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Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体,初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用,20℃和20mol%催化剂量下,获得了32.5%ee和72%收率的产物。

RAPD analysis indicated that the profiles of mycelial protoplasts obtained from same single spore isolates amplified by 10 random primers were entirely identical, corroborating that the two nuclei of a basidiospore were homogeneous.

RAPD分析显示,源于同一单孢分离物的菌丝原生质体为10个随机引物所扩增的图谱彼此完全相同,印证了担孢子中的双核是同质的。

Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.

此外配合物的结构还比较特殊,三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2:2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF,环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。

Some SPR-LI neurons were also positive for TH. After administration of vasopressin, SPR-LI structures became denser, especially at levels of pyramidal decussation and area postrema . The dendrites of motor dorsal nucleus of X in the dorsal part of MVZ appeared thin and straight in morphology instead of curl and thick outlooks. These results implicate that some SPR-LI neurons might receive or regulate the cardiovascular stress information induced by vasopressin.③In PHA-L/FOS/TH triple-labeled experiments, seven kinds of immunohistochemical structures were found in MVZ. They were FOS-LI neurons, TH-LI neurons, PHA-L positive fibers, PHA-L positive fibers terminated on FOS-LI or TH-LI neurons, FOS/TH doublelabeled neurons, PHA-L positive fibers terminated on FOS/TH double-labeled neurons.

在锥体交叉和最后区水平,SPR免疫反应阳性结构较正常组明显增强;背内侧部迷走神经运动背核的SPR纤维也由弯曲的粗纤维变为细的直纤维,30%的SPR阳性神经元为SPR/FOS双标记神经元,提示这些神经元参与感受心血管伤害性刺激信息,继而参与心血管活动信息的中枢传导或整合;③三重标记研究结果显示,在MVZ可见到七种免疫反应阳性结构,即PHA-L,FOS,TH,FOS/TH,PHA-L/FOS,PHA-L/TH,PHA-L/FOS/TH。

Some new results are obtained from the studies: 1 a novel thermokinetic research method, the characteristic reduced parameter method, has been proposed, and the kinetics of oxidation of benzoquinone by hydrogen peroxide has also been investigated with this method; 2 the kinetic mathematical models that the metallomicelles made from the mono-nuclear or dinuclear complexes and surfactants catalyze the phenolic derivant oxidation have been established respectively; 3 the feasibility and mechanism that the metallomicelle, a mimetic model of peroxidase, catalyzes the phenolic derivant oxidation has been discussed.

研究得到如下新的结果:(1)提出了一种新的热动力学研究法——特征对比参量法,用该法研究了过氧化氢氧化苯醌反应动力学;(2)分别建立了由单核和双核金属配合物与表面活性剂形成的金属胶束催化酚类氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

Interestingly, we observed that ANE itself caused cytokinesis failure and increased the frequency of binucleated cells following 24-h exposure.

有趣的是,我们还观察到槟榔子萃取物作用二十四小时后的细胞会出现细胞质分缺损,且双核细胞的比有明显增多的现象。

In all those complexes, no matter which conformation IDA assumes (mer- or fac-style), the two 0 atoms of 1N2O are both from carboxylic hydroxyl. However, by comparing the bond length, we can find that O(4) and O(2) atom is from different group in this complex, 0(4) atom from carboxylic hydroxyl, whereas, 0(2) from carboxylic carboxide.

值得注意的是:在这个双核配合物中,我们首次发现一种新颖的配位方式:IDA上与金属离子配位的三齿螯合原子是亚氨N原子、一个羧基上的羟基O原子和另外一个羧基上的羰基O原子。

Dikaryon A fungal hypha or mycelium whose cells each contain two different nuclei, arising from the fusion of two compatible cells, each with one nucleus.

双核:真菌的菌丝或菌丝体细胞含有两个不同的细胞核,来源于两个相同的各具有一个细胞核的细胞的融合。

Aim To search for the structural insights into the effect of isonucleoside on DNA:DNA duplexes and their thermal stabilization.

目的 研究异核苷的掺入对DNA:DNA双链的结构特征以及杂交热稳定性的影响。

The complexes were characterized by elemental analysis,UV,IR,TG,NMR and molar conductance measurements.Their formulas were in accordance with C34H32O8N2LnCl·nH2O or 〔(L4)2LnCl·nH2O,Ln=Nd,n=4;Ln=Pr,Yb,n=2;Ln=Sm,Eu,Dy,n=1〕.All the water molecules were uncoordinated.Dinuclear complexes were observed in the coordination environment.The coordination number of central ions was nine.

经元素分析、红外光谱、紫外光谱、核磁共振谱、质谱、摩尔电导、差热热重分析确证结构,其化学式为C34H32O8N2LnCl·nH2O,简写为:(L42LnCl·nH2O,Ln=Nd,n=4;Ln=Pr,Yb,n=2;Ln=Sm,Eu,Dy,n=1;该类配体是以酚氧原子、亚氨基的氮原子、桥联的羧基氧原子以及氯原子同稀土离子配位,形成了九配位的双核配合物。

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