双晶

On the basis of twin-roll thin strip continuous casting experiments and solidification structure characteristic analysis of thin strip and combining with the simulation results of effects of technological parameters, the forming mechanism of solidification structure zone (especially equiaxed crystal zone) on 1Crl8Ni9Ti stainless steel twin-roll thin strip was investigated.

在双辊薄带连铸实验和薄带凝固组织特征分析的基础上，结合对薄带凝固组织区的模拟预测结果，研究了1Cr18Ni9Ti不锈钢双辊薄带凝固组织区的形成机理。结果表明：1Cr18Ni9Ti不锈钢双辊薄带凝固组织中的等轴晶区不但在凝固类型为半固态时形成，在轧制或理想型时也能形成。其形成机理为，熔池中悬浮游离晶体的沉积、聚集以及在枝晶生长前沿的长大和薄带离开二铸辊最小间隙后，薄带/空气界面换热系数骤然降低抑制了柱状枝品的生长，并促使薄带中部未凝固熔体中游离晶体的择优长大

And the devices'properties and improve the properties to prepare the artificial boundary. The bi-epitaxial YBCO superconducting film with 45°grain boundary in a-b plane was made for the first time in China in this article by magnetic sputtering instrument that was designed and fabricated by ourselves. The x-ray θ～ 2θ scan 、Ф scan、rocking curve、non-symmetry diffraction and SEM、 TEM、AES etc. were utilized in the study.

为此，本工作采用自行设计制造的全金属密封超高真空磁控溅射设备，利用x射线θ～2θ扫描、Ф扫描、摇摆曲线、非对称衍射及SEM、TEM、AES等分析测试手段，在国内首次、也是至今唯一的一家，制得a—b平面内具有45°人工晶界的双外延YBCO超导薄膜，并进而得到双外延晶界Josephson结。

Five novel torsion-mirror optical actuators including double-beam thickness differential structure with single torsional axis, double flexible folded-beam structure with single torsional axis, double-beam vertical torsion comb structure with single torsion axis, four-beam differential compound-micromirror structure with double torsional axis and the combined structure of the four basis forms above, are brought forward. All of these devices could be fabricated by the same silicon micromachining process we have developed. The deformation compensation design with local enhancement for the thin torsional beam which is the key structure of these devices is also put forward to improve the reliability. The three-dimension solid model and two-dimension reduced order model of the torsion-mirror optical actuator are established and then the numerical simulations for evaluating the device characteristics of the statics, dynamics, electrostatic field, mechanical and electrostatic coupling, fluid and solid coupling are carried out to optimize the structure design. Furthermore, three optical fibre clamping structures which could be integrated monolithicly are designed and analyzed to improve the optical coupling capability. 4. Three flexible process flows combined with bulk silicon micromachining and surface silicon micromachining are brought forward to fabricate these novel single-crystal silicon or polysilicon torsion-mirror optical actuators by using the same lithography masks for both SOI wafer and regular silicon wafer. A series of important process experiments are carried out to optimize the process parameters and the process flows. Some novel and typical process phenomena which occurred during the microfabrication are analyzed and then the corresponding solutions are put forward. 5. A MEMS dynamic testing system which exploit blur image synthetic technique, stroboscopic image matching technique, stroboscopic mirau microscopic interferometry technique and microscopic laser dopper vibrometer technique is set up to measure three-dimension and six-freedom micro motions of any MEMS devices with nanometer resolution.

