卡宾

And the bridging carbene complex can be converted to other bridging carbene complexes which have a different substituent on the bridging carbene carbon.

而且这种新型的络合物可以转化为在桥卡宾碳上带有不同取代基的桥卡宾络合物。

The study of this thesis enlarges the application of rare earths metal- samarium in organic synthesis that has quite important meaning for our country having abundant rare earths resources. It promotes to explore the new use of rare earths metals in organic synthesis. There will be a great break in the theory and application of the production of carbene.

通过本研究扩大了稀土金属钐在有机合成中的应用范围，这对于我国具有丰富的稀土资源(贮量占世界总贮量的85%以上，稀土金属产量及质量占世界首位)而言，促进开发稀土金属在有机合成中的新用途，具有十分重要的意义；并在产生卡宾的理论上有所突破，填补了卡宾研究领域的空白，取得一些极具价值的学术成果。

The structures of the trimetal bridging carbene complex 28 and the ion-pair bridging carbyne complex 31 have been further confirmed by X-ray diffraction studies.

在与羰基金属阴离子络合物PPN和Na的反应中，我们得到了桥卡宾碳键合氢的桥卡宾络合物，并对两个此类桥卡宾络合物进行了晶体和分子结构的研究。

A novel zwitterion derived from the addition of thiazole carbene to ketene was discovered and captured by an activated alkyne. In this process, we developed a facile and efficient three-component tandem reaction involving thiazole or benzothiazole carbene, disubstituted ketene and activated alkyne.

我们发现了一种新的噻唑卡宾和烯酮形成的两性离子的存在，并用活泼炔成功捕捉，从而发展了一个新的噻唑卡宾或苯并噻唑卡宾、二取代烯酮和活泼炔的三组分串联反应。

Provincial prosecutor Antonio Nito of Cabinda said in a statement the 2 suspects belonged to the Front for the Liberation of the Enclave of Cabinda, which had claimed responsibility for Friday's attack.

卡宾达地区检查官尼托在声明中称，2名嫌犯隶属于"卡宾达解放阵线"，而该组织也已宣称对8日的袭击事件负责。

Because of their strong nucleophility of NHCs, the asymmetric Staudinger reaction between ketenes and imines catalyzed by chiral NHC was achieved, gave -lactams with excellent enantioselectivities.

中文摘要我们组利用氮杂环卡宾的亲核性，成功地实现了氮杂环卡宾催化的烯酮与亚胺的Staudinger反应。

In chapter 2, concerning the chemistry of many kinds of olefin-coordinated alkoxycarbene iron complexes and their isomerized products previously synthesized by our group, we examined their thermolysis reactions and many novel thermolysis products were isolated.

第二章中，对于我们小组以往合成的各类烯烃配位的铁卡宾络合物及其异构化产物，为了研究其反应性能，我们从热解反应着手，研究了一系列烯烃配位的铁卡宾络合物及其异构化产物的热解反应，获得了一系列新奇的热解产物。

It is ascertained the whole tandem reaction sequence pivots on the nucleophilicity of thiazole carbenes, and the solubility of thiazolium precursors has an enormous effect on the reactions.

整个反应的历程取决于噻唑卡宾的亲核性，而卡宾前体在有机溶剂中的溶解性对反应也有较大的影响。

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

The Chapter 2 also shows the reactions of a diiron cationic bridging carbyne complex with N-containing nucleophile such as LiNEt〓 to give the arylcarbene complex 〓.

在含氮亲核试剂LiNEt〓与阳离子桥卡拜络合物反应中，生成桥卡宾碳上键合氢的双铁桥卡宾络合物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。