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Based on this monomer, several novel polyimides bearing side chain s composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体,然后通过两步法热酰亚胺化工艺制备了新型的含氰基联苯基团侧链的聚酰亚胺。

Based on this monomer, several novel polyimides bearing side chains composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体,然后通过两步法热醯亚胺化工艺制备了新型的含氟基联苯基团侧链的聚醯亚胺。

Good thermal stability and self-extinguishing behavior was observed with the cured polybenzoxazine resins. Second, furan-containing benzoxazine monomers, P-FBz, BPA-FBz, and 4FP-FBz were prepared using furfurylamine as a raw material. Formation of furfurylamine Mannich bridge networks in the polymerizations of P-FBz and BPA-FBz increased the cross-linking densities and thermal stability of the resulting polybenzoxazines. P-FBz and BPA-FBz- based polymers also exhibited high glass transition temperatures above 300℃, high char yields, and low flammability with a limited oxygen index value of 31. The dielectric (Dk3.21–3.39) and mechanical properties (high storage modulus of 3.0–3.9 GPa and low coefficient of thermal expansion of 37.7– 45.4 ppm) of the P-FBz and BPA-FBz-based polymers were superior or comparable to other polybenzoxazines. 4FP-FBz used for polybenzo- xazine modification by means of formation of benzoxazine hybridation with P-FBz.

第二部份以2-呋喃甲胺为起始物,制备了P-FBz、4FP-FBz与BPA-FBz 三个含呋喃官能基之氧代氮代苯并环己烷的单体;BPA-FBz与P-FBz於开环聚合中形成之Mannich bridge网状结构有效地提升聚氧代氮代苯并环己烷聚合物之交联密度与热安定性;Poly与Poly具有大於300℃之玻璃转移温度、高的焦炭生成率与具有31之极限氧指数(Limited oxygen index, LOI)的难燃性特质,Poly与Poly之介电常数(Dk=3.21~3.39)与机械性质[3.0~3.9 GPa的储存模数与37.7~45.4ppm之低热膨胀系数( Low coefficient of thermal expansion, Low CTE)]均较其他聚氧代氮代苯并环己烷为优;4FP-FBz具有低之介电常数(Dk=2.7),以其作为降低介电常数之反应型改质剂,与P-FBz混成,证实可有效地降低Poly的介电常数。

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况:三氯氢硅:又名三氯硅烷、硅氯仿,主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成,是有机硅烷偶联剂中最基本的单体,也是生产半导体硅、单晶硅的原料;四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用,在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统,下步可制取多晶硅。

The method is characterized in that the acid solution of one of hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid and hydriodic acid is divided into two portions; aniline monomer and ammonium persulfate are respectively added; then aniline monomer solution and ammonium persulfate solution can be prepared.

一种乙酸松油酯的制备方法,其特征是,将盐酸、硫酸、硝酸、磷酸、氢碘酸中任一种酸溶液分成两等份,并分别加入苯胺单体和过硫酸铵,形成苯胺溶液和过硫酸铵溶液。

During the process of polysialic acid hydrolyzation, a large mount of pigment was produced and interfered the successive separation process.

聚唾液酸水解过程会产生大量的色素物质,影响唾液酸单体的后继分离。

It was found that the NA was influenced significantly by the hydrophobe content and the hydrophobic block size of the copolymer.

聚合物自组装聚集数NA随疏水单体含量的增加和疏水嵌段长度的减小而增大,同时也随聚合物浓度和NaCl浓度增加而增大。

The N A enhanced with increasing the hydrophobe content and decreasing the block length,as well as increased with increasing the concentration of copolymers and sodium chloride.

聚合物自组装聚集数NA随疏水单体含量的增加和疏水嵌段长度的减小而增大,同时也随聚合物浓度和NaCl浓度增加而增大。

Its solution behaviors are similar to and even better than those of corresponding polyelectrolytes singly modified with the same hydrophobe to the added surfactant.

通过溶液共聚,将碳氢和氟碳这两种疏水单体无规地接枝到聚电解质主链上,得到的这类混合改性的聚电解质无论与碳氢小分子表面活性剂还是与氟碳小分子表面活性剂作用均表现出和同种大分子表面活性剂与小分子表面活性剂作用时相似甚至更好的缔合情形。

By testing the material's hydroscopic properties, hygroscopic property, moisture vaporizing and moisture retention, we analyzed the effects of configuration of the substrates on the environmental behavior.

从材料的吸水性、吸湿性、水分蒸发性和保水性等方面探讨了纤维原料的单体纤维形态、材料面密度、蓬松度等因素对基材环境学特性的影响。

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