在对硅微机械扭转镜光致动器的光机电特性系统地理论研究的基础上提出了硅微机械扭转镜光致动器的结构设计准则。3、提出了单轴双梁厚度差分结构、单轴双柔性折叠梁结构、单轴双梁垂直扭转梳齿结构、双轴四梁差动复合微镜结构以及以上四种基本结构组合后的衍生结构等五种工艺加工技术兼容的新型的硅微机械扭转镜光致动器，对器件关键结构薄厚度、高耐疲劳扭转梁进行了局部加强的变形补偿设计，建立了器件的三维实体模型以及两维降阶模型，对提出的新结构硅微机械扭转镜光致动器进行了系统的静力学、动力学、静电场、力电耦合和流体固体耦合的建模仿真与优化设计，同时设计并分析了三种可实现单芯片集成的弹性光纤定位夹紧结构。4、提出了组合体硅微加工技术与表面硅微加工技术、兼容同一套光刻版图、可分别基于SOI 晶片和普通Si 晶片、适应于制造提出的各种新结构单晶硅和多晶硅硅微机械扭转镜光致动器的三套柔性加工工艺流程，开展了一系列重要工艺步骤的单项工艺试验，对工艺流程与工艺参数进行了优化，针对加工过程中出现的具有普遍意义的典型工艺问题进行了讨论和分析，并提出了解决方法。5、创新性地将模糊图像合成技术、频闪图像匹配技术、频闪Mirau 显微干涉技术与显微激光多普勒测振技术有机结合，建立起了一套周期运动测量与瞬态运动测量相结合、单点运动测量与全视场运动测量相结合、满足不同MEMS 器件各种动态测试要求的集成的MEMS 三维六自由度微运动精密测量系统。

This invention discloses a preparation method for anti-corrosion rare earth magnet material characterizing that it takes the optimized grain-boundary phase design as the starting point on the basis of a dual alloy method to select Nd base alloy with high crystal forming ability as the assist alloy and reduces the temperature of the press mold blank in a quartz container to room temperature from over grain-boundary phase melting point with the water extraction way to get enough cooling rate and guarantee the non-grain-boundary phase, compared with the material of the same composition prepared by ordinary method, the weightlessness of this invented material reduces over 30% after testing the weightlessness of the material by laying it for 96 hours under 121deg.C, 2 atmosphere and 100% humid environment to show the advanced performance of anti-corrosion.

本发明公开了一种耐腐蚀稀土永磁材料的制备方法，其特征是它在双合金法制备工艺的基础上，以优化晶界相设计为出发点，选取具有较高非晶形成能力的Nd基合金为辅合金，并在烧结回火时将置于耐高温石英容器中的压型坯件，从晶界相熔点以上以水淬冷却的方式降温至室温，以达到足够的冷却速率，确保得到非晶晶界相，根据本发明制得的耐腐蚀稀土永磁材料，通过测量在121℃、2个大气压以及100％湿度环境下放置96小时后材料的失重情况，结果显示本发明得到的材料与常规方法制备的相同成分的稀土永磁材料相比失重减少了30％以上，充分证明其具备了更优越的耐腐蚀性能。可广泛应用于电子、汽车、计算机、电力、机械、能源、环保、国防、医疗器械等领域。

The results indicate that the flow stress of the alloy increases with increasing strain rate and decreasing deformation temperature. The flow stress increases with increasing strain until the stress reaches the peak value, then the flow stress remains constant, which indicates that dynamic recrystallization happens during deformation. The flow behaviors are described by the hyperbolic sine constitutive equation, and the activation energy calculated is 337.75 kJ/mol. The as-forged microstructure consists of refined α2/γ and γ grains, and the grains are much homogeneous than before. The B2 phase distributes uniformly at the grain boundary of α2/γ and γ grains. The B2 phase decreases with increasing deformation temperature.

结果表明：流变应力随着应变速率提高和变形温度降低而增大；在变形过程中，流变应力随着变形量增大而增大，当流变应力达到峰值后趋于平稳，表明合金在变形过程中发生了动态再结晶；热变形过程的流变应力可采用双曲正弦本构关系来描述，平均激活能为337.75 kJ/mol；从合金的组织演化过程中可以看出，合金中不均匀的原始组织得到明显均匀化，变形后的组织是由α2/γ层片晶团和γ晶粒组成的双态组织，在α2/γ层片晶团和γ晶粒的晶界交界处发现分布均匀的B2相，并且随着变形温度升高B2相数量逐渐减少。

In addition to the black-white double-lobe caused by the displacement field around pores, we demonstrate that LSC should correspond to a novel, peculiar class of anti-phase domain, of which the interior is a local isomorphism with a non-zero phason-type displacement ε〓w〓 i.e.

