卤代烷

Four extracting agents for Lanthanides/Actinides separation , dialkyldithiophosphinic acids, were synthesized from PSCl3 and alkyl halide by Grignard reaction, sulfuration and acidification.

以PSCl3和卤代烷为原料，经格氏反应、硫化和酸化合成了用于镧/锕分离的4个萃取剂——二烷基二硫代次膦酸，其结构经NMR，IR和MS表征。

Amines can engage in nucleophile substitution reaction with alky.

胺能参加与卤代烷的亲核取代反应。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

The destruction of ozone molecules in the ozone layer by chemical reaction with materials released from human activities, including chlorofluorocarbons and halons.

从人类活动中释放出来的物质（包括氟氯烃和卤代烷哈龙）同臭氧层中的臭氧分子发生化学变化，导致其破坏。

This paperindicated that it was good for condensation reaction when benzene-ring bearingelectron-attaching groups. It also showed that and the 6-hydroxyl group could bereacted with acyl halide, haloid ether and halo alkene, but not with halo alkane. It wasnot only the first time to find that the reaction product of D-mannitol and aromaticaldehyde is tri-condensation derivatives, but also the first time to obtain thep-phthaldehyde-sorbitol derivatives containing eight hydroxyl groups.

研究发现：苯环上有吸电子基团时对缩合反应有利；多元醇缩醛衍生物6-羟基除与酰氯反应外，也能和卤代酸酯、溴代烯反应，但不与卤代烷反应；首次发现D-甘露醇与醛反应主要得到三缩合物；首次合成了含有8个羟基的对苯二甲醛和山梨醇的缩合物。

One route was that the amino-groups on the silica gel were transformed to tertiary amines by Eschweiler-clarke reaction that amine-groups react with formaldehyde and methanoic acid to prepare tertiary amines; the silica gel intermediates with tertiary amine groups reacted with chorohydrocarbons to prepare insoluble silica gel quaternary ammonium salt bactericides. Another route was that the amino-groups on the silica gel reacted with excessive chlorohexadecane; the preparing intermediates were quaternized with iodomethane to obtain insoluble silica gel quaternary ammonium salt bactericides.

一条路线是根据埃施韦勒-克拉克(Eschweiler-clarke)胺甲基化反应，进行胺基叔胺化反应，制成带有叔胺官能团的硅胶中间体，此中间体上的叔胺与卤代烷反应生成杀菌活性官能团季铵盐，制成硅胶类水不溶性季铵盐杀菌剂；另一条路线是带有胺反应活性中心的硅胶与过量正氯代十六烷反应，得到的中间体再用碘甲烷季铵化，得到最终产品——水不溶性季铵盐杀菌剂。

PETEDA was synthesized through pentaerythrityl tetrabromide and ethylenediamine's reacting by the aminolyzing reaction of alkyl halide. It was proved that the product contains a lot of amino groups analyzed by FTIR (Fourier Transform Infrared Spectroscopy) and ETA.

以四溴代季戊烷和乙二胺为原料，通过卤代烷胺解反应，合成了树枝状分子季戊四乙二胺，采用傅立叶变换红外光谱和元素分析对其进行了表征。

By reaction of alkyl halide with metallic sodium or hydrogen acid to restore the alkyl halide obtained.

可由卤代烷与金属钠反应或以氢碘酸还原卤代烷制得。

This reaction, called the Hofman elimination, is quite analogous to the dehydrohalogenation of an alkyl halide

这个反应称为Hofman消除反应，它很像卤代烷的脱卤化氢反应。

This reaction, called the Hofman elimination, is quite a nalogous to the dehydrohalogenation of an alkyl halide

这个反应称为Hofman消除反应，它很像卤代烷的脱卤化氢反应。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。