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All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物,并通过IR谱,元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明:超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构;[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物;(HgI_2L2)_2·3H_2O是双核金属大环化合物;[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物;[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物;以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解,并且金属离子与水解产物——异烟酸根离子自组装,形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

The state in certain fungi in which each compartment of a hypha contains two nuclei,each derived from a different parent .

双核某种真菌中的状态,在这种真菌中,每个菌丝体都含有两个核,而每个核都是从不同的母体上衍生的

The results showed that the four treatments of cytochrome c supplemented with ATP all suppressed the pollen germination and pollen tube growth, and induced nuclear DNA degradation, different treatments with different ratios of double nuclei, single nucleus, and no nuclei. Treatment with heavy concentration of ATP also restrained pollen germination and pollen tube growth, but can not induced nuclear DNA degration.

结果表明,细胞色素c和ATP混合处理的四个组合都能抑制离体花粉萌发和花粉管生长,并且引起了花粉管核DNA的降解,不同处理中双核、单核及无核花粉管所占比率存在明显差异;高浓度ATP虽能抑制花粉萌发和花粉管生长,但不能引起花粉管核DNA的降解。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。

Firstly, the a decay properties of the three nuclei 〓126.〓120 and 〓114 are investigated with the RMF theory. One of them is thought to be possibly the next doubly magic superheavy nucleus.

一、利用RMF理论,对目前人们公认的最有可能成为超重双幻核的三个核〓126,〓120和〓114的α衰变性质进行了研究,发现与另外两个核比较,〓120具有更大的相对稳定性。

The double labelling technique by combination of horseradish peroxidaseretrograde tracing with immunohistochemical staining for γ-amino-butyric acidwas used to observe the distribution of GABA-positive neurons in the abducens and vestibular nucleus,and its projection to oculomotor nucleus of rats.

用辣根过氧化物酶(horseradish peroxidase,HRP)逆行标记结合γ-氨基丁酸(γ-amino-butyric acid,GABA)的免疫组织化学双标技术观察大鼠的展神经核和前庭神经核内GABA阳性神经元的分布,以及其向动眼神经核的投射。

Methods Lymphocytes with different MTHFR C677T genotypes from the donors were cultured for 9 days in media with different concentrations of folic acid and the frequencies of micronucleated binucleated cell was evaluated by cytokinesisblock micronucleus cytome assay.

采用9天淋巴细胞长期培养辅以胞质阻断微核细胞组分析,分析不同浓度的叶酸对三种MTHFR C677T基因型乳腺癌人群和健康人群双核细胞微核率的影响与差异。

Auricularia auricula is of the single-factor controlled mating system according to mating test among the F1 progenies and their parents, combining the method of dyeing the nuclei of the mycelia and observing the nuclear phase under the fluorescence microscope and the method of observing the clamp connection under the light microscope to determine whether the dikaryotic mycelia were formed.

摘 要:从黑木耳种内杂交子H2J3的子实体上单孢分离培养得到F1代52个单核体菌株,将F1子代及亲本(H2,J3)等所有供试单核体菌株的菌丝体两两配对培养,采用核荧光染色观察核相,和光学显微镜观察锁状联合,鉴别菌丝交配反应是否形成双核体菌丝,同时测定了亲本菌株所有F1子代的交配型。

Auricularia auricula is of the single-factor controlled mating system according to mating test among the F1 progenies and their parents, combining the method of dyeing the nuclei of the mycelia and observing the nuclear phase under the fluorescence microscope and the method of observing the clamp connection under the light microscope to determine whether the dikaryotic mycelia were formed.

从黑木耳种内杂交子H2J3的子实体上单孢分离培养得到F1代52个单核体菌株,将F1子代及亲本(H2,J3)等所有供试单核体菌株的菌丝体两两配对培养,采用核荧光染色观察核相,和光学显微镜观察锁状联合,鉴别菌丝交配反应是否形成双核体菌丝,同时测定了亲本菌株所有F1子代的交配型。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物,使用六齿配体合成了一系列含有两个〓单元四核笼状化合物,并用各种谱学手段表征了它们,还研究了它们的物理化学性质确定了〓L=N,N,N',N'-四(苯骈咪唑基-1,4-丁二胺和〓,〓四-1,4-丁二胺化合物的晶体结构,它们含有两个〓单元,其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

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