原子

What is called atomic proposition is a deep thinking on atomic events of the objective world. Atomic events di- vide into two major categories: closed atomic events and open atomic events.

所谓原子命题就是关于客观世界的原子事件的思考；原子事件分闭原子事件和开原子事件两大类。

How did the synthesis elaborate Bohr according to the hydrogen atom spectrum experiment rule and Planck, in Einstein's quantum theory introduction atom, thus draws out the energy level rule, the Bohr atom theory's success has triggered the people to the atomic phenomenon and the atomic structure widespread deep research, promoted the atomic physics development.

综合论述了玻尔如何根据氢原子光谱实验规律并将普朗克、爱因斯坦的量子理论引入原子内部，从而引出能级规律，玻尔原子理论的成功触发了人们对原子现象和原子结构的广泛深入研究，推动了原子物理学的发展。

In this thesis, a semi-classical model of the force on an atom is used to describe the motion of a two-level atom interacting with a standing wave laser field. The velocity dependent force and momentum diffusion are derived through optical Bloch equations by using the matrix form of the continued fraction technique. By investigating the dynamic properties of atoms in laser field, we can control and manipulate the mechanical motion of an atom.

本文利用半经典理论，从二能级原子在激光驻波场中所满足的运动方程出发，推导出密度矩阵元所满足的递推关系，利用矩阵连分数方法求解出密度矩阵元，从而求出依赖于原子运动速度的光压力与动量扩散系数，通过讨论原子在激光场中的动力学行为，为原子在激光场中被囚禁、形成原子列阵以及可控制的量子态，从而为量子信息处理提供理论基础。

The results show that at finite temperature the thermal expansions for interatom ic spacings near the ends of monatomic chain are larger than those in the middle of the monatomic chain, and the thermal expansion coefficients near the ends of monatomic chain are smaller than those in the midd le of the monatomic chain.

研究结果表明，在有限温度下，纳米单原子链中靠近两端的原子间距的热膨胀大于内部的原子间距的热膨胀，而原子链中靠近两端的原子间距的热膨胀系数小于内部的原子间距热膨胀系数。

To conduct such research a new experimental apparatus was established.With this setup the two-photon excitation spectra of Barium and one-photonexcitation spectra of Strontium Rydberg atoms were recorded and identified.The Stark spectra of Strontium atoms showed the "l-mixing" and "n-mixing"features. By changing laser wavelength and external electric field strengthsimultaneously, the scaled-energy spectra of Strontium 〓 Rydberg atomsat constant scaled-energy ε=-3.00,-2.50 and -1.88 were recorded for thefirst time. The experimental spectra were Fourier transformed and yielded therecurrence spectra.

主要工作包括：建立了一套用于外电场原子光谱研究的原子束实验装置；获得了Ba原子的双光子、Sr原子的单光子零场激发谱，并对各谱线进行了标识；进行了Sr原子电场Stark效应研究，观察到了低场时能级角量子数"l"混合区及高场时主量子数"n"混合区的存在；首次获得了Sr原子在标度能量ε=-3.00、-2.50及-1.88时〓高Rydberg态电场标度能谱及傅立叶变换后的电子回归谱。

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型，其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位， 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链， Zn2原子的另外2个反式赤道配位点被2个水分子氧占据，同时这两种Zn原子的轴向配位点均被4，4'-联吡啶的氮原子占据，形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构，游离的2个水分子通过氢键作用形成二聚体，并与酒石酸根中未与Zn配位的羧酸氧连接，把二维层状结构连接成三维网状的超分子结构。

With proper atomic coherence, the performance has the following advantages compared with that of the velocity selection of the ultracold two-level atoms by the micromaser: high resonant transmitted efficiency, low unresonant transmitted efficiency, and large velocity selection scale. The second part includes the fifth chapter.

原子透射几率只受到一种量子干涉效应的影响，其来源为V型的两个跃迁通道，因此Micromaser对入射超冷V型三能级原子束速度的选择性能深深地受到原子相干性的影响，我们发现选取适当的原子相干参数以及其它参数，速度选择性能可以达到很理想的状态：共振原子透射效率高、透射原子束的速度纯度好、速度选择范围大。

For comp ound 7, the cage is consisted by six MoO〓 and four PO〓. The six MoO〓 octahedrons have consisted to the loop structure, the there PO〓 tetra hedron become triangle and the other one lies the centre. The one oxygen of two MoO〓 octahedron is coordinated to Mn atom which linked the other cage like this cag e and this Mn have six ligands.

在化合物7中，每一个笼由6个MoO〓八面体和4个PO〓四面体构成，6个MoO〓八面体构成环，四个PO〓四面体形成一个三角形在其上面，4个P和6个Mo具有C〓的对称性，每二个MoO〓八面体提供一个O原子与Mn原子配位，这个Mn原子再与相同的这样的笼相连，形成一个中间细两端粗的形状，这个Mn原子是6配位的，每一个这样的笼再通过一个Mn原子连接起来，形成二维的网状结构，而这个Mn原子是五配位的。

The calculated results show that azido in azides has linear structure , the most optimized CaN6 has linear structure , and the most optimized (CaN6)n (n=2～5) clusters have chain structure of perpendicularity of approximate diamond composed by two azido with two Ca atoms . The middle N atoms of azido show positive, the N atoms at both ends of azido show negative, and the N atoms effected with Ca atoms directly show more negative . There is strong ionic bond between the Ca and N atoms. The IR spectra of the most optimized (CaN6)n (n=1～5) clusters have four vibrational sections , the whole strongest vibrational peak lies in 2195～2280cm-1,and the vibrational mode is anti-symmetric stretching vibration of N-N bonds in azido . Stability analysis show that (CaN6)3 and (CaN6)5 clusters are more stable than other clusters .

结果表明，叠氮化合物中叠氮基以直线型存在，CaN6团簇的最稳定结构为线型结构，(CaN6)n(n=2～5)团簇首先由两个叠氮基与两个Ca原子构成一个近似菱形，再由菱形相互垂直形成链状最稳定结构；叠氮基中间的N原子显示正电性，两端的N原子显示负电性，且与Ca直接作用的N原子负电性更强，金属Ca原子和N原子之间形成很强的离子键；(CaN6)n(n=1～5)团簇最稳定结构的IR光谱分为4个部分，其最强振动峰均位于2195～2280cm-1，振动模式为叠氮基中N-N键的反对称伸缩振动；稳定性分析显示，(CaN6)3和(CaN6)5团簇相对于其他团簇较为稳定。

For the calculations of Mon (n= 2-55) clusters, the linear and planar clusters have a strong tendency to form diatomic pairs to assemble short-long bonds alternation structures which makes them like non-metallic clusters, the short bonds are characterized as covalent non-metallic bonds and the long ones are much like weak metal bonds.

本文首先计算了各种不同结构的Mon（n=2-55）原子簇，发现一维和二维Mo原子簇表现出了一定的非金属原子簇的性质，簇中原子有明显的成双原子对趋势，致使原子簇具有短-长键交替的几何结构，短键和长键分别呈现强共价键和弱金属键的特性。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。