利用这个结果，我们发现黑白双瓣衬度是二十面体准晶中的多面体微孔引起，而环形衬度则对应于一种二十面体准晶中新奇的反相畴界，其两侧是由相位子型位移ε〓w〓＝B〓联系着的局域同晶类。

Moreover, the hot compressive deformation behavior of the RS/PM AZ91 magnesium alloy and AZ91 alloy matrix composite were also investigated, the conclusions are drawn as follows:1. The processing parameters of the atomization-twin rolls quenching technology were optimized as follows: the diameter of the nozzle 1mm, the wheel velocity 25m/s, the pressure of atomization gas 0.3MPa and Ar gas for melt injection 0.1MPa. The RS AZ91 alloy flakes exhibited fine and uniform microstructures. When the flakes were extruded at 673K, extruded velocity of 0.1mm/min and extrusion ratio of 25:1,the magnesium alloy rods with clean surface, uniform dimension and excellent mechanical properties were obtained.2. The RS AZ91 magnesium alloy powders prepared by atomization-twin rolls quenched technology exhibited fine equiaxed grains with the grain size of 1-3μm, the phase constituent included supersaturate solid solution phaseα-Mg and miner fineβ-Mg_(17)Al_(12) phase. The as-extruded materials also exhibited equiaxed grains with the size of 5-7μm and a large number of fineβ-Al_(12)Mg_(17) and fewer AlMg_2Zn phases were detected in the alloy.

本文还研究了快速凝固/粉末冶金AZ91镁合金热压缩变形流变应力行为，快速凝固/粉末冶金法原位生成Mg_2Si增强AZ91镁基复合材料，经过系统的研究，获得如下结论：1、雾化-双辊急冷法在下列工艺参数组合下：双辊线速度25m/s；喷嘴直径1mm；熔体压射压力0.1MPa；雾化气体压力0.3MPa。，可获得宏观尺寸细小、微观组织均匀细小、综合性能优良的的快速凝固AZ91镁合金细碎箔带，快速凝固箔带在挤压温度为673K、挤压速度为0.1mm/min，挤压比为25：1时，可获得的外表光洁、尺寸均匀、组织性能优异的镁合金棒材。2、雾化-双辊急冷法制备的AZ91镁合金粉末态为细小等轴晶组织，晶粒尺寸1-3μm，组织为α-Mg过饱和固溶体和微量的细小β-Mg_(17)Al_(12)相组成；粉末挤压棒材为等轴晶组织，晶粒尺寸5-7μm，组织中含有大量细小的β-Al_(12)Mg_(17)以及AlMg_2Zn析出相，室温力学性能，抗拉强度383MPa，屈服强度275MPa，断后伸长率7.5%。

The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系，空间群P2(1)/c，晶胞参数：a=848.46(3)pm，b=681.54(3)pm，c=1967.16(8)pm，α=90°，β=95.8210(10)°，γ=90°，Z=4，R_1=0.0279，wR_2=0.0724，Cu原子位于轻微变形的四方锥场底心，底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据，而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶，因而形成一维链状结构；合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ，铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O，并用元素分析，IR光谱，电子光谱和磁化率测定对配合物的组

There exists isomorphous replacement in the rutile structure, and the most prominent feature is the average content of oxides, being 1.22%, 0.39%, 0.35% and 0.22% for V 2O 5, Fe 2O 3, ZnO and CuO respectively. They substitute Ti 4+ in octahedra. The valence of V is 5, and its polyhedron is trigonal bipyramid, which causes the lattice distortion, breaks the raw octahedron symmetry into square bipyramid, and produces the microstrains in the structure.

天然含钒金红石平均含V2O5可达1.22％，Fe2O30.39％，ZnO0.35％，CuO0.22％，这些金属离子可替代八面体中Ti^4 。V以5价形式存在，配位多面体呈三方双锥，其在晶格内部对Ti的替代导致晶格畸变，打破了配位多面体原有的八面体对称而呈四方双锥的几何形态，并产生结构微应力。

Based on the research on the solidifiation of twin-roll casting strip,the analytical model and emulational model of nucleation,the growth of dendrity tip and colunar dendrity transformation to equiaxis dendrityof twin-roll casting strip solidification are established by means of the principle of metal solidification and modern computer emulational technology.

在研究双辊薄带连铸工艺凝固过程的基础上，运用金属凝固的基本原理，并用现代计算机仿真技术建立了双辊连铸薄带凝固的形核、枝晶尖端的生长动力学、柱状晶向等轴晶生长的转变的解析模型及仿真模型，为双辊连铸薄带凝固组织形成的仿真模拟奠定了基础。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。