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十四碳烷

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They were eucalyptol, bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,(1R)-, borneol, 1-methyl-2-(1-methyl ethenyl)-(1R-cis)-cyclobutaneethanol, limonene, 1-hydroxymethyl-7,7-dimethy lbicyclo[2.2.1]heptan-2-one,-spathulenol, 3,7,11,15-Tetramethyl-2-hexadecen-1-ol, isocitronellol,-9-Octadecenoic acid, heneicosane, respectively.

阿给中共有11个阿给炭没有检测出的成分,包括桉油精、D-樟脑、冰片、(1R-cis)- 1-甲基-2-(1-甲基乙烯基)环丁基乙醇、二戊烯、1-羟甲基-7,7-二甲基-双环[2.2.1]庚-2-酮、-匙叶桉油烯醇、3,7,11,15-四甲基-2-十六碳烯-1-醇、异香茅醇、-9-十八碳烯酸和廿一烷。

Glycolipid biosurfactant can decrease oil-water interfacial tension greatly after it was recombined with other chemical additives, the emulsification capability of such glycolipid was excellent.

3以石油、十四烷为碳源产生的糖脂表面活性剂经复配后降低油水界面张力效果显著、乳化能力强。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3,4-二溴马来酰亚胺进行N-甲基化反应合成3,4-二溴-N-甲基马来酰亚胺的同时,以碳酸二甲酯为甲基化试剂,对3,4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究;考察了1,4-二氮杂双环[2.2.2]辛烷,1,8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响,并应用碳酸二甲酯为甲基化试剂,合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

In optimal condition, the biosurfactant concentration can reach 2.2g/L in 150h with 20g/L tetradecane as sole carbon source, the biosurfactant concentration was stable at 165~220mg/L with 20g/L crude oil as sole carbon source.

4在优化条件下,以20g/L十四烷为碳源,培养150小时,糖脂表面活性剂浓度可达到2.2g/L,以20g/L石油为唯一碳源,糖脂浓度稳定在165~220mg/L。

Inoptimal condition, the biosurfactant concentration can reach 2.2g/L in 150h with 20g/L tetradecane as sole carbon source, the biosurfactant concentration was stable at 165~220mg/L with 20g/L crude oil as sole carbon source.

4在优化条件下,以20g/L十四烷为碳源,培养150小时,糖脂表面活性剂浓度可达到2.2g/L,以20g/L石油为唯一碳源,糖脂浓度稳定在165~220mg/L。

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