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A range of oligoaryls having alternating para- or meta-benzene-furan rings is synthesized by rapid convergent/divergent method from the annlation of a propargylic dithioacetal and an aldehyde having a propargylic dithioacetal moiety as the substituent.

中文摘要结合分流法/汇集法,利用炔丙基硫缩酮单体和另一具有醛基的单体进行环化反应,可以迅速合成对位及间位取代苯环呋喃交错寡聚物。

Secondly,UV spectrophotometry was adopted to research the combination action on SM_2 and SIZ with MAA and 4-Vp.The combination action of functional monomer with template molecules were produced in the results. Then,the prediction imprinting principle of SM_2 and SIZ were given. The diagrams of infrared spectrum were analysed in MAA and 4-Vp and IMPs of SM_2. It was discoved that the absorbability peak of C=C function group in the IMPs were turn to be very low ,but the function group of carboxylic acid and pyridyl in the IMPs were no evidence change, and the condition was created in the molecular recognition of MIPs. Thermal Analysis was adopted to research IMPs ,in which ,a better thermal stability and its decompose temperature were showed in the results.

其次,本文利用紫外分光光度法研究磺胺二甲嘧啶和磺胺异噁唑与甲基丙烯酸或4-乙烯基吡啶的结合作用,结果表明,溶液中的功能单体与模板分子之间产生了结合作用,并预测磺胺二甲嘧啶和磺胺异噁唑印迹机理;分别分析了功能单体甲基丙烯酸、4-乙烯基吡啶、磺胺二甲嘧啶和磺胺异噁唑分子印迹聚合物的红外谱图,经过对比发现制得的印迹聚合物中C=C双键峰很小,并且功能键羧酸键和吡啶氮没有明显变化,这为聚合物特异识别特性创造了条件;利用综合热分析仪,对分子印迹聚合物进行综合热分析,结果表明分子印迹聚合物具有较好的热稳定性,分解温度也较高。

The synthesis of poly was based on 4,4′-oxydianiline and pyromellitic dianhydride.

本研究首先经由二胺基二苯基醚(4,4′-ODA)单体和苯均四甲酸二酐单体,反应合成聚醯胺酸前驱物。

Tgs are about 573 K for copolyimides based on pyromellitic dianhydride and 533—543 K for those based on 3,3′,4,4′-diphenylethertetra-carboxylic dianhydride and are almost independent of the chromophore loading level.

以刚性相对较大的均苯四甲酸二酐为二酐单体的PPI 的Tg在573 K左右;以二苯醚-3,3′,4,4′-四甲酸二酐为单体的OPI 的Tg在533~543 K之间,且基本与染料发色团含量无关。

Based on 26B4APBN monomer, polyamic acid was obtained by polymerization with pyromellitic dianhydride, and further imidized into polyimide film by heating process.

由二胺单体和均苯四甲酸二酐进行聚合得到26B4APBN/PMDA聚酰胺酸,再经热亚胺化得到聚酰亚胺薄膜;测试了该薄膜的接触角,讨论了单体分子结构对聚合物接触角的影响。

In this paper, the third monomer 1,4- benzenediamine was introduced into the system of pyromellitic dianhydride and 4, 4-diamino diphenyl. Polyamic acid was synthesized in N-methyl pyrrolidone by solution polycondensation. The chemical structure of the polymer obtained was characterized by infrared spectrum. The dynamic viscosity and intrinsic viscosity were measured. Studies were mainly focused on the influences of monomer solid contents, monomer adding methods on intrinsic viscosity.

本实验在常用的均苯四酸二酐和4,4'—二氨基二苯醚聚酰亚胺体系中,引入第三单体对苯二胺,采用三元共聚的办法合成出聚酰胺酸溶液,对合成产物进行了分子结构的红外光谱分析以及特性粘数、动力学粘度的测试,并讨论了单体固含量、加入方式等对聚酰胺酸特性粘数的影响。

In this paper, 4-4-(trifluoromethoxy benzoyl cyclohexyl-3, 5-diaminobenzoate with a large branch chain, pyromellitic dianhydride and 4-(4-aminobenzyl) benzenamine were used to synthesize polyimides. The effect of monomer charge order on pretilt angle was investigated for the first time when PIs were used as LC alignment layer, and the effect of diamine mole ratio on pretilt angle was studied. The thermal stability of the pretilt angle was discussed.

文章用均苯四酸二酐、4,4'-二胺基二苯甲烷和具有较大支链的4-(4-苯甲酰基)环己基-3,5-二胺基苯甲酸酯等单体制备聚酰亚胺,首次研究了单体加料顺序对液晶预倾角的影响,同时也研究了二胺配比对液晶预倾角的影响问题,并探讨了预倾角的热稳定性等问题。

Secondly, according to the construction and characteristic of the N-isopropylacrylamide and the temperature-sensitivity of PNIPA hydrogel, Pdualistic hydrogel was synthesized by microwave low temperature plasma. The effects of the factors on the swelling characteristic of P dualistic hydrogel, such as treatment time and power of plasma, concentrations of crosslinking agent and total monomers, proportion of AMPS, polymerizing temperature etc, was discussed in detail. The three dimensions structure , thermostability , reversional volume , swelling/deswelling kinetics, temperature-sensitivity and pH-sensitivity of the hydrogel were also investigated. The optimal synthesizing technics of P dualistic hydrogel initiated by microwave low temperature plasma was confirmed.

在此基础上,结合NIPA的结构特征和PNIPA的温敏性,用微波低温等离子体引发聚合了P二元智能凝胶,详细探讨了微波低温等离子体处理功率、处理时间、总单体浓度、AMPS单体浓度、交联剂浓度及聚合反应溫度等因素对P二元凝胶溶胀性能的影响;并对其三维交联结构、热稳定性、失水-吸水动力学、温度敏感性、pH敏感性、体积复原性等进行了研究;确定了适合微波低温等离子体引发聚合P二元智能凝胶的最佳工艺。

Two kinds of fluids including liquid crystal and the mixture of liquid crystal and dibutyl sebacate were injected into the micro motors with four different structures of electrodes respectively.The renational corves between the rotate speed of the rotor and the voltage were got,and a series of conclusions o...

分别将单体液晶和单体液晶与癸二酸二丁酯的混合液体注入具有4种不同电极结构的微马达,得到了8条转子转速与电压的关系曲线,得出了转速与电压、液体种类、电极结构等关系的一系列结论。

Through analysis of stage head, the influence factors sequently is: the dosage of initiation agent, the ratio of monomer to starch, the crossing agent, the ration of each monomer.

通过极差分析得出各因素对反应影响的主次:引发剂用量,淀粉与单体比,交联剂用量,单体比。

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