卡环

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

The cure rate of Yunbao on the diseases was 93.10%,7273% and 83.33% respectively.The effect of ciprofloxacin lactate on purulent catarrhal endometritis was better than that of Yunbao...

乳酸环丙沙星治疗慢性卡他性脓性子宫内膜炎的效果优于"孕宝"，"孕宝"治疗慢性卡他性子宫内膜炎和隐性子宫内膜炎的效果则高于乳酸环丙沙星。

Cassini imaging scientists analyzing images acquired over the course of about 600 days found the tiny moonlet, half a kilometer across, embedded within a partial ring, or ring arc, previously found by Cassini in Saturn's tenuous G ring.

卡西尼小组的成像科学家在分析了600多天来获取的图像时发现了这一小卫星，直径约1公里，镶嵌在一段环弧中。这段环弧是由卡西尼飞船早先在土星纤细的 G 环中发现的。

Products include a variety of castings and forging, and so on more than 1,000 pieces of products, of which shackle, the first card, blue flowers, wheels, rings, rotating ring, rings, screws, nuts rings, spring hook, hook-eye, rotating hook, Ring, D-ring, ring fast connection, U-Wire, bollard, hold the door, the living section bolts, butterfly nut products such as stainless steel rigging has been occupied with domestic and international cable industry's fixed market.

产品包括各种铸造件和锻造件等上千余种产品，其中卸扣、卡头、花兰、滑轮、套环、旋转环、吊环螺丝、吊环螺母、弹簧钩、眼型钩、旋转钩、圆环、D型环、快速连接环、U型丝、系船柱、门扣、活节螺栓、蝶型螺母等不锈钢索具产品已占领国内外索具行业的固定市场。

Our company specializes in manufacturing various stainless steel products, hardware accessories, marine hardware and other products, main products are as follows: Shackle (Bow type, Straight type, insurance, Japanese, Continental, American, reversing, rotary, fixed), chuck (Japanese, Continental, Americanê, German, American Forge, Din741), flower-lan (Japanese, American, Korean, closed), rotating ring (style, eye-eye , fork-eye), rings (Continental, Italian, Japanese-style), Pulley, Circle, D-rings, spring hooks, cargo hook, marine hardware (sleeve, slip cap, Smooth hinge base, side and base hinge, through-hole seat, single seat, etc.).

我公司专业生产加工各种不锈钢制品、五金配件、船用五金等产品，主要产品如下：卸扣（弓型，直型，保险，日式，欧式，美式，扭转，旋转式，固定式）、卡头（日式，欧式，美式玛钢，德式，美式锻打，Din741）、花兰（日式，美式，韩式，封闭）、旋转环（叉叉式，眼眼式，叉眼式）、套环、滑轮、圆环、D型环、弹簧钩、货钩、船用五金（滑套，滑帽，平滑底座绞链，侧而底座绞链，通孔座，单孔座等）。

We mainly supply all kinds stainless steel rigging of casting and forging, such as :shackle,wire rope clips,turnbuckle,pulley,thimble,swivels,eye bolt,eye nut,spring hook,eye hook,swivel hook,round ring,quick link,U-Bolt,bollard,pad eye,swivel bolt,wing nut ect.

产品包括各种铸造件和锻造件等上千余种产品，其中卸扣、卡头、花兰、滑轮、套环、旋转环、吊环螺丝、吊环螺母、弹簧钩、眼型钩、旋转钩、圆环、D型环、快速连接环、U型丝、系船柱、门扣、活节螺栓、蝶型螺母等不锈钢索具产品已占领国内外索具行业的固定市场。

Caption:: Saturn's icy rings shine in scattered sunlight in this view, which looks toward the unilluminated northern side of the rings from about 15 degrees above the ringplane. The Sun currently illuminates the rings from the south.

图中的土星环是由卡西尼号探测船以环面15度高的角度拍摄，由於现时太阳光由环的南面照射到环，现在所见的环是环的北面，不是被太阳光照射的一面。

During the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)CH=CH2, several stable osmacycles with novel structure, such as osmabenzenes, osmafurans, osmacycles containing intramolecular-coordinated allene, intramolecular-coordination osmacycles containing osmacarbene, an osmacyclopentadiene, were isolated during the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2-CH=C(PPh_3C(=CH_2)CH=CH_2.In addition, some convenient and efficient methods to prepare these osmacycles were developed.

首先，合成出两种具有反应活性的金属杂五元环IC配合物OsCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2和OsCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)-CH=CH_2，并对它们进行了系统表征；进而，研究了这些活性五元配合物的反应性，合成出多种稳定的锇杂环配合物，其中包括锇苯、锇呋喃、含配位联烯的锇杂IC环化合化物、含锇卡宾的IC环化物、首例锇杂环戊二烯化合物等多元化的产物。

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物：含五元膦-氧螯合环的1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明，配合物46、47都为变形的四方锥构型，膦-氧与钌形成螯合配位，其中苯亚甲基与钌的配位得以加强。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。