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The binding energy of imprinted molecule with functional monomer was calculated by using the density functional theory method.

采用密度泛函方法计算功能单体与印迹分子的结合能,以与目标分子结合能最大的单体分子来合成分子印迹聚合物。

The methacrylic acid, TRIM and SDBS were used as functional monomer, polymeric matrix and dispersant respectively.

本文以Cu2+为印迹离子,以MAA为功能单体,TRIM为聚合物母体,以SDBS为分散剂,利用反相乳液-悬浮聚合法制备了Cu2+印迹聚合物微球。

Western blot and the immunoblot results indicate that the antibodies not only can react with silicon-binding proteins of rice, but also can cross react with the proteins of other silicon-accumulated graminaceous plants, while it does not react with the proteins of non-silicon accumulated dicotyledonous plants and BSA. These findings indicate that the homologous proteins of SBP117 are widely existed in the graminaceous plants.

蛋白质印迹和免疫印迹检测表明,SBP117的抗体不仅能识别水稻硅结合蛋白,而且与其他累积硅的禾本科植物中提取的硅结合蛋白有交叉反应,但它不识别不累积硅的双子叶植物番茄叶中的蛋白质以及牛血清蛋白,说明与SBP117同源的硅结合蛋白广泛存在于禾本科植物之中。

Evaluation and recognition mechanism of molecularly imprinted polymer.

本论文以分子印迹理论为指导,以不同的分子为模板合成了不同的分子印迹聚合物,系统研究了分子印迹聚合物的几个方面:(1)MIP的评价和识别机理。

Our results suggest that the oxhide pastern is the best way to observe stomatal movement of A.corniculatum compared with the puddle method and the nail poish pastern.

结果表明:搅碎法、指甲油印迹法、牛皮胶印迹法三种观察气孔方法中,牛皮胶印迹法是观察气孔开度变化的最佳方法。

The results suggested that the oxhide pastern print was the best way to observe stomatal movement of A. comiculatum compared with the blender method and the nail enamel print method.

结果表明:在搅碎法、指甲油印迹法、牛皮胶印迹法三种观察气孔方法中,牛皮胶印迹法是观察气孔开度变化的最佳方法。

It was found that SMIPMs exhibited higher rebinding rate and better the specific rebinding property than EMIPMs did.

表面印迹聚合物微球比包埋印迹聚合物微球表现出更好的分子印迹特异重结合性如更快的重结合速度等。

It is found that many factors in gelling, removing template and rebinding process such as pH values and ionic concentration etc. make an important influence on the parameters such as rebinding capacity and imprinting efficiency etc. of protein-imprinted hybrid microspheres.

研究还表明,凝胶化、洗脱和重结合过程中的诸多因素如pH值和离子强度等对蛋白质大分子印迹杂化聚合物微球的分子印迹特异重结合性参数如重结合容量和印迹效率等产生重要影响。

Molecular imprinting polymers of pueraria were prepared with acrylamide as functional monomer.

首次将分子印迹技术用于天然产物的分离,结果表明制备的印迹聚合物具有较好的印迹效果。

objective: to prepare the molecularly imprinted composite membranes with propofol as template.methods: with the ultraviolet light and initiator, template molecular propofol, functional monomer methacrylate and crosslinking agent ethylenegly-coldimethacrylate formed molecularly imprinted composite membrane through polymerization on the surface of polyvinyli-dene fluoride microporous membrane.inspection of the combination of template molecule and functional monomer, characterization of the membrane surface morphology with scanning electron microscopy.results: the morphology of composite membranes was well.propofol bonded to methylacrylic acid with hydrogen bond.conclusion: the method of ultraviolet light-struck is feasible for preparation of molecularly imprinted composite membranes with propofol as template.

目的:制备异丙酚分子印迹复合膜。方法:在紫外光照和引发剂的作用下,模板分子异丙酚、功能单体甲基丙烯酸和交联剂乙二醇二甲基丙烯酸酯在聚偏氟乙烯微孔滤膜表面聚合形成分子印迹复合膜,考察模板分子和功能单体的结合特性,用扫描电镜表征膜的表面形态。结果:复合膜形态良好,异丙酚和甲基丙烯酸以氢键的方式缔合。结论:用紫外光照射法可以制得异丙酚分子印迹复合膜。

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