卤代烷

Determination of Theobromine and Caffeine in Cocoa Powder and Cacao Shell Tincture by High Performance Liquid Chromatography

性质：N-卤代胺在浓硫酸中加热，消除一分子卤化氢，环化成吡咯烷衍生物。

The reaction of perfluoroalkyl bromide and a,w-perfluoralkylene dibromide in sulfinatodehalogenation system with olefins and the differences in behavior between perfluoroalkyl bromides and their corresponding iodides are reported.

本文报道溴代全氟烷和α，ω-二溴代全氟烷在亚磺化脱卤反应体系中与烯烃的反应及其与相应的碘代全氟烷的区别。

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应，由于溴代苯乙酮是含有羰基的卤代烃结构，它可以发生亲电取代和亲核加成反应，当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时，控制反应条件可以发生单取代和双取代两种产物；当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时，溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物，这在以前的研究中是没有发现的。

The 6- cyano-1, 1 (1, 3- dioxypropylidene)-7-(carbomethoxyl group- methyl - 5- oxo-Delt6 (8)- tetrahydrochysene indolizine and haloethane reacts with each other for ethylization with existence of alkali and organic solution with or without phase transversion catalyst, and produces mentioned product.

本发明在相转移催化剂或无相转移催化剂存在下，6-氰基-1，1-(1，3-亚丙二氧基)-7-(甲氧羰基-甲基-5-氧代-Δ6(8)-四氢中氮茚类化合物与卤代乙烷在碱和有机溶剂的存在下进行乙基化反应即得6-氰基-1，1-(1，3-亚丙二氧基)-7-1′-(烷氧羰基-丙基-5-氧代-Δ6(8)-四氢中氮茚类化合物。

Except for benzene, hexane, nonane and heptane, the DVP pass ratio values are 77.8%-100%, the DP pass ratio valutes are 66.7%-100%, when sampled 29 other VOCs, which meet the demand for method TO-17 basically.

除了正己烷、正庚烷、苯和正壬炕，以该型采样管采集分析空气中其他29种非卤代烃类VOCs时，其DP合格率为77.8%-100%，DVP合格率为66.7%-100%，基本满足方法TO-17的要求。

In ultraviolet and spark discharging, dichloromethane, trichloromethane, tetrachloromethane and 1, 2-dichloroethane can react with nitrogen dioxide and nitrogen oxide respectively rapidly.

由此得到氯代烷与NO〓在火花放电、紫外光照射条件下，将发生快速化学反应。这对了解臭氧层中卤代烷烃和氮氧化物之间的化学反应有一定的参考意义。

In this project, we have prepared conveniently Si-Mg 1,1-difunctional group reagents-α-silylvinyl Grignard reagents by hydromagnesiation of alkynylsilanes; Se-Br 1,1-difunctional group reagents-α-bromovinylselenides by hydrobromination of alkynylselenides; Sn-Br and Sn-I 1,1-difunctional group reagents by hydrozirconation of alkynylstannanes followed by halogenating reaction.

本项目通过炔基硅烷的镁氢化反应，方便地制得了Si-Mg 1，1-双官能团试剂-α-硅基烯基镁化物；通过炔基硒醚的溴氢化反应，方便地制得了Se-Br 1，1-双官能试剂-α-溴代烯基硒醚；通过炔基锡烷的锆氢化反应，继而卤代方便地制得了Sn-Br和Sn-I 1，1-双官能试剂。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。