单膜

SAMs with different chain lengths have different annealing properties, because of different initial states at room temperature, such as gauche concentrations and degrees of order.

不同碳链长度的自组装单分子膜的温度特性不同，其主要原因是这些自组装单分子膜在室温时对应的初始状态不同，如有序度、膜内缺陷含量等不同。

The results indicated that the mixed monolayers containing FCA/ODA mixture with mole proportion of 1 to 1 possessed the best stability and the highest incompressibility.

第二部分：研究了不同pH值的亚硒酸溶液亚相上ODA单分子膜的性质，π-A等温线和dπ／dA-A曲线都表明碱性亚相上单分子膜的成膜性能较好。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

In this paper, the characterization meth-ods on SAMs in recent years by the means of electrochemistry, spectroscopy, micrology and surface wettibility are re-viewed .

本文综述了自组装单分子膜体系的类型和基底表面的处理方法，着重从电化学、谱学、显微学以及表面润湿性等方面综述了近几年来自组装单分子膜的表征方法研究进展，并对其发展前景作了展望。

The miscibility, molecular interaction of the two components and structure of condensed mixed momolayers were investigated in details.

对不同组分的Ru2+3［简称Ru］与花生酸在纯水亚相上的混合单分子膜的相容性、分子间相互作用以及凝聚单分子膜的结构进行了研究。

Methods The Wistar rats were used as the experimental animal. On the back of each rat, a skin flap, measuring 1.5 cm×6 cm, caudally based, was elevated. Wound edges and the flap bed were separated from the flap itself by a silicone sheet. The VitC, bFGF, Magnesium sulfate and Papaverine were taken in the areas between flap and sheet. With 8 rats in each group, the drug-taken group was as trial group, while the physiological saline group was as control group. On the seventh day after the flap elevation, flap survival length was measured.

以鼠背部中线为中轴，以两侧髂嵴连线为蒂，形成一个1.5cm×6cm的单蒂皮瓣，其全长自皮肌层下与深筋膜游离，下垫置医用硅膜，硅膜以不露出切口，又起到阻隔真皮血运为宜，以小三角针用3-0丝线先缝合皮瓣两侧切口，然后将上述4种药物加入皮瓣与硅膜之间，再缝合皮瓣的头端将维生素C、bFGF、硫酸镁、罂粟碱分别作为实验组，以生理盐水作为空白对照组，每组8只动物，术后单笼喂养7d，取材并检测皮瓣存活的长度。

Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.

全文共分8章：第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述；第二章研究了磷脂-桐酸脂质体的稳定性，通透能力及桐酸的聚合对这些性质的影响；磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体，〓的作用首先是使脂质体集聚然后使脂质体融合，并加速内包荧光物的释放；第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA，DDOL，研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响，聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性；第四章合成了两类氨基酸为极性基团的双亲分子，它们均可以在超声下形成稳定的脂质体结构；氨基酸基团可以在脂质体上进行缩聚反应，若聚合后脂质体表面仍有足够的亲水能力，则可得到稳定的多肽型脂质体；聚合后脂质体的相变温度降低，通透能力增加；第五章合成了四种亲水基团为单糖基的双亲分子GL-l，GL-2，GL-3， GL-4，研究了它们在水中的分散情况、集合体形态与分子结构的关系；在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高，阻止脂质体在低温放置时的集聚与融合；第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1，CL-2，CL-3；它们可以象胆固醇一样与磷脂混合形成稳定脂质体，胆甾环基团位于脂质体双分子层膜的中间；与胆固醇的作用相反，它们可以增加磷脂双分子层膜的流动性，降低混合脂质体的相变温度；三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关，比膜厚度短的分子影响最大。

The factors of temperature and humidity influenced on film thickness and order of layer were studied, in which pulling speed and pulling times were also included. It showed that the thickness of single dip-coating film reached 0.23 μm ~ 0.625 μm, and the degree of order of surface layer were still holding much higher.b Adopting calcined or uncalcined mesoporous silica membrane as matrix, nano zirconia particles were assembled through ion exchange method and ion-template exchange method.

结果表明，单次提拉膜膜厚0.23μm～0.625μm、8次提拉后表层膜仍有一定的有序性； b以自制的介孔氧化硅煅烧/未煅烧厚膜样为基体，采用离子交换法/离子模板交换法组装锆氧纳米粒子，选用DSC-TG、FT-IR、Uv-vis、SAXRD等对不同组装方法、锆源浓度、pH值等组装条件下ZrO_2/介孔氧化硅厚膜组装效果进行评价。

The results show that the perfect Honeycomb pattern films without defects within area of 0.8cm^2 can be obtained at the PS concentration ranges from 20 mg/mL to 50 mg/mL and PS/TEOS mass ratio less than 2. The films cast from the chloroform solution of dicarboxyl terminated PS were more perfect than those cast from the chloroform solution of monocarboxyl terminated PS. The perfect Honeycomb structure films could be obtained with both chloroform and benzene as solvents, but the pore diameter of films cast from benzene solution of PS was larger than that of films cast from chloroform solution of PS.

研究结果表明，聚合物浓度在20~50mg/mL，PS/TEOS质量比大于2：1的条件下可以制备结构完整的多孔膜，且制备的Honeycomb结构在0.8平方公分内无缺陷；采用双羧基封端的聚苯乙烯成膜效果好于单羧基封端的成膜效果；以氯仿和苯作为溶剂均可以制备完全Honeycomb结构的复合膜，但以苯为溶剂制备的多孔膜孔径较大。

EPE series: ordinary EPE, rehabilitation PO BAG EPE film anti-static, non-wax EPE, EPE Turpin, EPE encryption, encryption hardware add EPE, anti-static EPE, rehabilitation PO membrane Antistatic EPE, PO EPE laminating, PE EPE¤the one hand, PO composite aluminum composite film side of EPE, single / double-sided foil EPE review the one hand, while aluminum complex rehabilitation EPE color film, one side of complex aluminum complex of textile fabrics EPE, EPE composite of different materials, plating color film laminate EPE, EPE composite of various special materials, PS board, pearl board, KT board, advertisement board, fire EPE, EPE bridge, all kinds of special EPE Products.

珍珠棉全系列：普通珍珠棉、复PO膜防静电珍珠棉袋、无蜡珍珠棉、特平珍珠棉、加密珍珠棉、加密加硬珍珠棉、防静电珍珠棉、复PO膜防静电珍珠棉、PO复膜珍珠棉、PE淋膜珍珠棉、一面复合PO膜一面复合铝膜珍珠棉、单/双面覆铝箔珍珠棉、一面复铝膜一面复彩膜珍珠棉、一面复铝膜一面复纺织布珍珠棉、复合不同材料珍珠棉、镀彩膜贴合珍珠棉、复合各种特殊材料珍珠棉、PS板、珍珠板、KT板、广告板、防火珍珠棉、珍珠棉架桥、各种特殊珍珠棉产品。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失