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十四烷

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With benzoic acid, terephthalic acid, 2. 6naphthalene dicarboxylic acid, dimethyl-2, 6-naphthalene dicarboxylate as solutes, water, acetic acid, N, N-dimethylformamide, N, N-dimethylacemide, dimethyl sulphoxide, N-methl2-ketopyrolidine, and the mixture of water and acetic acid as solvents respectively, the solubilities of 15 binary systems and 4 ternary systems were determined.

实验以苯甲酸、对苯二甲酸、2,6-NDCA、2,6-萘二甲酸二甲酯为溶质,以水、醋酸、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺、二甲基亚砜、N-甲基-2-吡咯烷酮以及水和醋酸的混合溶液为溶剂,测定了十五个二元物系和四个三元物系的溶解度数据。

The uniform nano-sized titanic oxide mesoporous thin film which can be coated repeatedly was prepared by adding tetrahydrofuran which acts as dispersant to micro-emulsion system consisting of water,cyclohexane,hexadecyl trimethyl ammonium bromide and butyl alcohol.

通过在水、环己烷、十六烷基三甲基溴化铵、正丁醇4组分构成的微乳液体系中加入起分散作用的四氢呋喃,制备出均匀、可重复成膜的纳米氧化钛介孔薄膜。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3,4-二溴马来酰亚胺进行N-甲基化反应合成3,4-二溴-N-甲基马来酰亚胺的同时,以碳酸二甲酯为甲基化试剂,对3,4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究;考察了1,4-二氮杂双环[2.2.2]辛烷,1,8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响,并应用碳酸二甲酯为甲基化试剂,合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

Relative retentions of 12 S-compounds on 4 different liquid phases were given.

给出了十二种硫化物在沙鱼烷、苯二甲酸二壬酯、磷酸三甲苯酯及亚氨基二丙腈四种柱子上的相对保留值。

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