble bidental phosphines ligand BISBIS sulfonated 2,2''-bis(diphenylphosphinomethyl-1,1''-biphenyl was synthesized, and water-soluble rhodium complex Cl was synthesized in situ. This complex which was used as catalysts to catalyze the hydrogenation of avermectin was also tested. Although the rhodium complex containing bidentate phosphine BISBIS showed a higher catalytic activity than one containing TPPDS, the selectivity for ivermectin was lower. How to improve the selectivity will be needed to studied in futur.

同时我们用磺化的2,2''-二-- 1,1''--联苯,以及它们的水溶性威尔金森型铑配合物和环辛二烯的阳离子铑配合物,在利用这些配合物作催化剂,考察它们在各种反应条件下对阿维菌素的选择加氢,由于反应条件以及复合催化剂体系的组成还需要进一步优化,虽然双齿膦配合物显示了较高的活性,然而选择性还有待进一步提高。

In order to study strcture-bioactivity relationship concerning α,β-unsaturated-γ-lactones, we further synthesized γ-benzyloxymethy-γ-butanolide XXIII and the corresponding unsaturated buteno- lido XXV Scheme 6, p.

为了研究该类化合物的构效关系,在本论文第三部分,我们进一步设计并合成了--γ-苄氧基甲基-γ-丁内酯XXIII和--γ-苄氧基甲基-γ-丁烯内酯XXV这两个内酯化合物,目的是想考察内酯的α,β-不饱和双键是否是产生细胞毒性的关键结构。

Objective To synthesize 10-O-adipic acid-[2'-methoxy-4'-(3"-keto-1"-Butenyl)-Phenoxy-]-dihydroartemisinin conjugate.

目的 合成10-O-己二酸基-[2'-甲氧基4'-(3&-酮-1&-丁烯基)-苯酯]-双氢青蒿素酯。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨:&平等互利,信誉至上,团结合作,友谊长久&乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵

Objective: To investigate the effect of diclofenac sodium to the changes of MMS,PGs in aqueous humor in rabbit after Nd:YAG laser posterior capsulotomy.

目的 :探讨双氯酚酸钠对兔眼Nd :YAG激光晶体后囊膜切开术后房水内中等分子物质及花生四烯酸代谢产物变化的影响。

CySeCD exhibits better GPX activity than 6-AnSeCD in the reduction of H2O2 and cumenyl hydroperoxide by glutathione, respectively.

采用双酶偶联法测定GPX的活力结果显示,6A,6A'-二环己胺-6B,6B'-二硒桥联-β-环糊精(6-CySeCD)催化谷胱甘肽还原H2O2和枯烯H2O2的活力均比6-AnSeCD的高。

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