卡宾

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11，详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

With NMR and DFT methods, the Michael additions of alkynyl Fischer carbene complex with a series of substituted pyrazoles as nucleophiles were also studied. All reactions follow the same three-step pathway mechanism described above. Substituents on 3-, 4- and 5- positions of the pyrazolyl ring affect the reaction in the steric and electronic manners, even to change the rate-determining step.

一系列取代吡唑与1-炔基Fischer卡宾化合物的Michael加成反应都遵循前面提出的三步机理，其中吡唑的3-， 4-， 5-位分别从电子效应和立体效应方面不同程度地影响着反应的进行，甚至改变反应的决速步骤。

In the thesis a series ofβ-pyrazolyl-α,β-unsaturated Fischer carbene complexes were synthesized and structurally characterized by NMR, IR and X-ray crystallographic determinations. Based on the dynamic nuclear magnetic resonance and density functional calculation results, a three-step mechanism is proposed for the Michael type addition of pyrazoles to the alkynyl carbene complexes.

本论文合成了一系列β-吡唑基烯基卡宾化合物，并运用核磁共振动力学实验和密度泛函理论计算方法对Michael加成反应的机理及反应速率的影响因素进行了深入探讨。

The cyclopropanation reaction of ethylene with samarium carbenoid was studied by means of the B3LYP hybrid density functional method.

用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。

The reaction of tetrachloromethane with magnesium under general Grignard reaction condition was studied.

林海霞，徐良衡，黄乃聚，四氯化碳与镁的反应及其反应机理的研究──产生二氯卡宾的新方法

The crystal structure of the deoxygenating reaction product 1,1-dichlorotetraphenylcyclopentadienone of phenyl mercury with tetraphenylcyclopentadienone is reported.

本文报道了二氯卡宾(由一溴二氯苯基甲基汞产生)与四苯基环戊二烯酮脱氧反应产物的晶体与分子结构，并就其结构特征讨论了反应机理和产物的关系。

Here you see two different types of skis; the one in your left is modern carving ski.

这里你看到的是两种不同的雪板；左边的是现代卡宾板。

When diaryl ketones were treated in DMF promoted by samarium metal with TMSCl as activator, diaryl ketones react with DMF followed by a carbene rearrangement to afford benzoins unexpectedly, with benzils were obtained as byproducts, the formation of which may be explained as a result arising from the auto-oxidation of benzoins. Further investigation found the reaction could also proceed smoothly when I〓 was used as an activator. The reaction could occur as well in SmI〓/THF, though benzoins were obtained in relatively low yields.

发现当有活化剂TMSCl存在时，金属钐能有效的促进二芳酮和DMF的发生反应，偶联后发生卡宾重排，意外地得到苯偶姻类化合物，同时伴随着少量的二芳基二酮副产物生成，我们推测二芳基二酮的生成可能从苯偶姻的自氧化而来；进一步的研究表明，用一定量的I〓活化金属钐，该反应也可以顺利的进行，并且可以得到相对更好的实验结果。

In the first part of this thesis, a formal [4+2] cycloaddition of ketenes with N-benzoyldiazenes catalyzed by chiral NHCs was studied, which gave 1,3,4-oxadiazin-6-ones in very high yields and enantioselectivites.

论文的第一部分内容是在手性氮杂环卡宾的催化下，烯酮与N-苯甲酰偶氮化合物的环加成反应，合成各种手性的噁二嗪酮，它们还可以经过简单的两步一锅法制备手性氨基酯。

The oxidations of-abietic acid by 〓,〓 and 〓 under various reaction conditions and its addition reaction withdichlorocarbene were investigated.

本文首先从广西产松香中分离纯化得到松香酸，然后探讨了不同条件下〓等氧化剂对其共轭双键的氧化反应以及二氧卡宾对其共轭双键的加成反应。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。