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The X-ray diffraction patterns were calculated analogically by using Rietveld method and the phase content in rare-earth two phase Nd2Fe14B/α-Fe magnet was determined based on standardless quantitative phase analysis.

稀土双相永磁合金是基于软磁相的高饱和磁化强度和硬磁相的高各向异性的特点,通过两相晶粒在纳米尺度上交换耦合而成的一种纳米晶复合永磁材料,它具有显著的剩磁增强效应,可望获得较高的综合磁性能[1~3]。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions(0-D chain); complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物,并用X-射线单晶结构分析方法确定了晶体结构,分别为: [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构;配合物2借助水分子形成一维链状结构;配合物3、4、5、6是以H4btc为第一配体、phen为第二配体,通过水热法合成的配合物,其中,Co2+、Ni2+、Cu2+为中心离子;配合物3中的二价钴离子具有相同的配位环境,不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境,在配合物4中,一维链通过H4btc上的羧基形成一个二维层结构;配合物5、6是借助H4btc上的羧基形成的一维链状结构;配合物7、8属于异质同晶结构,它们的分子通过分子间氢键形成三维网状结构,H4btc上的羧基失去2个质子,作为一个二价负离子起到电荷平衡作用。

Common transparent quartz tube SiO2 more than 99.9% purity, geometry, chemical stability, thermal stability, resistance to thermal denaturation and anti-crystallization properties of the fine, optical transmittance above 93%; from hydroxyl in hydroxyl tube below 10ppm, after vacuum from hydroxyl, hydroxy-up to 5ppm below apply to high-pressure mercury lamp, sodium lamp, metal halide lamp, such as low-hydroxy products; white pipe, used mainly for heating tube, heating tube, far infrared control the manufacture, milky quartz pearl quartz tube possession of new technology, the management side as if the surface of pearls, all aspects of performance than ordinary white tube better; filter tube to filter out ultraviolet UV band in the harmful wavelengths of 190-320nm ultraviolet light source applied to environmental protection manufacturing; no ozone UV filter tube and pipe the contrary, through the ultraviolet wavelength around 253.7nm, there is no ozone UV lamp main material, widely used in medical equipment, water treatment, food hygiene, such as sterilization; quartz casing diameter 8-120mm in between, has a single opening, double opening round, flat-top shape and widen the mouth of necking, flanging, sanding and other processing, high temperature resistance, corrosion resistance, good light transmission and moisture-proof, explosion-proof characteristics such as widely used in aquarium thermostat, disinfection equipment, heating pipes, water treatment, metal halide lamp, such as product manufacturing and environmental protection, health, chemical and other fields; quartz Clamshell specifications 8-180mm, the shape according to the customer requirements, the bubble shell can take capillary has to carry out the exhaust, high temperature, light transmission is good, mainly for JC, JD, H1-H7, the stage lights and high-pressure mercury lamp, sodium lamp, metal halide lamp, such as product manufacturing; quartz water jacket mainly used in printing and packaging processing industry ---- UV light-curing, UV light curing is a very reliable and can be used to replace hot air dryers and other drying technique of curing technology, which in the printing and packaging of the processing industry has been widely.

普通透明石英管SiO2纯度达99.9%以上,几何尺寸、化学稳定性、热稳定性、抗热变性和抗析晶性能优良,光学透过率达93%以上;脱羟管羟基在10ppm以下,经过真空脱羟,羟基可达5ppm以下,适用于高压汞灯、钠灯、金卤灯等低羟基产品;乳白管,主要用于发热管、加热管、远红外管的制造,珠光石英管乳白石英管之新工艺,管面好象珍珠的表面,各方面性能比普通乳白管更优;滤紫外线管能够滤除紫外光谱波段中对人体有害的190-320nm波长的紫外线,适用于环保光源的制造;无臭氧管与滤紫外线管相反,可透过253.7nm左右波长的紫外线,是无臭氧紫外线杀菌灯的主要材料,广泛用于医疗器械、水处理、食品卫生等杀菌;石英套管直径范围在8-120mm之间,有单开口、双开口、圆头、平头等外形和扩口、缩口、翻边、磨砂等加工,具有耐高温、耐腐蚀、透光性好及防潮、防爆等特点,广泛使用于水族恒温器、消毒设备、加热管、水处理、金卤灯等产品的制造和环保、卫生、化工等领域;石英泡壳规格Φ8-180mm,形状根据客户要求,泡壳上可以接有毛细管,可进行排气,耐高温,透光性好,主要用于JC、JD、H1-H7、舞台灯和高压汞灯、钠灯、金卤灯等产品的制造;石英水套主要用于印刷和包装加工工业---- UV光固化, UV光固化是一种十分可靠的、可取代热空气干燥机和其他干燥技术的固化技术,它在印刷和包装加工工业已经得到广泛应用。

There are two transition points in the resistant-temperature curve of the La_(0.7)Ca_(0.3)MnO3 film fabricated by sol-gel method, and it is the result of the interaction between double exchange and small polarons that play a important role in CMR films.

在溶胶-凝胶法制备的La_(0.7)Ca_(0.3)MnO_3薄膜的电阻-温度曲线中,出现了两个转变点,这是双交换作用和晶格畸变产生的小极化子相互竞争的结果;

Conjugated polymers which are different from traditional semiconductor, have some unique properties. Most of them are quasi-one-dimensional systems with strong electron-phonon interaction. Their carriers are composite particles, which are different from simply electron and hole, characterized with the surrounding distortion of lattice configuration (polaron with spin 1/ 2 , bipolaron with spin 0 etc.). The transport of the carriers and the process that oppositely charged polarons combine to from exciton are believed to be of fundamental importance for electroluminescence properties.

共轭聚合物具有不同于传统半导体的特性,它们是强电-声相互作用的准一维体系,其载流子不再是简单的电子和空穴,而是伴随晶格畸变的具有内部结构的复合粒子(自旋1/2的极化子、自旋为0的双极化子等),这些载流子的输运、以及正负极化子对复合成激子的过程在很大程度上决定着聚合物的电致发光性质。

Since the contribution of the spin-orbital coupling interaction of the ligand to optical and electron paramagnetic resonance spectra can not be neglected, the optical and EPR spectra g factors g‖、g⊥ and hyperfine structure constant A‖、A⊥ of LiHSO4:VO2+ crystal are calculated from the high-order perturbation formulas on the basis of double-spin-orbital coupling model and crystal-field theory for 3d1 ion in tetragonal symmetry.

考虑到配体离子的自旋-轨道耦合作用对光谱和电子顺磁共振谱的贡献不可忽略,采用3d1离子在四角对称下基于双自旋-轨道耦合模型的高阶微扰公式和晶场理论公式,理论计算了LiHSO4:VO2+晶体的光谱和电子顺磁共振参量g因子g‖、g⊥和超精细结构常数A‖、A⊥。

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