卤烷

Determination of Theobromine and Caffeine in Cocoa Powder and Cacao Shell Tincture by High Performance Liquid Chromatography

性质：N-卤代胺在浓硫酸中加热，消除一分子卤化氢，环化成吡咯烷衍生物。

The reaction of perfluoroalkyl bromide and a,w-perfluoralkylene dibromide in sulfinatodehalogenation system with olefins and the differences in behavior between perfluoroalkyl bromides and their corresponding iodides are reported.

本文报道溴代全氟烷和α，ω-二溴代全氟烷在亚磺化脱卤反应体系中与烯烃的反应及其与相应的碘代全氟烷的区别。

The probable reactions of the adamantane,for example halogenation , alcoholization, nitration and alkylation,are summarized.

文章从分子设计的角度综述了金刚烷可能发生的化学反应，如卤化、羟基化、硝化、烷基化等；同时探讨了金刚烷化学反应的机理，为金刚烷在精细化工领域的深层次应用打下基础。

Syntheses of PPVs derivatives with alkoxyl as side-chain by the method of dehalogenating condensation reaction Those PPV derivatives, named poly (2-methoxy-5-alkoxyl) phenylene vinylene,containing alkoxyl on benzene ring, were placed on emphasis in this paper.

一。通过强碱诱导的去卤缩合法合成支链含不同烷氧基的PPV衍生物本文首先重点研究了支链中含不同链长烷氧取代基的PPV衍生物：聚(2-甲氧基-5-烷氧基)对苯乙炔。

The present invention relates to compounds of formula wherein R is hydrogen, lower alkyl, lower alkoxy, halogen or lower alkyl substituted by halogen; R is hydrogen or halogen; or R and R are together with the carbon atom to which they are attached -CH=CH-CH=CH-; R is hydrogen, lower alkyl, phenyl optionally substituted by halogen, or is hetaryl, optionally substituted by lower alkyl; R is hydrogen, lower alkyl, phenyl, benzyl, lower alkenyl, lower alkoxy, phenyloxy, benzyloxy, S-lower alkyl, halogen, CN, lower alkyl substituted by halogen or O-lower alkyl substituted by halogen; R is hydrogen or lower alkyl, aryl is phenyl or naphthyl; n is 1, 2 or 3; m is 1 or 2; and pharmaceutically acceptable acid addition salts and tautomeric forms thereof.

本发明涉及式化合物及其可药用的酸加成盐和互变异构形式，其中R 1 是氢、低级烷基、低级烷氧基、卤素或被卤素取代的低级烷基；R是氢或卤素；或R 1 和R与它们连接的碳原子一起是-CH＝CH-CH＝CH-；R 2 是氢、低级烷基、任选被卤素取代的苯基或者是任选被低级烷基取代的杂芳基；R 3 是氢、低级烷基、苯基、苄基、低级链烯基、低级烷氧基、苯氧基、苄氧基、S-低级烷基、卤素、CN、被卤素取代的低级烷基或被卤素取代的O-低级烷基；R 4 是氢或低级烷基，芳基是苯基或萘基；n是1、2或3；m是1或2。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1，2-氧硼杂环戊烷与〓反应，再经PCC氧化，分子内缩合得到二氢茉莉酮。1，2-氧硼杂环戊烷的C-B键除氧化断裂之外，也能够在〓或KF作用下卤化断裂成碳卤键。

In the presence of palladium catalyst and triphenylphosphine, alkynyl Grignards or alkynyllithiums could successfully couple with alkyl bromides and iodides. Aryl-substituted propargylic dithioacetals could also be obtained by this strategy.

在钯触媒和三苯基磷的存在下，我们可利用炔基格林那试剂或炔基锂和简单的卤烷进行偶合，而这样的反应条件也能应用在苯基取代炔丙基硫缩酮衍生物的合成上。

By reaction of alkyl halide with metallic sodium or hydrogen acid to restore the alkyl halide obtained.

可由卤代烷与金属钠反应或以氢碘酸还原卤代烷制得。

Besides, n-butyl and sec-butyl tosylate that are difficult for oxidative addition can react with phenylmagnesium bromide to form corresponding cross-coupling products. Primary alkyl halide which contains β-hydrogen and is relatively hard to undergo the reaction , n-butyl chloride for instance, can react with aryl Grignard reagents in the presence of NiB alloy as well.

此外，难以进行氧化加成的对甲苯磺酸正丁酯和对甲苯磺酸仲丁酯可以与苯基溴化镁作用生成相应的交叉偶联产物；反应相对困难的含β-H的伯卤烷，如：正氯丁烷也可以在NiB催化下与芳基格氏试剂发生偶联。

The novel molecular topological index was recommendedrelating to such atomic properties as electronegativity,electron number of valence shell,number of bonding electrons,the main quantum number of valence shell and bond length.

采用该拓扑指数对饱和烷烃、烷基苯、烷氧氯硅烷、卤代苯、含氮杂环化合物、碱金属卤化物及卤化锡的性质/活性进行了相关关系的研究。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。