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The impact of temperature,pH and ionic strength on the volume phase transition of the hydrogels is studied.The result shows that the volume phase transition temperature of ionizable and thermosenstive copolymer hydrogels depend upon the hydrophilic/hydrophobic character of the comonomers...

结果表明,疏水基末端端基的疏水程度决定凝胶体积相变的速率,随着疏水性单体甲基丙烯酸酯烷基链的增长,凝胶的疏水性增强,凝胶的相转变pH向低pH处迁移;温度高于LCST时,分子间的氢键作用减弱,疏水基团间的相互作用加强,凝胶发生体积相变。

In the polymerization procedure,S--α-phenyl ethylamine was used as target template molecules,methacrylic acid was selected as functional monomers, ethylene glycol dimethacrylate or divinylbenzene as crosslinker, azobisisobutyronitrile or benzophenone was used as irritator.

以S--α-苯乙胺为模板,甲基丙烯酸为功能单体,分别以二甲基丙烯酸乙二醇酯、二乙烯基苯为交联剂,偶氮二异丁睛或二苯甲酮为引发剂,采用了本体聚合法、悬浮聚合法合成了一系列的S--α-苯乙胺印迹聚合物。

Lauryl acrylate, octadecyl acrylate and isobornyl mechacrylate are used as monomers and reacted with 1. 0G and 2. 0G amine-terminal PAMAM dendrimers to form long chain dendrimer for the first time.

本文选用单体甲基丙烯酸异冰片酯、丙烯酸十二酯和丙烯酸十八酯与1.0、2.0G的胺端基PAMAM树形分子进行Michael加成反应合成得到长链树形分子衍生物。

Vinyl acetate was copolymerized with triallyl isocyanurate which was then saponified, activated, and DNA was immobilized on to the adsorbent.

本文以异氰尿酸三烯丙酯 TAIC为交联剂,醋酸乙烯酯为单体合成的共聚物,经皂化和活化后,固载上DNA,即得含DNA配体的VT吸附剂。

Polyethylene glycol monomethylether, isophorone diisocyanate and hydroxyl ethyl methacrylate were used as raw materials, the mixmonomer was synthesized.

采用聚乙二醇单甲醚、异氟尔酮二异氰酸酯和甲基丙烯酸β-羟乙酯合成混合单体

The 2-continuous stirred-tank reactor model was applied to simulating the fast transition of isophthalic acid content during the production conversion of bottle-grade polyester.

应用二级连续理想混合流模型对瓶用聚酯转产中第三单体间苯二甲酸的快速过渡法进行模拟研究,并分析得出影响间苯二甲酸过渡速度的因素。

The new type semi-aromatic transparent nylon has been successfully developed for the first time using cheaper monomers,including linear chain aliphatic diamines,terephthalic acid,isophthalic acid and so on,by means of polybasic copolycondensation.

采用无侧基的脂肪族混合二元胺、对苯二甲酸、间苯二甲酸等为单体,通过多元无规共缩聚方法制备了半芳香透明尼龙,研究了SA型透明尼龙的静态热机械性能和动态力学性能。

The wholly aromatic four-component copolyesters were prepared from p-acetoxy-benzoic acid, hydroquinone diacetate, 2,6-naphthalene dicarboxylic acid and isophthalic acid by melting polycondensation.

由对乙酰氧基苯甲酸、对苯二酚二乙酯、2,6-萘二甲酸及间苯二甲酸四种单体通过熔融缩聚反应,合成了全芳香族四组分共聚酯。

In this paper, the copolymers of acrylic acid/acrylamide, isopropenyl phosphonic acid/acrylamide were prepared with peroxide as initiator, water as solvent, acrylic acid, isopropeneyl phoshonic and acid acryl amide as monomers.

以水为溶剂,过硫酸铵为引发剂,丙烯酸、异丙烯膦酸、丙烯酰胺为单体,分别合成了低分子质量的丙烯酸/丙烯酰胺、异丙烯膦酸/丙烯酰胺二元共聚物,以及不同配比的丙烯酸/异丙烯膦酸/丙烯酰胺三元共聚物。

The chemical component and structure of polyborazine were analyzed, and the influence of different propylamine/isopropylamine molar ratio on the polyborazine properties and spinnability were examined.

通过分析不同正丙胺/异丙胺配比制得的聚合产物的组成与结构,探讨了不同单体的胺基取代基对先驱体的聚合反应性及对产物结构的影响。

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