双

Starting from the hydroxylamine (dimethyl amino ethanol, triethanolamine) and 1, 3-propane sultone, a series of hydroxyl and sulfonyl dual-functionalized zwitterionic salts were synthesized. Then dual-functionalized ionic liquids containing both hydroxyl and sulfonyl functional groups were produced successfully by zwitterionic salts and three kinds of strong acids (p-toluene sulfonic acid, trifluoromethanesulfonic acid, methanesulfonic acid) respectively. The structure of zwitterionic salts and dual-functional ionic liquids were confirmed by the 1H NMR and IR.

以羟基有机胺(N，N-二甲基乙醇胺，三乙醇胺)为原料与1，3-磺酸内酯反应合成了一系列含有羟基和磺酸基双官能团的内盐，并将所得到的内盐分别与三种强酸(对甲苯磺酸，三氟磺酸，甲磺酸)反应，成功地合成了双功能化室温离子液体，并通过红外光谱、核磁氢谱测定，证实了内盐和双功能化离子液体的结构。

In only 12 month, Tanan Shenran 150 thousand M3 per day LNG project has finished the work from the very beginning to the very end. This project has created a milestone on China gas history, it is not only the first on constructing period, but also make many first on technology: The first self-owned intellectual property LNG plant which is nitrogen expanding and recycling refrigerating in China; the first plant which are all made in China; the first plant which use the parallel connection temperature expander refrigerate technology; the first use the pressure dryness vaporizer technology on Nitrogen gas liquefaction and purity system; the first use the deep fat stove technology in purity system; the piston nitrogen compressor is the biggest in China and etc.

短短12个月内，泰安深燃日产15万立方米液化天然气工程项目完成了从立项到投产的全部建设工程，该套项目的顺利投产完成创造了中国燃气史上的一个新的里程碑，不仅在建设周期上创造了第一，在技术方面同样创造了多个第一：我国首个具有自有知识产权的氮气膨胀、循环制冷液化天然气设备，填补了国内在这一技术领域的空白，对我国名族天然气液化事业的发展产生了积极的推动作用；首次实现设备国产化达到100%；首次采用并联双温区的膨胀机制冷技术；首次将等压干燥脱水技术应用于天然气液化系统、净化系统；首次在净化系统采用了导热油炉、单炉双温区共用形式；所采用的单级双列活塞式氮气压缩机位国内最大等技术。

In only 12 month, Tanan Shenran 150 thousand M3 per dayLNG project has finished the work from the very beginning to the very end. This project has created a milestone on China gas history, it is not only the first on constructing period, but also make many first on technology: The first self-owned intellectual property LNG plant which is nitrogen expanding and recycling refrigerating in China; the first plant which are all made in China; the first plant which use the parallel connection temperature expander refrigerate technology; the first use the pressure dryness vaporizer technology on Nitrogen gas liquefaction and purity system; the first use the deep fat stove technology in purity system; the piston nitrogen compressor is the biggest in China and etc.

短短12个月内，泰安深燃日产15万立方米液化天然气工程项目完成了从立项到投产的全部建设工程，该套项目的顺利投产完成创造了中国燃气史上的一个新的里程碑，不仅在建设周期上创造了第一，在技术方面同样创造了多个第一：我国首个具有自有知识产权的氮气膨胀、循环制冷液化天然气设备，填补了国内在这一技术领域的空白，对我国名族天然气液化事业的发展产生了积极的推动作用；首次实现设备国产化达到100%；首次采用并联双温区的膨胀机制冷技术；首次将等压干燥脱水技术应用于天然气液化系统、净化系统；首次在净化系统采用了导热油炉、单炉双温区共用形式；所采用的单级双列活塞式氮气压缩机位国内最大等技术。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本论文的主要贡献为：(1)合成了配体NTB的七个新型单核配合物；(2)合成了十七个铁、锌、钴及铜系列混桥双核配合物，其中双核钴和双核铜配合物为反铁磁偶合；(3)选用多吡啶配体tpdp和TPA，改变桥联配体，合成了十个四核配合物；(4)选择配体KH〓pdc，采用水热合成方法得到了反铁磁性一维链状锰、铜配合物；以草酸根为桥联配体，合成了配体tpdp的一维链状铜配合物，该化合物为铁磁偶合，文献较少报道。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1，4-丁二胺催化氧化环己烷的催化活性被测试，结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性，而单核的Fe化合物是非催化活性的。

Vein of Galen thrombosis have a special CT and MR appearance,that is symmetric hypodense areas or long-T1 and long-T2 signal of bilaleral thalami,internal capsules and basal ganglias.Thrombus and its changing maybe directly observed on CT and MRI.

Galen静脉血栓有特征性的CT及MR表现，即双丘脑、双内囊及双基底节区对称性低密度影和长T1、长T2异常信号，CT和MR可直接观察栓子及其变化。

Results MRI showed symmetric abnormal signals in basal ganglia in 27 patients, in thalami and dentate nucleus in 21 patients, and in corona radiata-centrum ovale in 9 patients. All the lesions were hyperintensity on T1WI. Local hypointensity in basal ganglia was found in 4 patients, while hyperintensity or slight hyperintensity on both T2WI and T2-FLAIR were found in 26 patients, and slight hyperintensity with hypointensity on both T2WI and T2-FLAIR in 1 patient.

结果 27例颅脑MRI表现为双侧基底节区片状对称性异常信号，21例双侧丘脑、齿状核片状异常信号，9例双侧放射冠－半卵圆中心见片状对称性异常信号；27例T1WI上见高信号区，其中4例基底节区病灶内见小片状低信号；26例T2WI及T2-FLAIR见高或稍高信号，1例见稍高、低混杂信号。

According to the nutritional needs of B.bifidum,based culture and stimulated factors were optimized by quadratic design.The optimum based culture was as following: yeast extract was 0.9%,tryptone was 0.3%,soya peptone was 0.3%,glucose was 2.0%,bifidus was 0.8%,growth factor was 10%.

针对两歧双歧杆菌的营养需要，采用正交试验设计优化增殖培养基，结果表明，酵母膏是影响短双歧杆菌的显著因素，最佳的优化培养基配比是：酵母膏0.9%，胰蛋白胨0.3%，大豆蛋白胨0.3%，葡萄糖2.0%，双歧因子0.8%，生长因子10%。

A two-lane road is full duplex. A connection that allows traffic either way, but only one way at a time is called half duplex. A single railroad track is half duplex.

一个两条通道是全双工，允许使用任一通道的连接，但是每一次只使用一个通道就被称为半双工，单一的道路轨迹是半双工。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。