原子

The metal ions of the dinuclear copper complex of [Cu_2_2Cl_4] are linked by two N~1,N~2 1,2,4-triazole bridges,and the central Cu ions have distorted trigonal bipyramid geometries. The central Cu ion of [CuL22]·H2O has a centrosymmetric and distorted tetragonal-octahedral geometry. The metal ions of the dinuclear manganese complex of [Mn_2L_2_2Cl_2(H_2O)_2] are bridged by two chlorine atoms, and the central Mn ions have distorted tetragonal-octahedral geometries. Part III.

配合物[Cu_2_2Cl_4]是通过配体L的1，2，4-三唑环上两个氮原子(N~1，N~2)桥联形成的双桥双核配合物，每个中心铜离子都具有畸变的三角双锥构型；配合物[CuL22]·H_2O的中心铜离子具有中心对称的畸变八面体构型；配合物[Mn2L2_2Cl_2(H_2O)2]是通过两个氯原子桥联形成的双桥双核配合物，每个中心锰离子都具有畸变的八面体构型。

The Xray diffraction analysis of the compounds (3) and (4) shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a fivemembered ring in which the metal exhibits a distorted trigonal bipyramidal geometry.

并通过X-射线衍射测定了（3）和（4）的晶体结构，其空间群均为P2〓/c，晶胞内分子数Z=4，分子结构是以锡原子为中心金属原子、含分子内O→Sn配位键五员环的扭曲三角双锥结构，碳碳双键的两个氢是顺式构型。

The crystal structures of two complexes have been determined by X-ray diffraction as: complex (11) is distorted octahedron configuration,α=15. 9002 (6), b=16. 2413 (5), c=23. 4401 (8)〓,β=90°, V=6053. 2 (4)〓, Z=8 and R=0.0531; complex (8) is trigonal bipyramidal configuration,α=9. 3476 (8), b=17. 4236 (13), c=9. 7836 (8)〓,β=91. 197 (3)°, V=1593. 1 (2)〓, Z=2 and R=0.0325, which shows that three secondary amine groups (N-1, N-2, N-3) of the glycosylamine ligand forms the equatorial plane, and the tertiary amine (N-4) and one Cl〓 are pointed on the apical positions.

分别对其进行X-ray衍射分析可以得出：配合物(11)的晶体数据为α=15.9002(6)，b=16.2413(5)，c=23.4401(8)〓，β=90°，V=6053.2(4)〓，Z=8 and R=0.0531，为畸变的八面体构型，而配合物(8)中，α=9.3476(8)，b=17.4236(13)，c=9.7836(8)〓，β=91.197(3)°，V=1593.1(2)〓，Z=2 andR=0.0325，为三角双锥构型，糖胺配体的三个氮原子（N-1，N-2，N-3）位于赤道平面上，而另外一个氮原子（N-4）和一个Cl〓位于轴向上。

In the crystal, the tin atoms are five-coordinated in trigonal bipyramidal structure by bridging pyridine N atoms, resulting in the chain organotin compound.

该化合物中心锡原子为五配位三角双锥构型，并且通过4-吡啶甲酸配体的氮原子桥联作用形成一维无限链状结构。

It is found that in this structure the molybdenum atom is coordinated by six sulfur atoms of three 1, 1 -dicynoethylene 2 ,2 -dithiolate(i-mnt2 -) ligands and a terminal oxygen atom, forming a distorted pentagonal bipyramidal structure.

结构分析结果说明Mo原子与三个配位基的六个硫原子和一个端基氧形成扭歪五角双锥结构。

The spectrum peaks nearby 530nm and 480 nm are corresponding with BTSD and BMD respectively. It is found from measurement that the luminescence peak from BMD is bluely shifted. The atoms of BTSD nearby dislocation core are affected by tensile stress along the Burger's vector direction leading to its band gap narrowed. In addition, there is the effect of part quantity of edge dislocation in BMD existed. Part of atoms in BMD are strained by compressive stress leading to its band gap narrowed, in other words, the wavelength from BMD is shorter than that from BTSD.

从测试结果中还发现BMD 的发光位较BTSD有所蓝移，分析认为BTSD位错芯附近原子沿伯格斯矢量方向只受到拉应力，致使禁带宽度变窄，BMD由于除了具有螺型位错的分量外还具有部分刃型位错的分量，而刃型位错中有部分原子受到压应力的作用，导致禁带宽度增宽，从而使得BMD的发光波长比BTSD短

Comparing with the photodissociation of bromobenzene, the extra fluorine atom of fluorobenzene accelerates the rate of the internal conversion from the state to the state, and the different positions on the phenyl ring also have distinct effect on it.

与溴苯相比，氟溴苯上的氟原子显著加快了解离的速度，并且氟原子在苯环上的位置的不同对解离速度也有显著影响。

By using Atomic Absorption Spectrophotometry and Atomic Fluorescence Spectrophotometry, the contents of heavy metals in sullages and the flocculated sullages were analyzed.The Samples were collected from the selected region of the six tipical areas in Jiangsu province for four seasons, including Ancinet Canel in Wuxi, Hengcaolugang in Wujiang, Meiliang Bay in Taihu, Hongze Lake in Hongze, Xiexinggang in Qidong, the port in Lianyungang.

本文运用原子吸收光谱法和原子荧光光谱法，分析了江苏省内的这六个典型地区的春夏秋冬四个季节的淤泥不同层面的重金属含量及絮凝前后泥样和水体中的重金属含量。

It was found that the condensation could be completed within 24 hours at 60°C in a solution containing 10mg CAWs, 20mg 2-aminoethyl mercaptan, 10mL CH2Cl2, 1 mL triethyl amine and 0.2g DCC (N, N'-dicyclohexyl carbodiimide).

实验结果表明：10mg经浓硝酸氧化处理过的碳原子线在含有20mg巯基乙胺、10mL CH2Cl2、1mLN3、0.2g DCC的液相反应体系中，60℃温度下作用24h可完成缩合反应，生成巯基化碳原子线。

It was revealed that the film was constituted mainly by Zr-C, C=C (s^2) and C-C(sp^3) bonds; structure of the films was crystalline ZrCN embedded in an amorphous carbon and carbonitride matrix. With increasing flow rate, film Zr content decreased, but C and N contents increased.

实验结果表明薄膜结构是由ZrCN晶粒镶嵌在无定形碳和碳氮化合物基体中；膜中的化合键主要以Zr-C，C=C(sp^2)和C-C(sp^3)形式存在；随着混合气体流量的增加，薄膜的锆原子分数减小，而N和C的原子分数逐渐增大。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。