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A mode of the directionally growth of PAn on the surface of NaFe〓P〓rod-like particle was suggested. Some of aniline molecules in the reactants are fixed on the surface of skutterudite particles before the beginning of the polymerization. Other aniline molecules link with the aniline molecules fixed on the surface of skutterudite and form liner chains when the initiater is added into the reactants.

提出了聚苯胺在棒状方钴矿NaFe〓P〓材料表面定向生长的物理化学模型:在表面配位键的作用下方钴矿晶须表面首先附着了一层苯胺单体,在引发剂的作用下溶液中的苯胺分子在这层单体上定向聚合,形成了定向聚苯胺线性分子。

The polymerization reactivity of the monomers increases with an increase in the spacer length and only those monomers and polymers with a flexible spacer≥(CH_2)_6 show liquid crystalline with their mesophases being smectic A.

随着柔性间隔基增长,单体的反应活性也相应增加,而且只有当柔性间隔基≥6时聚合物和单体才呈现出近晶A液晶态。

The encapsulated TiO〓 particles by polymer were obtained with soapless emulsion polymerization of methyl methacrylate in water in the presence of the pretreated TiO〓 particles.

一种是用偶联剂钛酸丁酯对亲水性TiO〓粒子进行预处理,钛酸丁酯与TiO〓表面羟基反应,交联到TiO〓粒子表面,使TiO〓粒子表面由亲水性转变为憎水性,改善无机粉体与有机单体的亲合性,再进行TiO〓存在下甲基丙烯酸甲酯的无皂乳液聚合,即可得到TiO〓-PMMA复合粒子:另一种方法是用表面活性剂对TiO〓进行预处理,再进行TiO〓粒子存在下甲基丙烯酸甲酯的无皂乳液聚合,TiO〓粒子表面可形成一层均匀的聚合物膜,提出了包覆机理,指出单体在无机粉体表面发生聚合的关键是预先在粒子表面形成聚合场所,即吸附一层表面活性剂。

Di-para-zylyene vaporizes at 400K in vacuum and is spitted at 950K with the vapor being deposited on the surface of solid when its temperature is below 300K.

制备聚对二甲苯薄膜的原料在400K附近蒸发,950K附近裂解成单体单体在300K的低温表面聚合成膜。

First, 4-(2, 3-epoxypropoxyl) benzaldehyde was obtained by reaction of 4-hydroxy benzaldehyde and epichlorohydrin. Then, the Wittig reaction was carried out to convert EBD to styryl glycidyl ether.

首先用对羟基苯甲醛和环氧氯丙烷反应制备4-(2, 3-环氧丙氧基)苯甲醛,然后通过Wittig反应将醛基转化为乙烯基得到含环氧基团的功能性单体苯乙烯基环氧丙基醚,最后用ATRP方法聚合单体SGE得到含环氧侧基的聚苯乙烯。

The result indicated that we can get stable homopolymer and copolymer emulsion with uniform size distribution, when the ratio of sodium polyether sulfovinate modified polysiloxane to sodium lauryl sulfate was two, the quantity of the emulsifiers ranged from 6% to 8%, the quantity of initiator ranged from 0.4% to 0.8%, the stirring speed ranged from 200rpm to 250rpm, the polymerization temperature was 80 centigrade degree. As for the copolymer emulsion, the more the TRIS content in the monomers, the larger the water contact angle of their films became, namely, the surface energy of the copolymer films increased with the TRIS content in the monomers. In addition, the glass-transition temperature of the copolymers ranged from high temperature region to low temperature region with the increasing of TRIS content in the monomers.

结果表明:当乳化剂用量在6%~8%、改性乳化剂与十二烷基硫酸钠复配比为2:1、引发剂用量在0.4~0.8%、聚合温度为80℃、搅拌速度在200~250rpm时,得到的均聚物和共聚物乳液稳定,而且粒径分布均匀;对于共聚物乳液来说,随着单体中TRIS含量的增加,所得聚合物膜的水滴接触角增加,即其表面能增加:另外,随着共聚单体中TRIS含量的增加,共聚物的玻璃化转变温度从PMMA的Tg的高温区向PTRIS的Tg的低温区移动。

This paper first stated the hydrolysis law of organochlorosilane and the effect of various R/Si and ph/R on the properties of propolymer,there showed the mathematical calcu- lation method and computer progrom of the every monomer amount to synthetize propolymer, and provided the necessary theortical basis and quantitive calculation equation for the syn- thetise,In addition,the co-existing structure model of linear and trapezoid was put forward on the analysis of prepolymer micro-structure,which laid a found...

本文阐述了有机氯硅烷单体的水解规律及不同R/Si和ph/R值对预聚体性能的影响,在此基础上,提出了合成预聚体所需各单体用量的数学计算方法和计算机计算的程序,为合成提供了必要的理论依据和定量的计算公式。此外,文章在剖析预聚体微观结构的基础上,提出了线型与梯型结构并存的结构模型,为进一步更深入地认识预聚体的性能奠定了理论基础。

This product was prepared w ith octamethyl-cyclotetrasiloxane and tetramethyltetravinylcyclote-trasiloxane as monomers,a low visco sity hydroxyl -terminated silicone oil as an end -bl ocking agent and tetramethylammonium hydroxide as catalyst.

以八甲基环四硅氧烷为单体,四甲基四乙烯基环四硅氧烷为改性单体,羟基硅油为封端剂和相对分子质量调节剂,四甲基氢氧化铵为催化剂,在羟基硅油质量分数小于0。

This product was prepared w ith octamethyl-cyclotetrasiloxane and tetramethyltetravinylcyclote-trasiloxane as monomers,a low visco sity hydroxyl -terminated silicone oil as an end -bl ocking agent and tetramethylammonium hydroxide as catalyst.

以八甲基环四硅氧烷为单体,四甲基四乙烯基环四硅氧烷为改性单体,羟基硅油为封端剂和相对分子质量调节剂,四甲基氢氧化铵为催化剂,在羟基硅油质量分数小于0.13%,催化剂质量分数为0.004%~0.007%时,采用共聚法制备了相对分子质量大于45×104,收率大于90%的端羟基聚二甲基硅氧烷。

This dissertation successfully fabricated cross-linked polysiloxanes under base catalysts such as potassium hydroxide siloxanolate or tetramethylammonium hydroxide (Me_4NOH) siloxanolate by anionic ring-opening copolymerization of cyclosiloxanes and Polyhedral Oligomeric Silsesquioxanes as multifunctional monomers.

本论文首次通过阴离子开环共聚,成功地将POSS大分子作为多官能团单体,与环硅氧烷在KOH硅醇盐或Me_4NOH硅醇盐等碱性催化剂的作用下,直接合成交联聚硅氧烷:通过调节POSS大分子和环硅氧烷单体的种类以及化学计量比,可合成出一系列不同种类和不同交联密度的交联聚硅氧烷;并对其阴离子开环共聚机理以及极性调节剂DMAc对凝胶时间的影响进行了详细讨论;同时借以凝胶含量和溶胀比、GPC、FT-IR、固体~(13)C和~(29)Si NMR、WAXD、DSC以及TG等手段对所得聚合物的微观结构以及热性能进行了详细考察。

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