卡宾

Six ruthenium benzylidene complexes (60-65) containing pyridine derivative ligandsare prepared and three of them are new.

为此，合成了六个吡啶及其衍生物配位的钌卡宾配合物60-65，其中三个是新的。

RCM reactions of 49 and 50 are chosen to evaluate the catalytic performance ofthe complexes 46-48 because they are informative and simple to manipulate. The resultsindicated that ruthenium benzylidene complexes 46 and 48 possess significant thermalstability and cyano group tolerance.

由于烯烃49、50的闭环交互置换反应简单、清晰，故用来考察新钌卡宾配合物的催化性能，结果表明配合物46、48具有良好的热稳定性及耐氰基性能。

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62)，1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基-(2，4-二甲基吡啶)-二氯合钌(63)中，邻位取代的吡啶作为解离配体，通过邻位基团的空间效应削弱钌-氮配位键，使配体更易解离，提高了催化剂的初活性。

Cabinda is saperated separated from Angola by the the Democratic Republic of Congo.

卡宾达省与安哥拉本土并不接壤，而是被刚果共和国隔开了。

Ivory Coast are currently playing Algeria in Cabinda.

象牙海岸现在正在卡宾达与阿尔及利亚对决。

The other Congo lies to the north, and there seems to be a continued struggle by those who live in the province to achieve independence. Attempts to declare the Republic of Cabinda have met with failure but you can't fault people for trying.

刚果的另一部分朝北躺着，这里似乎总有那些为了赢得独立的人们不断的挣扎，企图向世界宣告：卡宾达共和国虽然遭遇失败，但却不能否定他们的尝试。

A packed crowd watched the entertaining game in the Chiazi Stadium in Cabinda with the locals providing vocal support, especially for Ivory Coast.

拥挤的人群在卡宾达Chiazi体育馆观看了这场娱乐性的比赛，当地球迷提供声援，主要是为象牙海岸。

The arrests were made near the site of the attack in the oil-rich enclave of Cabinda, where rebels have been fighting for independence.

多哥队遇袭发生在卡宾达，此地石油丰富，并且反叛者一直为争取独立而作战。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。