双分子层

In this thesis, we solve this problem by combining the overall functions of potential interactions, which include the van der Waals attractive potential, repulsive electrical double layer potential, Born repulsive potential and magnetic interaction, as well as the hydrodynamic interaction, the gravity and the Brown diffusion, and therefore unveil the significant influence of the interparticle potential on the sedimentation of stable colloidal systems.

在本论文中，通过综合考虑胶体粒子间的势力相互作用——包括vander Waals分子引力势、双电荷层静电斥力势、Born排斥势和磁力势等，还有流体动力相互作用、重力相互作用、布朗热动力等诸多因素的影响，我们解决了这一难题，揭示了粒子间势给胶体系统的沉降行为带来的重大影响。

DEMS combined with the dual thin layer flow through cell is a good tool for the quantitative study on the oxidation of small organic molecules.

微分电化学质谱仪与双薄层流动电解池结合是一个很好的定量研究小分子有机物氧化的有力工具。

At least one layer of said I-Polar is optically anisotropic and is made by means of Cascade Crystallization Process, is characterized by a globally ordered biaxial crystalline structure with an intermolecular spacing of 3.4 } 0.3 A in the direction of one of optical axes, is transparent in the visible spectral range, and is formed by rodlike supramolecules representing at least one polycyclic organic compound with a conjugated -system and ionogenic groups.

所述I-Polar中至少有一层是光学各向异性的，并通过级联结晶工艺制得，其特征是在一个光轴方向上具有3.4±0.3的分子间间距的全局有序的双轴晶体结构，该层在可见光光谱区域内是透明的，并由代表至少一种具有共轭π体系和离子型基团的多环有机化合物的棒状超分子形成。

We found that during the growth process the double steps first grow separately and the connected by short bridge before tangential growth. After eighth or ninth layer the spiral steps would merge into intact elliptic layers. At the merging point right-handed spiral sources might appear but the left ones always overgrow it which made the whole growth topography looked like left-handed apparently. It indicated that the EAFP molecules has strong ability to adjust itself to adapt the environment. 5. Through various analysis of interactions in the EAFP crystals it indicated that there were 218 residue interactions between 12 symmetry-related EAFP molecules around one EAFP molecule, 18 strong ones and 72 weak ones .

EAFP在低过饱和度下的螺旋生长过程中会出现台阶的合并，从而表现出单-双的螺旋台阶，在小范围扫描中捕获到了这种现象，使得对螺旋生长台阶的合并过程有了更加深入的认识；并且台阶的生长受到沿晶体学b轴方向上的21螺旋对称的控制；当台阶生长至第八到第九层时，螺旋台阶会自动地形成完整的生长层，这充分说明了EAFP分子或分子簇具有良好的自身调节能力，这样在晶体生长过程中，晶体的缺陷减少，晶体质量提高，这也可说明EAFP晶体的x射线衍射能力很强的原因。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

The results can be expressed as follows:(1) With the increase of water phase content, the amine salt aggregated orderly in different forms such as W/O micro-emulsion, nodus-knot catenulate aggregates, layer liquid crystal and O/W micro-emulsion.(2) In layer liquid crystal, SO〓 mainly combined with amine salt cation by two oxygen atoms in bridge.(3) In UV-VIS spectrum of layer L. C., there is an absorption about 500 nm and "light short circuit"appeared about 430 nm. These phenomena may be very important for measuring the distance between the layers of the L.

研究发现该体系随水相含量的增加，胺盐发生不同形式的有序缔合，分别形成了W/O型微乳液、&节-结&型链状缔合体、层状液晶和O/W型微乳液：在层状液晶中，SO〓主要以桥式双齿配位形式存在，中性胺分子有利于体系中液晶的形成；层状液晶于500nm波长处有一吸收峰，在430nm附近发生&光短路&现象，该现象可能对测定层状液晶的层间距有重要意义。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

The main goal of this research is to establish a conventional electroanalytical method for studying the deterioration kinetics and mechanism of the polymer/metal interface.

本课题研究的主要目标是建立以水分子为探针，通过测量聚合物/金属体系的双电层电容变化及其规律，建立简便易行的研究金属/涂层界面行为的电化学分析方法。

From the viewpoint of electrochemistry and biology, the sensing mechanism of s-BLM was analyzed utilizing the electric double layer theory. The author described qualitatively the functional mechanism of modifier recuring to the knowledges of molecular biology. Stability mechanism of s-BLM added trehalose or cholesterol was briefly investigated.

从电化学和生物学角度，利用双电层理论分析了s-BLM的敏感机理，借助于分子生物学相关知识对修饰剂的作用机理进行了定性描述，并就海藻糖和胆固醇对膜的稳定作用机理进行了简要分析。

Electrostatic potential and velocity of water molecules across the channel are also calculated in continuum theory for comparison.

模拟结果显示，双电层内的静电势大体上成线性下降，偏离了连续性理论的预测曲线；分子动力学方法所得到的流速值要比与连续性理论预测结果低50%。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。