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RAPD analysis indicated that the profiles of mycelial protoplasts obtained from same single spore isolates amplified by 10 random primers were entirely identical, corroborating that the two nuclei of a basidiospore were homogeneous.

RAPD分析显示,源于同一单孢分离物的菌丝原生质体为10个随机引物所扩增的图谱彼此完全相同,印证了担孢子中的双核是同质的。

This dissertation divides into seven chapters and the main contents and conclusions are listed as following:1. Three series binuclear lanthanide carboxylate coordination polymers 1~7 have been synthesized under hydrothermal conditions by altering the length of carbon chains between carboxyl group and phenyl ring on ligands, which are isophthalic acid, 1,3-phenylenediacetic acid and 1,3-phenoxydiacetic acid, and lanthanide ions such as Pr~(3+), Eu~(3+)and Ho~(3+).

论文共分七章,主要研究内容和结论如下:1、通过改变间苯二甲酸配体的羧基和苯环之间的碳链长度,从间苯二甲酸、间苯二乙酸到间苯二氧乙酸,以及改变稀土离子半径Pr~(3+、Eu~(3+)和Ho~(3+)出发,在水热条件下制备了三个系列双核金属单元的稀土羧酸二维配位聚合物1~7。

Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.

此外配合物的结构还比较特殊,三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2:2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF,环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。

Three kinds of small molecular copper and zinc superoxide dismutase mimics were synthesized with N, N-bis (benzimidazol-2-ylmethyl) amine (N3), N, N-bis (benzimidazol-2-ylmethyl) methylamine(MN3) and N,N-bis (benzimidazol-2-ylmethyl) benzylamine(BN3) as ligands. The com-plexes were characterized by UV, IR and element analysis and the structures were proposed.

模拟铜一锌超氧化物歧化酶的活性中心,以二(2-苯并咪唑)丙烷为桥、二(2-苯并咪唑亚甲基)胺(N3)、二(2-苯并咪唑亚甲基)甲胺(MN3)及二(2-苯并咪唑亚甲基)苄胺(BN3)为配体合成了3种异双核的小分子模型化合物,并进行了紫外、红外表征及元素分析,推测了可能的结构。

5 Mononuclear and 6 binuclear schiff base manganese complexes have been prepared.

以Schiff碱为配体制备了5个单核和6个双核锰配合物。

Compound (3) and (4) are isostructural compounds containing lanthanide binuclear dimer and 1-D lanthanide helical chain.

化合物(3)包括两种基本结构单元,由配体pydc上μ3-O桥连起来的镧双核单元和1-Dn螺旋链。

Binuclear dimmer and tetrahedron of Zn and Yb〓O〓 cubane assembled by hydrogen bond structures were obtained.

上述配合物分别具有双核二聚体结构以及氢键组装的Zn四面体和Yb〓O〓立方烷结构。

Reaction of the ligand with CdI2 or Cu(NO3)2 afforded dinuclear monohelical complexes 1 and 2 equipped with the aromatic rings, and the complex interacted each other through cooperative C-H...π and π...π interactions to form homochiral 2D layer along ab plane.

配体与CdI2和Cu(NO3)2反应得到双核单螺旋化合物1和2,在化合物2中,由于C-H…π和π…π的协同相互作用沿ab面形成单一手性的二维平面。

Both iron atoms of the binuclear unit are bridged by one oxy atom and two acetate groups. Each iron atom is also bound to facially - coordinating tridentate IDB ligand with the aliphatic nitrogen donor situated trans to theμ- oxy atom. Each iron centers is in a distorted octahedral symmetry.

每个双核单元的两个铁原子均通过一个氧原子和两个醋酸根连接,每个铁原子同时还与位于桥氧原子对位的三齿配体IDB重脂肪链上氮原子相结合,每个铁中心为一变形八面体结构。

With two tripodal ligands, dtma and tmpa, dtma=diethylenetriamine-N'-acetate and tmpa=tris(2-pyridyl-methylamine and a polyamine ligand, trien (=triethylenetetramine), serving as terminal ligands, we synthesized 19 species of new imidazolate -bridged Cu-Zn, Zn-Zn and Cu-Cu, and other relating compounds, in which 〓 and 〓 complexes are model compounds of Cu, Zn-SOD.

用不等臂三脚架dtma(diethylenetriamine-N'-acetate)、直链trien和等臂三脚架tmpatris(2-pyridyl-methyl-amine为配体,合成了一系列咪唑桥联Cu-Zn、Zn-Zn和Cu-Cu等有关19个新化合物,其中两个异双核〓Cu〓和〓〓配合物为Cu,Zn-SOD活性中心的模型化合物。2。

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