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We introduce two pyridinedicarboxylate (2,5-H2pdc and 2,6-H2pdc) ligands, under hydrothermal or solvothermal condition, to yield 7 complexes with InCl3. Complex 17 presents a rare example of chiral binodal (4,8)-connected lattice with self-interpenetration.

选择了两种吡啶二羧酸配体: 2,5-吡啶二羧酸(2,5-H2pdc); 2,6-吡啶二羧酸(2,6-H2pdc)和InCl3反应合成了七个配位化合物其中17表现了一例少有的手性的(4,8)连接的双节点自穿插拓扑结构。

I am currently 37 weeks pregnant already, make B-, fetal biparietal diameter was 9.6, fetal position for the head position, the placenta for 2, Palais high of 36, abdominal circumference for the 102, can I shun the middle?

我目前怀孕已37周,做B超,胎儿双顶径为9.6,胎位为头位,胎盘为二级,宫高为36,腹围为102,请问我能否顺产?

Based on the input data, a timing detector 130 detects a timing which corresponds to boundaries between bits of a data portion before biphase encoding.

根据输入数据,定时检测器(130)检测对应于双相编码之前数据部分的位之间边界的定时。

Based on the analysis on the transformation model of anterior-posterior and lateral projection spaces, initial registration parameters are automatically estimated and the mapping from the 3D surgical space to the CT space is established by using the biplanar geometric constraint.

通过分析正侧位投影空间变换模型,利用该双平面几何约束实现自动的配准初值估计并建立3维手术空间与CT空间的映射。

The tin atoms are five-coordinated with geometry of distorted trigonal bipyramid.

两个锡原子为五配位的三角双锥构型。

The structure is a distorted triangular bipyramid with five coordinated central tin atom.

配合物中锡原子呈五配位畸变三角双锥构型。

In the complex, the tin atom is hepta-coordinated in a distorted pentagonal bipyramid including a bridging pyridyl N atom, by which the one-dimensional infinite chain is formed.

结果表明,该化合物中锡原子配位数为7,处在畸变五角双锥配位场中,化合物通过吡啶基氮原子的桥连作用形成了一维无限链状结构。

Bipyridyl and 1,10-phenanthroline (L3), Cl3SnCH2CH2COORo L (L= L1, a; L2, b; L3, c), formed by low-heating solid-state reaction. The crystal structures of 1 and 2 show that the tin atom adopts a distorted trigonal bipyramid geometry via intramolecular carbonyl oxygen to tin coordination [the distances of Sn-0 bond are 0.2351(6) ran for 1 and 0.2362(3) nm for 2]. Compound 1 belongs to monoclinic with space group P2/c, a = 0.9842(2) nm, b =1. 0923(8) nm, c = 1.23948(11) nm,/?= 93.894(15)°, V= 1.3294(4) ran3, Mr = 366.23, 7 = 4. Compound2 belongs to monoclinic with space group P2{/c, a = 1.04443(9) nm, b = 1.04823(7) nm, c = 1.28113(9) nm,/= 90. 953(8)°, V= 1.40239(19) nm3, Mr = 380.25, Z = 4

利用元素分析、红外光谱、核磁共振对其结构进行了表征,并通过X射线单晶衍射测定了1和2的晶体结构,二者均为具有分子内羰基氧原子配位的畸变三角双锥结构。1属于单斜品系,空间群P21/c, a=0.9842(2)nm,b=1.0923(8)nm,c=1.23948(11)nm,β=93.894(15)°,V=1.3294(4) nm^3,Mr=366.23,Z=4.2属于单斜晶系,空间群P21/c,a=1.04443(9)nm,b=1.04823 (7)nm,c=1.28113(9)nm,β=90.953(8)°,V=1.40239(19)nm^3,Mr=380.25,Z=4。

Fe(superscript 3+) occupied both tetrahedral sites in spinel block and trigonal bipyramid sites in mirror plane for LaFeMnAl(subscript 12-x-y)O19 (x=0.5, 1) hexaaluminate.

LaFeMnAl(下标 12-x-y)O19(x=0.5, 1)中Fe以Fe(上标 3+)位于六铝酸盐尖晶石结构中的四面体位和镜面层结构中的三角双锥位,其中后者为N2O分解的主要活性中心。

The Sn atoms are considered as five-coordinate and exist as distorted trigonal bipyramidal geometry in a one-dimensional chain.

合成化合物的中心Sn原子为五配位,构成以Sn为中心,扭曲的三角双锥构型,通过分子间氢键形成一维链状结构。

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